Optical tags comprising rare earth metal-organic frameworks

Sava Gallis, Dorina F.; Butler, Kimberly; Rohwer, Lauren E. S.

Optical tags comprising rare earth metal-organic frameworks

Patent · Tue Sep 26 04:00:00 EDT 2023

OSTI ID:2222361

Sava Gallis, Dorina F.; Butler, Kimberly; Rohwer, Lauren E. S.

Optical tags provide a way to identify assets quickly and unambiguously, an application relevant to anti-counterfeiting and protection of valuable resources or information. The present invention is directed to a tag fluorophore that encodes multilayer complexity in a family of heterometallic rare-earth metal-organic frameworks (RE-MOFs) based on highly connected polynuclear clusters and carboxylic acid-based linkers. Both overt (visible) and covert (near infrared, NIR) properties with concomitant multi-emissive spectra and tunable luminescence lifetimes impart both intricacy and security. Tag authentication can be validated with a variety of orthogonal detection methodologies. The relationships between structure, composition, and optical properties of the family of RE-MOFs can be used to create a large library of rationally designed, highly complex, difficult to counterfeit optical tags.

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Research Organization:: Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

DOE Contract Number:: NA0003525

Assignee:: National Technology & Engineering Solutions of Sandia, LLC (Albuquerque, NM)

Patent Number(s):: 11,767,468

Application Number:: 17/479,710

OSTI ID:: 2222361

Country of Publication:: United States

Language:: English

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