The {sup 12}C/{sup 13}C Ratio in Sgr B2(N): Constraints for Galactic Chemical Evolution and Isotopic Chemistry

Journal Article · Sun Aug 20 04:00:00 EDT 2017 · Astrophysical Journal

DOI:https://doi.org/10.3847/1538-4357/AA816B· OSTI ID:22663207

Halfen, D. T.; Ziurys, L. M. ^[1]

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1. Department of Chemistry and Biochemistry, University of Arizona, 1305 E. 4th Street, Tucson, AZ 85719 (United States)

A study has been conducted of {sup 12}C/{sup 13}C ratios in five complex molecules in the Galactic center. H{sub 2}CS, CH{sub 3}CCH, NH{sub 2}CHO, CH{sub 2}CHCN, and CH{sub 3}CH{sub 2}CN and their {sup 13}C-substituted species have been observed in numerous transitions at 1, 2, and 3 mm, acquired in a spectral-line survey of Sgr B2(N), conducted with the telescopes of the Arizona Radio Observatory (ARO). Between 22 and 54 individual, unblended lines for the {sup 12}C species and 2–54 for {sup 13}C-substituted analogs were modeled in a global radiative transfer analysis. All five molecules were found to consistently exhibit two velocity components near V {sub LSR} ∼ 64 and 73 km s{sup −1}, with column densities ranging from N {sub tot} ∼ 3 × 10{sup 14} − 4 × 10{sup 17} cm{sup −2} and ∼2 × 10{sup 13} − 1 × 10{sup 17} cm{sup −2} for the {sup 12}C and {sup 13}C species, respectively. Based on 14 different isotopic combinations, ratios were obtained in the range {sup 12}C/{sup 13}C = 15 ± 5 to 33 ± 13, with an average value of 24 ± 7, based on comparison of column densities. These measurements better anchor the {sup 12}C/{sup 13}C ratio at the Galactic center, and suggest a slightly revised isotope gradient of {sup 12}C/{sup 13}C = 5.21(0.52) D {sub GC} + 22.6(3.3). As indicated by the column densities, no preferential {sup 13}C enrichment was found on the differing carbon sites of CH{sub 3}CCH, CH{sub 2}CHCN, and CH{sub 3}CH{sub 2}CN. Because of the elevated temperatures in Sgr B2(N), {sup 13}C isotopic substitution is effectively “scrambled,” diminishing chemical fractionation effects. The resulting ratios thus reflect stellar nucleosynthesis and Galactic chemical evolution, as is likely the case for most warm clouds.

• OSTI ID: 22663207
• Journal Information: Astrophysical Journal, Journal Name: Astrophysical Journal Journal Issue: 2 Vol. 845; ISSN ASJOAB; ISSN 0004-637X
• Country of Publication: United States
• Language: English

Related Subjects

79 ASTRONOMY AND ASTROPHYSICS
ABUNDANCE
CARBON 12
CARBON 13
COMPARATIVE EVALUATIONS
DENSITY
ENRICHMENT
EVOLUTION
FRACTIONATION
GALAXIES
ISOTOPE RATIO
ISOTOPIC EXCHANGE
MOLECULES
NUCLEAR REACTIONS
NUCLEOSYNTHESIS
RADIANT HEAT TRANSFER
TELESCOPES
VELOCITY