Effect of Mn and Ti substitution on the reflection loss characteristic of Ba{sub 0.6}Sr{sub 0.4}Fe{sub 11-z}MnTi{sub z}O{sub 19} (z = 0, 1, 2 and 3)
The synthesis and characterization of composition Ba{sub 0.6}Sr{sub 0.4}Fe{sub 11-z}MnTi{sub z}O{sub 19} (z = 0; 1; 2 and 3) compound by solid state reaction using mechanical milling have been performed. The raw materials were BaCO{sub 3}, SrCO{sub 3}, Fe{sub 2}O{sub 3}, MnCO{sub 3}, and TiO{sub 2}. The mixed powder was compacted and sintered at 1000°C for 5 hours. X-ray diffraction studies indicate expansion of hexagonal unit cell and compression of atomic density with substitution of Mn{sup 2+} and Ti{sup 4+} ions. Effect of substitution upon magnetic properties revealed that total magnetization, remanence, and coercivity changed with substitution due to preferential site occupancy of substituted Mn{sup 2+} and Ti{sup 4+} ions. Since the coercivity and total magnetization may be controlled by substitution while maintaining resistive properties, this material is useful for microwave absorber.
- OSTI ID:
- 22591137
- Journal Information:
- AIP Conference Proceedings, Journal Name: AIP Conference Proceedings Journal Issue: 1 Vol. 1725; ISSN APCPCS; ISSN 0094-243X
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
BARIUM CARBONATES
COERCIVE FORCE
HEXAGONAL LATTICES
IRON OXIDES
MAGNETIC PROPERTIES
MAGNETIZATION
MANGANATES
MANGANESE CARBONATES
MANGANESE IONS
MICROWAVE RADIATION
POWDERS
RAW MATERIALS
REFLECTION
SOLIDS
STRONTIUM CARBONATES
SYNTHESIS
TITANATES
TITANIUM IONS
TITANIUM OXIDES
X-RAY DIFFRACTION