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Title: Growth-induced non-planar magnetic anisotropy in FeCoZr-CaF{sub 2} nanogranular films: Structural and magnetic characterization

Abstract

The relation between nanoscale structure, local atomic order and magnetic properties of (FeCoZr){sub x}(CaF{sub 2}){sub 100−x} (29 ≤ x ≤ 73 at. %) granular films is studied as a function of metal/insulator fraction ratio. The films of a thickness of 1–6 μm were deposited on Al-foils and glass-ceramic substrates, by ion sputtering of targets of different metal/insulator contents. Structural characterization with X-ray and electron diffraction as well as transmission electron microscopy revealed that the films are composed of isolated nanocrystalline bcc α-FeCo(Zr) alloy and insulating fcc CaF{sub 2} matrix. They grow in a columnar structure, where elongated metallic nanograins are arranged on top of each other within the columns almost normal to the substrate surface. Mössbauer spectroscopy and magnetometry results indicate that their easy magnetization axes are oriented at an angle of 65°–74° to the surface in films with x between 46 and 74, above the electrical percolation threshold, which is attributed to the growth-induced shape anisotropy. Interatomic distances characteristic for metallic state of α-FeCo(Zr) nanograins were revealed by X-ray Absorption Spectroscopy. The results show a lack of surface oxidation of the alloy nanograins, so the growth-induced orientation of nanograins in the films cannot be attributed to this effect. The study is among the first tomore » report a growth-induced non-planar magnetic anisotropy in metal/insulator granular films above the percolation threshold and to reveal the origin of it.« less

Authors:
;  [1]; ; ; ;  [2];  [3];  [3];  [4]
  1. NC PHEP Belarusian State University, 220040 Minsk (Belarus)
  2. Department of Solid State Physics, Faculty of Physics and Applied Computer Science, AGH University of Science and Technology, al. Mickiewicza 30, 30-059 Krakow (Poland)
  3. VINČA Institute of Nuclear Sciences, Belgrade University, P.O. Box 522, 11001 Belgrade (Serbia)
  4. (United Kingdom)
Publication Date:
OSTI Identifier:
22308550
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Applied Physics; Journal Volume: 116; Journal Issue: 4; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; ABSORPTION SPECTROSCOPY; ANISOTROPY; BCC LATTICES; CALCIUM FLUORIDES; CERAMICS; COBALT COMPOUNDS; CRYSTALS; ELECTRON DIFFRACTION; FCC LATTICES; IRON COMPOUNDS; MAGNETIC PROPERTIES; MAGNETIZATION; NANOSTRUCTURES; SUBSTRATES; SURFACES; TERNARY ALLOY SYSTEMS; TRANSMISSION ELECTRON MICROSCOPY; X RADIATION; X-RAY SPECTROSCOPY; ZIRCONIUM COMPOUNDS

Citation Formats

Kasiuk, J. V., Fedotova, J. A., Przewoznik, J., E-mail: januszp@agh.edu.pl, Zukrowski, J., Sikora, M., Kapusta, Cz., Grce, A., Milosavljević, M., and Advanced Technology Institute, Faculty of Engineering and Physical Sciences, University of Surrey, Guildford, Surrey GU2 7XH. Growth-induced non-planar magnetic anisotropy in FeCoZr-CaF{sub 2} nanogranular films: Structural and magnetic characterization. United States: N. p., 2014. Web. doi:10.1063/1.4891016.
Kasiuk, J. V., Fedotova, J. A., Przewoznik, J., E-mail: januszp@agh.edu.pl, Zukrowski, J., Sikora, M., Kapusta, Cz., Grce, A., Milosavljević, M., & Advanced Technology Institute, Faculty of Engineering and Physical Sciences, University of Surrey, Guildford, Surrey GU2 7XH. Growth-induced non-planar magnetic anisotropy in FeCoZr-CaF{sub 2} nanogranular films: Structural and magnetic characterization. United States. doi:10.1063/1.4891016.
Kasiuk, J. V., Fedotova, J. A., Przewoznik, J., E-mail: januszp@agh.edu.pl, Zukrowski, J., Sikora, M., Kapusta, Cz., Grce, A., Milosavljević, M., and Advanced Technology Institute, Faculty of Engineering and Physical Sciences, University of Surrey, Guildford, Surrey GU2 7XH. Mon . "Growth-induced non-planar magnetic anisotropy in FeCoZr-CaF{sub 2} nanogranular films: Structural and magnetic characterization". United States. doi:10.1063/1.4891016.
@article{osti_22308550,
title = {Growth-induced non-planar magnetic anisotropy in FeCoZr-CaF{sub 2} nanogranular films: Structural and magnetic characterization},
author = {Kasiuk, J. V. and Fedotova, J. A. and Przewoznik, J., E-mail: januszp@agh.edu.pl and Zukrowski, J. and Sikora, M. and Kapusta, Cz. and Grce, A. and Milosavljević, M. and Advanced Technology Institute, Faculty of Engineering and Physical Sciences, University of Surrey, Guildford, Surrey GU2 7XH},
abstractNote = {The relation between nanoscale structure, local atomic order and magnetic properties of (FeCoZr){sub x}(CaF{sub 2}){sub 100−x} (29 ≤ x ≤ 73 at. %) granular films is studied as a function of metal/insulator fraction ratio. The films of a thickness of 1–6 μm were deposited on Al-foils and glass-ceramic substrates, by ion sputtering of targets of different metal/insulator contents. Structural characterization with X-ray and electron diffraction as well as transmission electron microscopy revealed that the films are composed of isolated nanocrystalline bcc α-FeCo(Zr) alloy and insulating fcc CaF{sub 2} matrix. They grow in a columnar structure, where elongated metallic nanograins are arranged on top of each other within the columns almost normal to the substrate surface. Mössbauer spectroscopy and magnetometry results indicate that their easy magnetization axes are oriented at an angle of 65°–74° to the surface in films with x between 46 and 74, above the electrical percolation threshold, which is attributed to the growth-induced shape anisotropy. Interatomic distances characteristic for metallic state of α-FeCo(Zr) nanograins were revealed by X-ray Absorption Spectroscopy. The results show a lack of surface oxidation of the alloy nanograins, so the growth-induced orientation of nanograins in the films cannot be attributed to this effect. The study is among the first to report a growth-induced non-planar magnetic anisotropy in metal/insulator granular films above the percolation threshold and to reveal the origin of it.},
doi = {10.1063/1.4891016},
journal = {Journal of Applied Physics},
number = 4,
volume = 116,
place = {United States},
year = {Mon Jul 28 00:00:00 EDT 2014},
month = {Mon Jul 28 00:00:00 EDT 2014}
}