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Differences between direct current and alternating current capacitance nonlinearities in high-k dielectrics and their relation to hopping conduction

Journal Article · · Journal of Applied Physics
DOI:https://doi.org/10.1063/1.4893583· OSTI ID:22314682
;  [1]; ;  [1];  [2];  [3]
  1. Univ. Grenoble Alpes, LTM, F-38000 Grenoble (France)
  2. Univ. Grenoble Alpes, G2ELAB, F-38000 Grenoble (France)
  3. El Manar University, LMOP, 2092 Tunis (Tunisia)

Capacitance nonlinearities were studied in atomic layer deposited HfO{sub 2} films using two types of signals: a pure ac voltage of large magnitude (ac nonlinearities) and a small ac voltage superimposed to a large dc voltage (dc nonlinearities). In theory, ac and dc nonlinearities should be of the same order of magnitude. However, in practice, ac nonlinearities are found to be an order of magnitude higher than dc nonlinearities. Besides capacitance nonlinearities, hopping conduction is studied using low-frequency impedance measurements and is discussed through the correlated barrier hopping model. The link between hopping and nonlinearity is established. The ac nonlinearities are ascribed to the polarization of isolated defect pairs, while dc nonlinearities are attributed to electrode polarization which originates from defect percolation paths. Both the ac and dc capacitance nonlinearities display an exponential variation with voltage, which results from field-induced lowering of the hopping barrier energy.

OSTI ID:
22314682
Journal Information:
Journal of Applied Physics, Journal Name: Journal of Applied Physics Journal Issue: 8 Vol. 116; ISSN JAPIAU; ISSN 0021-8979
Country of Publication:
United States
Language:
English

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