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1,4-Bis(trimethylsilyl)-2,5-dimethoxybenzene: a novel redox shuttle additive for overcharge protection in lithium-ion batteries that doubles as a mechanistic chemical probe

Journal Article · · Journal of Materials Chemistry. A
DOI:https://doi.org/10.1039/C5TA00899A· OSTI ID:1392353
 [1];  [2];  [2];  [3];  [1];  [2];  [1];  [2];  [3];  [1]
  1. Joint Center for Energy Storage Research; Argonne National Laboratory; , USA; Chemical Sciences and Engineering Division; Argonne National Laboratory
  2. Chemical Sciences and Engineering Division; Argonne National Laboratory; , USA
  3. Joint Center for Energy Storage Research; Argonne National Laboratory; , USA; Materials Science Division; Argonne National Laboratory

A novel redox shuttle additive, 1,4-bis(trimethylsilyl)-2,5-dimethoxybenzene, is shown to deliver superb overcharge protection of LiFePO4electrode in Li-ion batteries.

Research Organization:
Argonne National Laboratory (ANL)
Sponsoring Organization:
USDOE Office of Science - Office of Basic Energy Sciences
DOE Contract Number:
AC02-06CH11357
OSTI ID:
1392353
Journal Information:
Journal of Materials Chemistry. A, Journal Name: Journal of Materials Chemistry. A Journal Issue: 14 Vol. 3; ISSN JMCAET; ISSN 2050-7488
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

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Asymmetric Form of Redox Shuttle Based on 1,4-Di- tert -butyl-2,5-dimethoxybenzene journal January 2013
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Molecular engineering towards safer lithium-ion batteries: a highly stable and compatible redox shuttle for overcharge protection journal January 2012
Fused ring and linking groups effect on overcharge protection for lithium-ion batteries journal February 2011
Electrolytes and Interphases in Li-Ion Batteries and Beyond journal October 2014
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Issues and challenges facing rechargeable lithium batteries journal November 2001
Spectroelectrochemical Studies of Redox Shuttle Overcharge Additive for LiFePO[sub 4]-Based Li-Ion Batteries journal January 2005

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