Solid-state crystallization of metal organic frameworks within mesoporous materials methods and hybrid materials thereof

Minguez, Ignacio Luz; Soukri, Mustapha; Lail, Marty

Solid-state crystallization of metal organic frameworks within mesoporous materials methods and hybrid materials thereof

Patent · Tue Sep 26 00:00:00 EDT 2023

OSTI ID:2222359

Minguez, Ignacio Luz; Soukri, Mustapha; Lail, Marty

A method, comprising i) contacting an aqueous solution of an organic ligand salt of the formula A_X(L^−X) with a mesoporous material (MPM) to form an impregnated mesoporous salt material of the formula A_X(L^−X)/MPM, ii) treating the impregnated mesoporous salt material with an aqueous acidic solution to form an impregnated mesoporous acid material of the formula H_X(L^−X)/MPM, iii) contacting an aqueous solution of a metal precursor of the formula M^+y(B)y with the impregnated mesoporous acid material to form an impregnated mesoporous metal organic framework precursor of the formula [M^+y(B)_y][H_x(L^−x)]/MPM, and iv) at least one of 1) heating the impregnated mesoporous metal organic framework precursor in the absence of a solvent or 2) exposing the impregnated mesoporous metal organic framework precursor to a volatile vapor in the absence of a solvent such that the heating or the exposing forms a hybrid material of the formula (M^+yL^−x)/MPM, wherein the hybrid material comprises a nano-crystalline metal organic framework (MOF) embedded within the mesoporous material.

View Patent

Research Organization:: RTI International, Research Triangle Park, NC (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: FE0026432

Assignee:: Research Triangle Institute (Research Triangle Park, NC)

Patent Number(s):: 11,767,225

Application Number:: 16/324,296

OSTI ID:: 2222359

Country of Publication:: United States

Language:: English

References (60)

An In Situ High-Temperature Single-Crystal Investigation of a Dehydrated Metal-Organic Framework Compound and Field-Induced Magnetization of One-Dimensional Metal-Oxygen Chains Dietzel, Pascal D. C.; Morita, Yusuke; Blom, Richard Angewandte Chemie International Edition, Vol. 44, Issue 39, p. 6354-6358 https://doi.org/10.1002/anie.200501508	journal	October 2005
Zirconium-Metalloporphyrin PCN-222: Mesoporous Metal-Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts Feng, Dawei; Gu, Zhi-Yuan; Li, Jian-Rong Angewandte Chemie International Edition, Vol. 51, Issue 41 https://doi.org/10.1002/anie.201204475	journal	August 2012
Multifunctional, Defect-Engineered Metal-Organic Frameworks with Ruthenium Centers: Sorption and Catalytic Properties Kozachuk, Olesia; Luz, Ignacio; Llabrés i. Xamena, Francesc X. Angewandte Chemie International Edition, Vol. 53, Issue 27 https://doi.org/10.1002/anie.201311128	journal	May 2014
The Direct Catalytic Oxidation of Methane to Methanol-A Critical Assessment Ravi, Manoj; Ranocchiari, Marco; van Bokhoven, Jeroen A. Angewandte Chemie International Edition, Vol. 56, Issue 52 https://doi.org/10.1002/anie.201702550	journal	November 2017
Boosting the Catalytic Performance of Metal-Organic Frameworks for Steroid Transformations by Confinement within a Mesoporous Scaffold Cirujano, Francisco G.; Luz, Ignacio; Soukri, Mustapha Angewandte Chemie International Edition, Vol. 56, Issue 43 https://doi.org/10.1002/anie.201706721	journal	September 2017
Catalytic converters: state of the art and perspectives Farrauto, Robert J.; Heck, Ronald M. Catalysis Today, Vol. 51, Issue 3-4 https://doi.org/10.1016/S0920-5861(99)00024-3	journal	July 1999
Applications of metal–organic coordination polymers as precursors for preparation of nano-materials Masoomi, Mohammad Yaser; Morsali, Ali Coordination Chemistry Reviews, Vol. 256, Issue 23-24 https://doi.org/10.1016/j.ccr.2012.05.032	journal	December 2012
Low temperature dry methane reforming over Ce, Zr and CeZr promoted Ni–Mg–Al hydrotalcite-derived catalysts Dębek, Radosław; Galvez, Maria Elena; Launay, Franck International Journal of Hydrogen Energy, Vol. 41, Issue 27 https://doi.org/10.1016/j.ijhydene.2016.02.074	journal	July 2016
Gold(III) – metal organic framework bridges the gap between homogeneous and heterogeneous gold catalysts Zhang, X.; Llabrés i. Xamena, F. X.; Corma, A. Journal of Catalysis, Vol. 265, Issue 2 https://doi.org/10.1016/j.jcat.2009.04.021	journal	July 2009
New insight into mesoporous silica for nano metal–organic framework Kondo, Atsushi; Takanashi, Shinji; Maeda, Kazuyuki Journal of Colloid and Interface Science, Vol. 384, Issue 1 https://doi.org/10.1016/j.jcis.2012.06.040	journal	October 2012
Synthesis of continuous MOF-5 membranes on porous α-alumina substrates Liu, Yunyang; Ng, Zhenfu; Khan, Easir A. Microporous and Mesoporous Materials, Vol. 118, Issue 1-3, p. 296-301 https://doi.org/10.1016/j.micromeso.2008.08.054	journal	February 2009
Solvent effect on the synthesis of MIL-96(Cr) and MIL-100(Cr) Long, Peipei; Wu, Huawei; Zhao, Qiang Microporous and Mesoporous Materials, Vol. 142, Issue 2-3 https://doi.org/10.1016/j.micromeso.2010.12.036	journal	July 2011
Synthesis and gas adsorption properties of mesoporous silica-NH2-MIL-53(Al) core–shell spheres Sorribas, Sara; Zornoza, Beatriz; Serra-Crespo, Pablo Microporous and Mesoporous Materials, Vol. 225 https://doi.org/10.1016/j.micromeso.2015.12.004	journal	May 2016
Liquid Organic Hydrogen Carriers (LOHCs): Toward a Hydrogen-free Hydrogen Economy Preuster, Patrick; Papp, Christian; Wasserscheid, Peter Accounts of Chemical Research, Vol. 50, Issue 1 https://doi.org/10.1021/acs.accounts.6b00474	journal	December 2016
Transformation of Metal–Organic Frameworks/Coordination Polymers into Functional Nanostructured Materials: Experimental Approaches Based on Mechanistic Insights Lee, Kyung Joo; Lee, Jae Hwa; Jeoung, Sungeun Accounts of Chemical Research, Vol. 50, Issue 11 https://doi.org/10.1021/acs.accounts.7b00259	journal	October 2017
Confining Metal–Organic Framework Nanocrystals within Mesoporous Materials: A General Approach via “Solid-State” Synthesis Luz, Ignacio; Soukri, Mustapha; Lail, Marty Chemistry of Materials, Vol. 29, Issue 22 https://doi.org/10.1021/acs.chemmater.7b02042	journal	August 2017
Immobilization of Metal–Organic Framework Nanocrystals for Advanced Design of Supported Nanocatalysts Li, Ping; Zeng, Hua Chun ACS Applied Materials & Interfaces, Vol. 8, Issue 43 https://doi.org/10.1021/acsami.6b11775	journal	October 2016
Elucidating the Nature of Fe Species during Pyrolysis of the Fe-BTC MOF into Highly Active and Stable Fischer–Tropsch Catalysts Wezendonk, Tim A.; Santos, Vera P.; Nasalevich, Maxim A. ACS Catalysis, Vol. 6, Issue 5 https://doi.org/10.1021/acscatal.6b00426	journal	April 2016
Switchable Alkene Epoxidation/Oxidative Cleavage with H ₂ O ₂ /NaHCO ₃ : Efficient Heterogeneous Catalysis Derived from Biosourced Eco-Mn Escande, Vincent; Petit, Eddy; Garoux, Laetitia ACS Sustainable Chemistry & Engineering, Vol. 3, Issue 11 https://doi.org/10.1021/acssuschemeng.5b00561	journal	October 2015
Nanoscale Metal–Organic Frameworks for Biomedical Imaging and Drug Delivery Della Rocca, Joseph; Liu, Demin; Lin, Wenbin Accounts of Chemical Research, Vol. 44, Issue 10, p. 957-968 https://doi.org/10.1021/ar200028a	journal	October 2011
Using Functional Nano- and Microparticles for the Preparation of Metal–Organic Framework Composites with Novel Properties Doherty, Cara M.; Buso, Dario; Hill, Anita J. Accounts of Chemical Research, Vol. 47, Issue 2 https://doi.org/10.1021/ar400130a	journal	November 2013
Synthesis and Stability of Tagged UiO-66 Zr-MOFs Kandiah, Mathivathani; Nilsen, Merete Hellner; Usseglio, Sandro Chemistry of Materials, Vol. 22, Issue 24 https://doi.org/10.1021/cm102601v	journal	December 2010
Rapid Room-Temperature Synthesis and Characterization of Nanocrystals of a Prototypical Zeolitic Imidazolate Framework Cravillon, Janosch; Münzer, Simon; Lohmeier, Sven-Jare Chemistry of Materials, Vol. 21, Issue 8 https://doi.org/10.1021/cm900166h	journal	April 2009
Synthesis, Single-Crystal X-ray Microdiffraction, and NMR Characterizations of the Giant Pore Metal-Organic Framework Aluminum Trimesate MIL-100 Volkringer, Christophe; Popov, Dimitry; Loiseau, Thierry Chemistry of Materials, Vol. 21, Issue 24 https://doi.org/10.1021/cm901983a	journal	December 2009
Metal–Organic Frameworks for Separations Li, Jian-Rong; Sculley, Julian; Zhou, Hong-Cai Chemical Reviews, Vol. 112, Issue 2, p. 869-932 https://doi.org/10.1021/cr200190s	journal	September 2011
Metal–Organic Framework Materials as Chemical Sensors Kreno, Lauren E.; Leong, Kirsty; Farha, Omar K. Chemical Reviews, Vol. 112, Issue 2, p. 1105-1125 https://doi.org/10.1021/cr200324t	journal	September 2011
Carbon Dioxide Capture in Metal–Organic Frameworks Sumida, Kenji; Rogow, David L.; Mason, Jarad A. Chemical Reviews, Vol. 112, Issue 2, p. 724-781 https://doi.org/10.1021/cr2003272	journal	September 2011
Engineering Metal Organic Frameworks for Heterogeneous Catalysis Corma, A.; García, H.; Llabrés i Xamena, F. X. Chemical Reviews, Vol. 110, Issue 8, p. 4606-4655 https://doi.org/10.1021/cr9003924	journal	August 2010
Armored MOFs: Enforcing Soft Microporous MOF Nanocrystals with Hard Mesoporous Silica Li, Zheng; Zeng, Hua Chun Journal of the American Chemical Society, Vol. 136, Issue 15 https://doi.org/10.1021/ja409675j	journal	April 2014
An Amine-Functionalized MIL-53 Metal−Organic Framework with Large Separation Power for CO ₂ and CH ₄ Couck, Sarah; Denayer, Joeri F. M.; Baron, Gino V. Journal of the American Chemical Society, Vol. 131, Issue 18 https://doi.org/10.1021/ja900555r	journal	May 2009
Application of Consistency Criteria To Calculate BET Areas of Micro- And Mesoporous Metal–Organic Frameworks Gómez-Gualdrón, Diego A.; Moghadam, Peyman Z.; Hupp, Joseph T. Journal of the American Chemical Society, Vol. 138, Issue 1 https://doi.org/10.1021/jacs.5b10266	journal	December 2015
Cooperative insertion of CO2 in diamine-appended metal-organic frameworks McDonald, Thomas M.; Mason, Jarad A.; Kong, Xueqian Nature, Vol. 519, Issue 7543 https://doi.org/10.1038/nature14327	journal	March 2015
Directly converting CO2 into a gasoline fuel Wei, Jian; Ge, Qingjie; Yao, Ruwei Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15174	journal	May 2017
Using carbon dioxide as a building block in organic synthesis Liu, Qiang; Wu, Lipeng; Jackstell, Ralf Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms6933	journal	January 2015
Towards stable catalysts by controlling collective properties of supported metal nanoparticles Prieto, Gonzalo; Zečević, Jovana; Friedrich, Heiner Nature Materials, Vol. 12, Issue 1 https://doi.org/10.1038/nmat3471	journal	November 2012
Generation of subnanometric platinum with high stability during transformation of a 2D zeolite into 3D Liu, Lichen; Díaz, Urbano; Arenal, Raul Nature Materials, Vol. 16, Issue 1 https://doi.org/10.1038/nmat4757	journal	September 2016
The platinum rush de Jong, Krijn P.; Zečević, Jovana Nature Materials, Vol. 16, Issue 1 https://doi.org/10.1038/nmat4832	journal	December 2016
Bimetallic Metal-Organic Frameworks for Controlled Catalytic Graphitization of Nanoporous Carbons Tang, Jing; Salunkhe, Rahul R.; Zhang, Huabin Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep30295	journal	July 2016
Metal-Organic Framework Templated Synthesis of Ultrasmall Catalyst Loaded ZnO/ZnCo2O4 Hollow Spheres for Enhanced Gas Sensing Properties Koo, Won-Tae; Choi, Seon-Jin; Jang, Ji-Soo Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/srep45074	journal	March 2017
A robust, catalytic metal–organic framework with open 2,2′-bipyridine sites Fei, Honghan; Cohen, Seth M. Chem. Commun., Vol. 50, Issue 37 https://doi.org/10.1039/C4CC01607F	journal	January 2014
MOF-based electronic and opto-electronic devices Stavila, V.; Talin, A. A.; Allendorf, M. D. Chem. Soc. Rev., Vol. 43, Issue 16 https://doi.org/10.1039/C4CS00096J	journal	January 2014
Facile synthesis of mesoporous MOF/silica composites Yan, Xinlong; Hu, Xiaoyan; Komarneni, Sridhar RSC Adv., Vol. 4, Issue 101 https://doi.org/10.1039/C4RA09626F	journal	January 2014
Multifunctional metal–organic frameworks: from academia to industrial applications Silva, Patrícia; Vilela, Sérgio M. F.; Tomé, João P. C. Chemical Society Reviews, Vol. 44, Issue 19 https://doi.org/10.1039/C5CS00307E	journal	January 2015
Metal–organic framework composites: from fundamentals to applications Li, Shaozhou; Huo, Fengwei Nanoscale, Vol. 7, Issue 17 https://doi.org/10.1039/C5NR00518C	journal	January 2015
Ammonia synthesis over Co–Mo alloy nanoparticle catalyst prepared via sodium naphthalenide-driven reduction Tsuji, Yuki; Kitano, Masaaki; Kishida, Kazuhisa Chemical Communications, Vol. 52, Issue 100 https://doi.org/10.1039/C6CC08566K	journal	January 2016
Transformation of single MOF nanocrystals into single nanostructured catalysts within mesoporous supports: a platform for pioneer fluidized-nanoreactor hydrogen carriers Luz, Ignacio; Soukri, Mustapha; Lail, Marty Chemical Communications, Vol. 54, Issue 61 https://doi.org/10.1039/C8CC04562C	journal	January 2018
Hydrogen adsorption in a nickel based coordination polymer with open metal sites in the cylindrical cavities of the desolvated framework Dietzel, Pascal D. C.; Panella, Barbara; Hirscher, Michael Chemical Communications, Issue 9 https://doi.org/10.1039/b515434k	journal	January 2006
Mesoporous silica–metal organic composite: synthesis, characterization, and ammonia adsorption Furtado, Amanda M. B.; Liu, Jian; Wang, Yu Journal of Materials Chemistry, Vol. 21, Issue 18 https://doi.org/10.1039/c1jm10451a	journal	January 2011
Fast and high yield post-synthetic modification of metal–organic frameworks by vapor diffusion Servalli, Marco; Ranocchiari, Marco; Van Bokhoven, Jeroen A. Chemical Communications, Vol. 48, Issue 13 https://doi.org/10.1039/c2cc17461h	journal	January 2012
Facile synthesis of MOF-5 confined in SBA-15 hybrid material with enhanced hydrostability Wu, Chia-Ming; Rathi, Monika; Ahrenkiel, S. Phil Chemical Communications, Vol. 49, Issue 12 https://doi.org/10.1039/c2cc38366g	journal	January 2013
Modulated formation of metal-organic frameworks by oriented growth over mesoporous silica Karimi, Zahra; Morsali, Ali Journal of Materials Chemistry A, Vol. 1, Issue 9 https://doi.org/10.1039/c2ta01565j	journal	January 2013
Versatile functionalization of the NU-1000 platform by solvent-assisted ligand incorporation Deria, Pravas; Bury, Wojciech; Hupp, Joseph T. Chemical Communications, Vol. 50, Issue 16, p. 1965-1968 https://doi.org/10.1039/c3cc48562e	journal	January 2014
Towards acid MOFs – catalytic performance of sulfonic acid functionalized architectures Juan-Alcañiz, Jana; Gielisse, Robin; Lago, Ana B. Catalysis Science & Technology, Vol. 3, Issue 9 https://doi.org/10.1039/c3cy00272a	journal	January 2013
Mg-MOF-74@SBA-15 hybrids: Synthesis, characterization, and adsorption properties Chakraborty, Anindita; Maji, Tapas Kumar APL Materials, Vol. 2, Issue 12 https://doi.org/10.1063/1.4902816	journal	December 2014
CO ₂ methanation over Ni-Ceria-Zirconia catalysts: effect of preparation and operating conditions Ocampo, F.; Louis, B.; Kiennemann, A. IOP Conference Series: Materials Science and Engineering, Vol. 19 https://doi.org/10.1088/1757-899X/19/1/012007	journal	March 2011
A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area Ferey, G.; Mellot-Draznieks, C.; Serre, C. Science, Vol. 309, Issue 5743, p. 2040-2042 https://doi.org/10.1126/science.1116275	journal	September 2005
The Chemistry and Applications of Metal-Organic Frameworks Furukawa, H.; Cordova, K. E.; O'Keeffe, M. Science, Vol. 341, Issue 6149, p. 1230444-1230444 https://doi.org/10.1126/science.1230444	journal	August 2013
Triblock Copolymer Syntheses of Mesoporous Silica with Periodic 50 to 300 Angstrom Pores Zhao, Dongyuan; Feng, Jianglin; Huo, Qisheng Science, Vol. 279, Issue 5350, p. 548-552 https://doi.org/10.1126/science.279.5350.548	journal	January 1998
Designing Multifunctionality into Single Phase and Multiphase Metal-Oxide-Selective Propylene Ammoxidation Catalysts Brazdil, James Catalysts, Vol. 8, Issue 3 https://doi.org/10.3390/catal8030103	journal	March 2018
Ammonia as a Hydrogen Source for Fuel Cells: A Review Cheddie, Denver Hydrogen Energy - Challenges and Perspectives https://doi.org/10.5772/47759	book	October 2012

Similar Records

Catalyst Of A Metal Heteropoly Acid Salt That Is Insoluble In A Polar Solvent On A Non-Metallic Porous Support And Method Of Making

Patent · Mon Nov 08 23:00:00 EST 2004 · OSTI ID:879856

Catalyst of a metal heteropoly acid salt that is insoluble in a polar solvent on a non-metallic porous support and method of making

Patent · Mon Oct 28 23:00:00 EST 2002 · OSTI ID:874842

Co-precipitation synthesis of precursors to bismuth-containing superconductors

Patent · Mon Dec 30 23:00:00 EST 1991 · OSTI ID:5578180

Solid-state crystallization of metal organic frameworks within mesoporous materials methods and hybrid materials thereof

Citation Formats

References (60)

Similar Records

Related Subjects