An organophosphine oxide redox shuttle additive that delivers long-term overcharge protection for 4 V lithium-ion batteries

Huang, Jinhua; Azimi, Nasim; Cheng, Lei; Shkrob, Ilya A.; Xue, Zheng; Zhang, Junjie; Dietz-Rago, Nancy L.; Curtiss, Larry A.; Amine, Khalil; Zhang, Zhengcheng; Zhang, Lu

doi:10.1039/C5TA01326G

An organophosphine oxide redox shuttle additive that delivers long-term overcharge protection for 4 V lithium-ion batteries

Journal Article · Thu May 28 04:00:00 EDT 2015 · Journal of Materials Chemistry. A

DOI:https://doi.org/10.1039/C5TA01326G· OSTI ID:2205075

Huang, Jinhua; Azimi, Nasim; Cheng, Lei; Shkrob, Ilya A.; Xue, Zheng; Zhang, Junjie; Dietz-Rago, Nancy L.; Curtiss, Larry A.; Amine, Khalil; Zhang, Zhengcheng; Zhang, Lu

Redox shuttle additives are used to protect Li-ion batteries from overcharge. Increased operating voltage requires striking a balance between a high redox potential and electrochemical stability. 1,4-Bis[bis(1-methylethyl) phosphinyl]-2,5-dimethoxybenzene (BPDB) exhibits a redox potential of 4.5 V vs. Li/Li+ and provides stable overcharge protection for 4 V cells delivering 95 cycles of 100% overcharge ratio.

Research Organization:: Argonne National Laboratory (ANL)

Sponsoring Organization:: USDOE Office of Science - Office of Basic Energy Sciences - Joint Center for Energy Storage Research (JCESR)

DOE Contract Number:: AC02-06CH11357

OSTI ID:: 2205075

Journal Information:: Journal of Materials Chemistry. A, Journal Name: Journal of Materials Chemistry. A Journal Issue: 20 Vol. 3; ISSN 2050-7488

Country of Publication:: United States

Language:: English

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