Solvent‐free Synthesis of Multi‐Module Pore‐Space‐Partitioned Metal‐Organic Frameworks for Gas Separation

Xiao, Yuchen; Chen, Yichong; Hong, Anh N.; Bu, Xianhui; Feng, Pingyun

doi:10.1002/ange.202300721

Solvent‐free Synthesis of Multi‐Module Pore‐Space‐Partitioned Metal‐Organic Frameworks for Gas Separation

Journal Article · Mon Feb 27 00:00:00 EST 2023 · Angewandte Chemie

DOI:https://doi.org/10.1002/ange.202300721· OSTI ID:1958921

Xiao, Yuchen ^[1]; Chen, Yichong ^[1]; Hong, Anh N. ^[1]; Bu, Xianhui ^[2]; ^[1]

Department of Chemistry University of California Riverside 900 University Ave Riverside CA-92521 USA
Department of Chemistry and Biochemistry California State University Long Beach 1250 Bellflower Boulevard Long Beach CA-90840 USA

Abstract

Multi‐module design of framework materials with multiple distinct building blocks has attracted much attention because such materials are more amenable to compositional and geometrical tuning and thus offer more opportunities for property optimization. Few examples are known that use environmentally friendly and cost‐effective solvent‐free method to synthesize such materials. Here, we report the use of solvent‐free method (also modulator‐free) to synthesize a series of multi‐module MOFs with high stability and separation property for C ₂ H ₂ /CO ₂ . The synthesis only requires simple mixing of reactants and short reaction time (2 h). Highly porous and stable materials can be made without any post‐synthetic activation. The success of solvent‐free synthesis of multi‐module MOFs reflects the synergy between different modules, resulting in stable pore‐partitioned materials, despite the fact that other competitive crystallization pathways with simpler framework compositions also exist.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0010596

OSTI ID:: 1958921

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Journal Issue: 14 Vol. 135; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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