Solvent–free Synthesis of Multi–Module Pore–Space–Partitioned Metal–Organic Frameworks for Gas Separation

Xiao, Yuchen; Chen, Yichong; Hong, Anh N.; Bu, Xianhui; Feng, Pingyun

doi:10.1002/anie.202300721

Solvent–free Synthesis of Multi–Module Pore–Space–Partitioned Metal–Organic Frameworks for Gas Separation

Journal Article · Mon Feb 13 00:00:00 EST 2023 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.202300721· OSTI ID:2205468

Xiao, Yuchen ^[1]; Chen, Yichong ^[2]; Hong, Anh N. ^[2]; Bu, Xianhui ^[3]; ^[2]

University of California, Riverside, CA (United States); UC Riverside
University of California, Riverside, CA (United States)
California State University Long Beach, CA (United States)

Multi-module design of framework materials with multiple distinct building blocks has attracted much attention because such materials are more amenable to compositional and geometrical tuning and thus offer more opportunities for property optimization. Few examples are known that use environmentally friendly and cost-effective solvent-free method to synthesize such materials. Here, we report the use of solvent-free method (also modulator-free) to synthesize a series of multi-module MOFs with high stability and separation property for C₂H₂/CO₂. The synthesis only requires simple mixing of reactants and short reaction time (2 h). Highly porous and stable materials can be made without any post-synthetic activation. Here, the success of solvent-free synthesis of multi-module MOFs reflects the synergy between different modules, resulting in stable pore-partitioned materials, despite the fact that other competitive crystallization pathways with simpler framework compositions also exist.

View Accepted Manuscript (DOE)

Research Organization:: University of California, Riverside, CA (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division (MSE)

Grant/Contract Number:: SC0010596

OSTI ID:: 2205468

Alternate ID(s):: OSTI ID: 1959390

Journal Information:: Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Journal Issue: 14 Vol. 62; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

References (56)

A Crystalline Mesoporous Coordination Copolymer with High Microporosity Koh, Kyoungmoo; Wong-Foy, Antek G.; Matzger, Adam J. Angewandte Chemie, Vol. 120, Issue 4, p. 689-692 https://doi.org/10.1002/ange.200705020	journal	January 2008
Multiple Functions of Ionic Liquids in the Synthesis of Three‐Dimensional Low‐Connectivity Homochiral and Achiral Frameworks Zhang, Jian; Chen, Shumei; Bu, Xianhui Angewandte Chemie, Vol. 120, Issue 29 https://doi.org/10.1002/ange.200801838	journal	July 2008
Urothermal Synthesis of Crystalline Porous Materials Zhang, Jian; Bu, Julia T.; Chen, Shumei Angewandte Chemie, Vol. 122, Issue 47 https://doi.org/10.1002/ange.201003900	journal	October 2010
Framework Cationization by Preemptive Coordination of Open Metal Sites for Anion-Exchange Encapsulation of Nucleotides and Coenzymes Zhao, Xiang; Mao, Chengyu; Luong, Karen Tu Angewandte Chemie, Vol. 128, Issue 8 https://doi.org/10.1002/ange.201510812	journal	February 2016
A Tale of Two Trimers from Two Different Worlds: A COF‐Inspired Synthetic Strategy for Pore‐Space Partitioning of MOFs Wang, Yanxiang; Zhao, Xiang; Yang, Huajun Angewandte Chemie, Vol. 131, Issue 19 https://doi.org/10.1002/ange.201901343	journal	February 2019
A Strategy for Constructing Pore‐Space‐Partitioned MOFs with High Uptake Capacity for C ₂ Hydrocarbons and CO ₂ Wang, Yong; Jia, Xiaoxia; Yang, Huajun Angewandte Chemie, Vol. 132, Issue 43 https://doi.org/10.1002/ange.202008696	journal	August 2020
Simultaneous Control of Pore‐Space Partition and Charge Distribution in Multi‐Modular Metal–Organic Frameworks Hong, Anh N.; Kusumoputro, Emily; Wang, Yanxiang Angewandte Chemie, Vol. 134, Issue 13 https://doi.org/10.1002/ange.202116064	journal	February 2022
A Crystalline Mesoporous Coordination Copolymer with High Microporosity Koh, Kyoungmoo; Wong-Foy, Antek G.; Matzger, Adam J. Angewandte Chemie International Edition, Vol. 47, Issue 4, p. 677-680 https://doi.org/10.1002/anie.200705020	journal	January 2008
Multiple Functions of Ionic Liquids in the Synthesis of Three‐Dimensional Low‐Connectivity Homochiral and Achiral Frameworks Zhang, Jian; Chen, Shumei; Bu, Xianhui Angewandte Chemie International Edition, Vol. 47, Issue 29 https://doi.org/10.1002/anie.200801838	journal	July 2008
Urothermal Synthesis of Crystalline Porous Materials Zhang, Jian; Bu, Julia T.; Chen, Shumei Angewandte Chemie International Edition, Vol. 49, Issue 47 https://doi.org/10.1002/anie.201003900	journal	October 2010
Framework Cationization by Preemptive Coordination of Open Metal Sites for Anion-Exchange Encapsulation of Nucleotides and Coenzymes Zhao, Xiang; Mao, Chengyu; Luong, Karen Tu Angewandte Chemie International Edition, Vol. 55, Issue 8 https://doi.org/10.1002/anie.201510812	journal	February 2016
A Tale of Two Trimers from Two Different Worlds: A COF-Inspired Synthetic Strategy for Pore-Space Partitioning of MOFs Wang, Yanxiang; Zhao, Xiang; Yang, Huajun Angewandte Chemie International Edition, Vol. 58, Issue 19 https://doi.org/10.1002/anie.201901343	journal	April 2019
A Strategy for Constructing Pore‐Space‐Partitioned MOFs with High Uptake Capacity for C ₂ Hydrocarbons and CO ₂ Wang, Yong; Jia, Xiaoxia; Yang, Huajun Angewandte Chemie International Edition, Vol. 59, Issue 43 https://doi.org/10.1002/anie.202008696	journal	August 2020
Simultaneous Control of Pore‐Space Partition and Charge Distribution in Multi‐Modular Metal–Organic Frameworks Hong, Anh N.; Kusumoputro, Emily; Wang, Yanxiang Angewandte Chemie International Edition, Vol. 61, Issue 13 https://doi.org/10.1002/anie.202116064	journal	February 2022
Solvent‐Free Synthesis of Zeolitic Imidazolate Frameworks and the Catalytic Properties of Their Carbon Materials Xiao, Yuchen; Hong, Anh N.; Hu, Dandan Chemistry – A European Journal, Vol. 25, Issue 71 https://doi.org/10.1002/chem.201903888	journal	November 2019
Solvent‐ and HF‐Free Synthesis of Flexible Chromium‐Based MIL‐53 and MIL‐88B Teo, Wei Liang; Ariff, Siti Khadijah Binte; Zhou, Weiqiang ChemNanoMat, Vol. 6, Issue 2 https://doi.org/10.1002/cnma.201900665	journal	January 2020
Water exchange on metal ions: experiments and simulations Helm, L.; Merbach, A. E. Coordination Chemistry Reviews, Vol. 187, Issue 1 https://doi.org/10.1016/S0010-8545(99)90232-1	journal	June 1999
Fine-tuning of pore-space-partitioned metal-organic frameworks for efficient C2H2/C2H4 and C2H2/CO2 separation Mu, Xiaobing; Xue, Yingying; Hu, Mancheng Chinese Chemical Letters, Vol. 34, Issue 2 https://doi.org/10.1016/j.cclet.2022.03.019	journal	February 2023
Linker functionalized metal-organic frameworks Ali Akbar Razavi, Sayed; Morsali, Ali Coordination Chemistry Reviews, Vol. 399 https://doi.org/10.1016/j.ccr.2019.213023	journal	November 2019
Green and time-saving synthesis of MIL-100(Cr) and its catalytic performance Mao, Ying; Qi, Hui; Ye, Gan Microporous and Mesoporous Materials, Vol. 274 https://doi.org/10.1016/j.micromeso.2018.07.026	journal	January 2019
Pore Space Partition in Metal–Organic Frameworks Zhai, Quan-Guo; Bu, Xianhui; Zhao, Xiang Accounts of Chemical Research, Vol. 50, Issue 2 https://doi.org/10.1021/acs.accounts.6b00526	journal	January 2017
Synthetic Strategy for Incorporating Carboxylate Ligands into Coordination Polymers under a Solvent-Free Reaction Hinokimoto, Akira; Izu, Hitoshi; Wei, Yong-Sheng Crystal Growth & Design, Vol. 21, Issue 11 https://doi.org/10.1021/acs.cgd.1c00587	journal	October 2021
Rapid Synthesis of Metal–Organic Frameworks MIL-101(Cr) Without the Addition of Solvent and Hydrofluoric Acid Leng, Kunyue; Sun, Yinyong; Li, Xiaolin Crystal Growth & Design, Vol. 16, Issue 3 https://doi.org/10.1021/acs.cgd.5b01696	journal	February 2016
Hierarchical Accordion-like Lanthanide-Based Metal–Organic Frameworks: Solvent-Free Syntheses and Ratiometric Luminescence Temperature-Sensing Properties Liu, Jiaqiang; Pei, Liu; Xia, Zhiguo Crystal Growth & Design, Vol. 19, Issue 11 https://doi.org/10.1021/acs.cgd.9b01014	journal	September 2019
Solvent-Free and Phase-Selective Synthesis of Aluminum Trimesate Metal–Organic Frameworks Li, Jiahong; Hurlock, Matthew J.; Goncharov, Vitaliy G. Inorganic Chemistry, Vol. 60, Issue 7 https://doi.org/10.1021/acs.inorgchem.0c03598	journal	March 2021
In Situ Monitoring of the Mechanosynthesis of the Archetypal Metal–Organic Framework HKUST-1: Effect of Liquid Additives on the Milling Reactivity Stolar, Tomislav; Batzdorf, Lisa; Lukin, Stipe Inorganic Chemistry, Vol. 56, Issue 11 https://doi.org/10.1021/acs.inorgchem.7b00707	journal	May 2017
Pore-Space Partition and Optimization for Propane-Selective High-Performance Propane/Propylene Separation Hong, Anh N.; Yang, Huajun; Li, Tong ACS Applied Materials & Interfaces, Vol. 13, Issue 44 https://doi.org/10.1021/acsami.1c10391	journal	July 2021
Solvent-Free Synthetic Route for Cerium(IV) Metal–Organic Frameworks with UiO-66 Architecture and Their Photocatalytic Applications Campanelli, Matteo; Del Giacco, Tiziana; De Angelis, Filippo ACS Applied Materials & Interfaces, Vol. 11, Issue 48 https://doi.org/10.1021/acsami.9b13730	journal	November 2019
Entrapment of Metal Clusters in Metal–Organic Framework Channels by Extended Hooks Anchored at Open Metal Sites Zheng, Shou-Tian; Zhao, Xiang; Lau, Samuel Journal of the American Chemical Society, Vol. 135, Issue 28 https://doi.org/10.1021/ja4044642	journal	May 2013
Pore Space Partition by Symmetry-Matching Regulated Ligand Insertion and Dramatic Tuning on Carbon Dioxide Uptake Zhao, Xiang; Bu, Xianhui; Zhai, Quan-Guo Journal of the American Chemical Society, Vol. 137, Issue 4 https://doi.org/10.1021/ja512137t	journal	January 2015
A Porous Coordination Copolymer with over 5000 m ² /g BET Surface Area Koh, Kyoungmoo; Wong-Foy, Antek G.; Matzger, Adam J. Journal of the American Chemical Society, Vol. 131, Issue 12 https://doi.org/10.1021/ja809985t	journal	April 2009
Ultrastable High-Connected Chromium Metal–Organic Frameworks Yang, Huajun; Peng, Fang; Hong, Anh N. Journal of the American Chemical Society, Vol. 143, Issue 36 https://doi.org/10.1021/jacs.1c07277	journal	August 2021
In Situ Monitoring and Mechanism of the Mechanochemical Formation of a Microporous MOF-74 Framework Julien, Patrick A.; Užarević, Krunoslav; Katsenis, Athanassios D. Journal of the American Chemical Society, Vol. 138, Issue 9 https://doi.org/10.1021/jacs.5b13038	journal	February 2016
Multivariable Modular Design of Pore Space Partition Zhao, Xiang; Bu, Xianhui; Nguyen, Edward T. Journal of the American Chemical Society, Vol. 138, Issue 46 https://doi.org/10.1021/jacs.6b07901	journal	November 2016
Solvent-Free Synthesis of ZIFs: A Route toward the Elusive Fe(II) Analogue of ZIF-8 López-Cabrelles, Javier; Romero, Jorge; Abellán, Gonzalo Journal of the American Chemical Society, Vol. 141, Issue 17 https://doi.org/10.1021/jacs.9b02686	journal	April 2019
Pore-Space-Partition-Enabled Exceptional Ethane Uptake and Ethane-Selective Ethane–Ethylene Separation Yang, Huajun; Wang, Yanxiang; Krishna, Rajamani Journal of the American Chemical Society, Vol. 142, Issue 5 https://doi.org/10.1021/jacs.9b12924	journal	January 2020
An ultra-tunable platform for molecular engineering of high-performance crystalline porous materials Zhai, Quan-Guo; Bu, Xianhui; Mao, Chengyu Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms13645	journal	December 2016
A new isoreticular class of metal-organic-frameworks with the MIL-88 topology Surblé, Suzy; Serre, Christian; Mellot-Draznieks, Caroline Chemical Communications, Vol. 0, Issue 3, p. 284-286 https://doi.org/10.1039/B512169H	journal	January 2006
Ligand design for functional metal–organic frameworks Almeida Paz, Filipe A.; Klinowski, Jacek; Vilela, Sérgio M. F. Chem. Soc. Rev., Vol. 41, Issue 3 https://doi.org/10.1039/C1CS15055C	journal	January 2012
A mechanochemical strategy for IRMOF assembly based on pre-designed oxo-zinc precursors Prochowicz, D.; Sokołowski, K.; Justyniak, I. Chemical Communications, Vol. 51, Issue 19 https://doi.org/10.1039/C4CC09917F	journal	January 2015
A facile solvent-free synthesis route for the assembly of a highly CO ₂ selective and H ₂ S tolerant NiSIFSIX metal–organic framework Shekhah, Osama; Belmabkhout, Youssef; Adil, Karim Chemical Communications, Vol. 51, Issue 71 https://doi.org/10.1039/C5CC04487A	journal	January 2015
Template mediated and solvent-free route to a variety of UiO-66 metal–organic frameworks Zou, Chao; Vagin, Sergei; Kronast, Alexander RSC Advances, Vol. 6, Issue 105 https://doi.org/10.1039/C6RA23947A	journal	January 2016
A facile and green synthesis of MIL-100(Fe) with high-yield and its catalytic performance Han, Le; Qi, Hui; Zhang, Dan New Journal of Chemistry, Vol. 41, Issue 22 https://doi.org/10.1039/C7NJ02975F	journal	January 2017
Alterations to secondary building units of metal–organic frameworks for the development of new functions Ha, Junsu; Lee, Jae Hwa; Moon, Hoi Ri Inorganic Chemistry Frontiers, Vol. 7, Issue 1 https://doi.org/10.1039/C9QI01119F	journal	January 2020
Bioinspired chemistry at MOF secondary building units Bour, James R.; Wright, Ashley M.; He, Xin Chemical Science, Vol. 11, Issue 7 https://doi.org/10.1039/C9SC06418D	journal	January 2020
N-Methylimidazolium containing metal phosphate–oxalates: solvent-free synthesis, crystal structure, and proton conduction Zhang, Junfeng; Lei, Qing; Luan, Lindong CrystEngComm, Vol. 24, Issue 4 https://doi.org/10.1039/D1CE01659H	journal	January 2022
Accelerated and scalable synthesis of UiO-66(Zr) with the assistance of inorganic salts under solvent-free conditions Gu, Yulong; Li, Xiaolin; Ye, Gan New Journal of Chemistry, Vol. 45, Issue 21 https://doi.org/10.1039/D1NJ01059J	journal	January 2021
Solvent-free synthesis of a microporous metal–organic framework Pichon, Anne; Lazuen-Garay, Ana; James, Stuart L. CrystEngComm, Vol. 8, Issue 3 https://doi.org/10.1039/b513750k	journal	January 2006
An array-based study of reactivity under solvent-free mechanochemical conditions—insights and trends Pichon, Anne; James, Stuart L. CrystEngComm, Vol. 10, Issue 12 https://doi.org/10.1039/b810857a	journal	January 2008
Secondary building units, nets and bonding in the chemistry of metal–organic frameworks Tranchemontagne, David J.; Mendoza-Cortés, José L.; O’Keeffe, Michael Chemical Society Reviews, Vol. 38, Issue 5, p. 1257-1283 https://doi.org/10.1039/b817735j	journal	January 2009
Direct structure elucidation by powder X-ray diffraction of a metal–organic framework material prepared by solvent-free grinding Fujii, Kotaro; Garay, Ana Lazuen; Hill, Janeen Chemical Communications, Vol. 46, Issue 40 https://doi.org/10.1039/c0cc02635b	journal	January 2010
Mineral neogenesis as an inspiration for mild, solvent-free synthesis of bulk microporous metal–organic frameworks from metal (Zn, Co) oxides Mottillo, Cristina; Lu, Yuneng; Pham, Minh-Hao Green Chemistry, Vol. 15, Issue 8 https://doi.org/10.1039/c3gc40520f	journal	January 2013
Secondary building units as the turning point in the development of the reticular chemistry of MOFs Kalmutzki, Markus J.; Hanikel, Nikita; Yaghi, Omar M. Science Advances, Vol. 4, Issue 10 https://doi.org/10.1126/sciadv.aat9180	journal	October 2018
Ultrahigh Porosity in Metal-Organic Frameworks Furukawa, H.; Ko, N.; Go, Y. B. Science, Vol. 329, Issue 5990, p. 424-428 https://doi.org/10.1126/science.1192160	journal	July 2010
Solvent-Free Synthesis of Iron-Based Metal-Organic Frameworks (MOFs) as Slow-Release Fertilizers Du, Yaxiao; Xu, Xuebin; Ma, Fei Polymers, Vol. 13, Issue 4 https://doi.org/10.3390/polym13040561	journal	February 2021
Solvent-Free Synthesis of MIL-101(Cr) for CO2 Gas Adsorption: The Effect of Metal Precursor and Molar Ratio Chong, Kok Chung; Ho, Pui San; Lai, Soon Onn Sustainability, Vol. 14, Issue 3 https://doi.org/10.3390/su14031152	journal	January 2022

Figures / Tables (3)

Figure 1(p. 2)

Figure 2(p. 3)

Figure 3(p. 4)

Similar Records

Solvent‐free Synthesis of Multi‐Module Pore‐Space‐Partitioned Metal‐Organic Frameworks for Gas Separation

Journal Article · Sun Feb 26 19:00:00 EST 2023 · Angewandte Chemie · OSTI ID:1958921

Multi–Stage Optimization of Pore Size and Shape in Pore–Space–Partitioned Metal–Organic Frameworks for Highly Selective and Sensitive Benzene Capture

Journal Article · Wed Sep 18 20:00:00 EDT 2024 · Angewandte Chemie (International Edition) · OSTI ID:2478390

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
MOF
gas separation
multi-module
pacs
solvent-free

Solvent–free Synthesis of Multi–Module Pore–Space–Partitioned Metal–Organic Frameworks for Gas Separation

Citation Formats

References (56)

Figures / Tables (3)

Similar Records

Related Subjects