Encoding Multilayer Complexity in Anti‐Counterfeiting Heterometallic MOF‐Based Optical Tags

Deneff, Jacob I.; Butler, Kimberly S.; Rohwer, Lauren E. S.; Pearce, Charles J.; Valdez, Nichole R.; Rodriguez, Mark A.; Luk, Ting S.; Sava Gallis, Dorina F.

doi:10.1002/ange.202013012

Encoding Multilayer Complexity in Anti‐Counterfeiting Heterometallic MOF‐Based Optical Tags

Journal Article · Mon Dec 14 00:00:00 EST 2020 · Angewandte Chemie

DOI:https://doi.org/10.1002/ange.202013012· OSTI ID:1786177

Deneff, Jacob I. ^[1]; ^[2]; Rohwer, Lauren E. S. ^[3]; ^[1]; Valdez, Nichole R. ^[4]; Rodriguez, Mark A. ^[4]; Luk, Ting S. ^[5]; ^[1]

Nanoscale Sciences Department Sandia National Laboratories Albuquerque NM 87185 USA
Molecular and Microbiology Department Sandia National Laboratories Albuquerque NM 87185 USA
Microsystems Integration Department Sandia National Laboratories Albuquerque NM 87185 USA
Materials Characterization and Performance Department Sandia National Laboratories Albuquerque NM 87185 USA
Nanostructure Physics Department Sandia National Laboratories Albuquerque NM 87185 USA

Abstract

Optical tags provide a way to quickly and unambiguously identify valuable assets. Current tag fluorophore options lack the tunability to allow combined methods of encoding in a single material. Herein we report a design strategy to encode multilayer complexity in a family of heterometallic rare‐earth metal–organic frameworks based on highly connected nonanuclear clusters. To impart both intricacy and security, a synergistic approach was implemented resulting in both overt (visible) and covert (near‐infrared, NIR) properties, with concomitant multi‐emissive spectra and tunable luminescence lifetimes. Tag authentication is validated with a variety of orthogonal detection methodologies. Importantly, the effect induced by subtle compositional changes on intermetallic energy transfer, and thus on the resulting photophysical properties, is demonstrated. This strategy can be widely implemented to create a large library of highly complex, difficult‐to‐counterfeit optical tags.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

OSTI ID:: 1786177

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Journal Issue: 3 Vol. 133; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

References (54)

Tuning the Dual Emission of Photon-Upconverting Nanoparticles for Ratiometric Multiplexed Encoding Gorris, Hans H.; Ali, Reham; Saleh, Sayed M. Advanced Materials, Vol. 23, Issue 14 https://doi.org/10.1002/adma.201004697	journal	February 2011
Optical Nanomaterials and Enabling Technologies for High‐Security‐Level Anticounterfeiting Ren, Wei; Lin, Gungun; Clarke, Christian Advanced Materials https://doi.org/10.1002/adma.201901430	journal	June 2019
Triple-Mode Emission of Carbon Dots: Applications for Advanced Anti-Counterfeiting Jiang, Kai; Zhang, Ling; Lu, Junfeng Angewandte Chemie, Vol. 128, Issue 25 https://doi.org/10.1002/ange.201602445	journal	May 2016
Mixed‐Metal MOFs: Unique Opportunities in Metal–Organic Framework (MOF) Functionality and Design Masoomi, Mohammad Yaser; Morsali, Ali; Dhakshinamoorthy, Amarajothi Angewandte Chemie, Vol. 131, Issue 43 https://doi.org/10.1002/ange.201902229	journal	October 2019
Heteroepitaxial Growth of Multiblock Ln‐MOF Microrods for Photonic Barcodes Yao, Yinan; Gao, Zhenhua; Lv, Yuanchao Angewandte Chemie, Vol. 131, Issue 39 https://doi.org/10.1002/ange.201907433	journal	July 2019
Loading Photochromic Molecules into a Luminescent Metal–Organic Framework for Information Anticounterfeiting Li, Zhiqiang; Wang, Guannan; Ye, Yingxiang Angewandte Chemie, Vol. 131, Issue 50 https://doi.org/10.1002/ange.201910467	journal	October 2019
Spatially Responsive Multicolor Lanthanide‐MOF Heterostructures for Covert Photonic Barcodes Gao, Zhenhua; Xu, Baoyuan; Zhang, Tongjin Angewandte Chemie, Vol. 132, Issue 43 https://doi.org/10.1002/ange.202009295	journal	August 2020
Triple-Mode Emission of Carbon Dots: Applications for Advanced Anti-Counterfeiting Jiang, Kai; Zhang, Ling; Lu, Junfeng Angewandte Chemie International Edition, Vol. 55, Issue 25 https://doi.org/10.1002/anie.201602445	journal	May 2016
Mixed‐Metal MOFs: Unique Opportunities in Metal–Organic Framework (MOF) Functionality and Design Masoomi, Mohammad Yaser; Morsali, Ali; Dhakshinamoorthy, Amarajothi Angewandte Chemie International Edition, Vol. 58, Issue 43 https://doi.org/10.1002/anie.201902229	journal	October 2019
Heteroepitaxial Growth of Multiblock Ln‐MOF Microrods for Photonic Barcodes Yao, Yinan; Gao, Zhenhua; Lv, Yuanchao Angewandte Chemie International Edition, Vol. 58, Issue 39 https://doi.org/10.1002/anie.201907433	journal	September 2019
Loading Photochromic Molecules into a Luminescent Metal–Organic Framework for Information Anticounterfeiting Li, Zhiqiang; Wang, Guannan; Ye, Yingxiang Angewandte Chemie International Edition, Vol. 58, Issue 50 https://doi.org/10.1002/anie.201910467	journal	December 2019
Spatially Responsive Multicolor Lanthanide‐MOF Heterostructures for Covert Photonic Barcodes Gao, Zhenhua; Xu, Baoyuan; Zhang, Tongjin Angewandte Chemie International Edition, Vol. 59, Issue 43 https://doi.org/10.1002/anie.202009295	journal	August 2020
Electronic, Structural and Functional Versatility in Tetrathiafulvalene‐Lanthanide Metal–Organic Frameworks Castells‐Gil, Javier; Mañas‐Valero, Samuel; Vitórica‐Yrezábal, Iñigo J. Chemistry – A European Journal, Vol. 25, Issue 54 https://doi.org/10.1002/chem.201902855	journal	August 2019
Two Series of Lanthanide Coordinated Compounds and Novel Three-Component Near-White Light Emission Xin, Ling-yun; Ju, Feng-yang; Li, Yun-ping Journal of Inorganic and Organometallic Polymers and Materials, Vol. 30, Issue 5 https://doi.org/10.1007/s10904-019-01396-6	journal	November 2019
Design of luminescent lanthanide complexes: From molecules to highly efficient photo-emitting materials Armelao, L.; Quici, S.; Barigelletti, F. Coordination Chemistry Reviews, Vol. 254, Issue 5-6 https://doi.org/10.1016/j.ccr.2009.07.025	journal	March 2010
Reticular chemistry in the rational synthesis of functional zirconium cluster-based MOFs Chen, Zhijie; Hanna, Sylvia L.; Redfern, Louis R. Coordination Chemistry Reviews, Vol. 386 https://doi.org/10.1016/j.ccr.2019.01.017	journal	May 2019
Color tunable carbon quantum dots from wasted paper by different solvents for anti-counterfeiting and fluorescent flexible film Park, Sung Jun; Park, Jin Young; Chung, Jong Won Chemical Engineering Journal, Vol. 383 https://doi.org/10.1016/j.cej.2019.123200	journal	March 2020
The syntheses, structures, magnetic and luminescent properties of five new lanthanide(III) complexes based on tetrazole 1-acetic ligand Lu, Ying-Bing; Wang, Shui-Hu; Zhu, Shui-Dong Inorganic Chemistry Communications, Vol. 111 https://doi.org/10.1016/j.inoche.2019.107667	journal	January 2020
A 1-D model of the photoluminescent decay of ZnS phosphors as a function of excitation conditions Martin, James E.; Shea-Rohwer, Lauren E. Journal of Luminescence, Vol. 128, Issue 9 https://doi.org/10.1016/j.jlumin.2008.01.019	journal	September 2008
Fluorescence Lifetime Standards for Time and Frequency Domain Fluorescence Spectroscopy Boens, Noël; Qin, Wenwu; Basarić, Nikola Analytical Chemistry, Vol. 79, Issue 5 https://doi.org/10.1021/ac062160k	journal	March 2007
A Long Journey in Lanthanide Chemistry: From Fundamental Crystallogenesis Studies to Commercial Anticounterfeiting Taggants Guillou, Olivier; Daiguebonne, Carole; Calvez, Guillaume Accounts of Chemical Research, Vol. 49, Issue 5 https://doi.org/10.1021/acs.accounts.6b00058	journal	April 2016
Yb-Based Nanoparticles with the Same Excitation and Emission Wavelength for Sensitive in Vivo Biodetection Wu, Na; Gu, Yuyang; Kong, Mengya Analytical Chemistry, Vol. 92, Issue 2 https://doi.org/10.1021/acs.analchem.9b04448	journal	December 2019
Photophysics Modulation in Photoswitchable Metal–Organic Frameworks Rice, Allison M.; Martin, Corey R.; Galitskiy, Vladimir A. Chemical Reviews https://doi.org/10.1021/acs.chemrev.9b00350	journal	October 2019
Multi-Emissive Lanthanide-Based Coordination Polymers for Potential Application as Luminescent Bar-Codes Wang, Jinzeng; Suffren, Yan; Daiguebonne, Carole Inorganic Chemistry, Vol. 58, Issue 4 https://doi.org/10.1021/acs.inorgchem.8b03277	journal	February 2019
Defect and Linker Effects on the Binding of Organophosphorous Compounds in UiO-66 and Rare-Earth MOFs Harvey, Jacob A.; Greathouse, Jeffery A.; Sava Gallis, Dorina F. The Journal of Physical Chemistry C, Vol. 122, Issue 47 https://doi.org/10.1021/acs.jpcc.8b06198	journal	November 2018
Antibody Targeted Metal–Organic Frameworks for Bioimaging Applications Butler, Kimberly S.; Pearce, Charles J.; Nail, Elizabeth A. ACS Applied Materials & Interfaces, Vol. 12, Issue 28 https://doi.org/10.1021/acsami.0c07835	journal	June 2020
Multifunctional, Tunable Metal–Organic Framework Materials Platform for Bioimaging Applications Sava Gallis, Dorina F.; Rohwer, Lauren E. S.; Rodriguez, Mark A. ACS Applied Materials & Interfaces, Vol. 9, Issue 27 https://doi.org/10.1021/acsami.7b05859	journal	June 2017
Carbon Dot Fluorescence-Lifetime-Encoded Anti-Counterfeiting Kalytchuk, Sergii; Wang, Yu; Poláková, Kateřina ACS Applied Materials & Interfaces, Vol. 10, Issue 35 https://doi.org/10.1021/acsami.8b11663	journal	August 2018
NO _x Adsorption and Optical Detection in Rare Earth Metal–Organic Frameworks Sava Gallis, Dorina F.; Vogel, Dayton J.; Vincent, Grace A. ACS Applied Materials & Interfaces, Vol. 11, Issue 46 https://doi.org/10.1021/acsami.9b16470	journal	October 2019
Luminescent Supraparticles Based on CaF ₂ –Nanoparticle Building Blocks as Code Objects with Unique IDs Miller, Franziska; Wintzheimer, Susanne; Reuter, Tim ACS Applied Nano Materials, Vol. 3, Issue 1 https://doi.org/10.1021/acsanm.9b02245	journal	December 2019
Heterometallic Metal–Organic Frameworks (MOFs): The Advent of Improving the Energy Landscape Rice, Allison M.; Leith, Gabrielle A.; Ejegbavwo, Otega A. ACS Energy Letters, Vol. 4, Issue 8 https://doi.org/10.1021/acsenergylett.9b00874	journal	July 2019
From Antenna to Assay: Lessons Learned in Lanthanide Luminescence Moore, Evan G.; Samuel, Amanda P. S.; Raymond, Kenneth N. Accounts of Chemical Research, Vol. 42, Issue 4 https://doi.org/10.1021/ar800211j	journal	April 2009
Efficient Photoluminescence via Metal–Ligand Alteration in a New MOFs Family Sava Gallis, Dorina F.; Rohwer, Lauren E. S.; Rodriguez, Mark A. Chemistry of Materials, Vol. 26, Issue 9, p. 2943-2951 https://doi.org/10.1021/cm500700z	journal	April 2014
Luminescent Functional Metal–Organic Frameworks Cui, Yuanjing; Yue, Yanfeng; Qian, Guodong Chemical Reviews, Vol. 112, Issue 2 https://doi.org/10.1021/cr200101d	journal	June 2011
Tunable Rare-Earth fcu-MOFs: A Platform for Systematic Enhancement of CO₂ Adsorption Energetics and Uptake Xue, Dong-Xu; Cairns, Amy J.; Belmabkhout, Youssef Journal of the American Chemical Society, Vol. 135, Issue 20, p. 7660-7667 https://doi.org/10.1021/ja401429x	journal	May 2013
Near-Infrared Luminescent Lanthanide MOF Barcodes White, Kiley A.; Chengelis, Demetra A.; Gogick, Kristy A. Journal of the American Chemical Society, Vol. 131, Issue 50 https://doi.org/10.1021/ja907885m	journal	December 2009
Quest for Highly Connected Metal–Organic Framework Platforms: Rare-Earth Polynuclear Clusters Versatility Meets Net Topology Needs Alezi, Dalal; Peedikakkal, Abdul Malik P.; Weseliński, Łukasz J. Journal of the American Chemical Society, Vol. 137, Issue 16 https://doi.org/10.1021/jacs.5b00450	journal	April 2015
A Fine-Tuned Metal–Organic Framework for Autonomous Indoor Moisture Control AbdulHalim, Rasha G.; Bhatt, Prashant M.; Belmabkhout, Youssef Journal of the American Chemical Society, Vol. 139, Issue 31 https://doi.org/10.1021/jacs.7b04132	journal	July 2017
Discovery and introduction of a (3,18)-connected net as an ideal blueprint for the design of metal–organic frameworks Guillerm, Vincent; Weseliński, Łukasz J.; Belmabkhout, Youssef Nature Chemistry, Vol. 6, Issue 8 https://doi.org/10.1038/nchem.1982	journal	June 2014
Luminescent multifunctional lanthanides-based metal–organic frameworks Rocha, João; Carlos, Luís D.; Paz, Filipe A. Almeida Chem. Soc. Rev., Vol. 40, Issue 2 https://doi.org/10.1039/C0CS00130A	journal	January 2011
Programmable microfluidic synthesis of spectrally encoded microspheres Gerver, R. E.; Gómez-Sjöberg, R.; Baxter, B. C. Lab Chip, Vol. 12, Issue 22 https://doi.org/10.1039/C2LC40699C	journal	January 2012
Luminescent metal–organic frameworks for chemical sensing and explosive detection Hu, Zhichao; Deibert, Benjamin J.; Li, Jing Chem. Soc. Rev., Vol. 43, Issue 16 https://doi.org/10.1039/C4CS00010B	journal	January 2014
Efficient MOF-based degradation of organophosphorus compounds in non-aqueous environments Sava Gallis, Dorina F.; Harvey, Jacob A.; Pearce, Charles J. Journal of Materials Chemistry A, Vol. 6, Issue 7 https://doi.org/10.1039/C7TA10794C	journal	January 2018
Biocompatible MOFs with high absolute quantum yield for bioimaging in the second near infrared window Sava Gallis, Dorina F.; Butler, Kimberly S.; Rohwer, Lauren E. S. CrystEngComm, Vol. 20, Issue 39 https://doi.org/10.1039/C8CE00909K	journal	January 2018
Mixed-metal metal–organic frameworks Abednatanzi, Sara; Gohari Derakhshandeh, Parviz; Depauw, Hannes Chemical Society Reviews, Vol. 48, Issue 9 https://doi.org/10.1039/C8CS00337H	journal	January 2019
Blue, green, and red full-color ultralong afterglow in nitrogen-doped carbon dots Lin, Cunjian; Zhuang, Yixi; Li, Wuhui Nanoscale, Vol. 11, Issue 14 https://doi.org/10.1039/C8NR09672D	journal	January 2019
Structure and electronic properties of rare earth DOBDC metal–organic-frameworks Vogel, Dayton J.; Sava Gallis, Dorina F.; Nenoff, Tina M. Physical Chemistry Chemical Physics, Vol. 21, Issue 41 https://doi.org/10.1039/C9CP04038B	journal	January 2019
Taking advantage of luminescent lanthanide ions Bünzli, Jean-Claude G.; Piguet, Claude Chemical Society Reviews, Vol. 34, Issue 12 https://doi.org/10.1039/b406082m	journal	January 2005
Lanthanide-chelate silica nanospheres as robust multicolor Vis-NIR tags Samuel, Jorice; Tallec, Gaylord; Cherns, Peter Chemical Communications, Vol. 46, Issue 15 https://doi.org/10.1039/b926031e	journal	January 2010
Multicolor upconverted luminescence-encoded superparticles via controlling self-assembly based on hydrophobic lanthanide-doped NaYF4 nanocrystals Zhang, Qingbin; Wang, Xin; Zhu, Yimin Journal of Materials Chemistry, Vol. 21, Issue 32 https://doi.org/10.1039/c1jm10350d	journal	January 2011
A facile building-block synthesis of multifunctional lanthanide MOFs Tanase, Stefania; Mittelmeijer-Hazeleger, Marjo C.; Rothenberg, Gadi Journal of Materials Chemistry, Vol. 21, Issue 39 https://doi.org/10.1039/c1jm12789f	journal	January 2011
Designing lanthanide-doped nanocrystals with both up- and down-conversion luminescence for anti-counterfeiting Liu, Yanlan; Ai, Kelong; Lu, Lehui Nanoscale, Vol. 3, Issue 11 https://doi.org/10.1039/c1nr10752f	journal	January 2011
Luminescence Decay by Energy Migration and Transfer: Observation of Diffusion-Limited Relaxation Weber, Marvin J. Physical Review B, Vol. 4, Issue 9 https://doi.org/10.1103/PhysRevB.4.2932	journal	November 1971
The Chemistry and Applications of Metal-Organic Frameworks Furukawa, H.; Cordova, K. E.; O'Keeffe, M. Science, Vol. 341, Issue 6149, p. 1230444-1230444 https://doi.org/10.1126/science.1230444	journal	August 2013

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