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Enhancement of the near-band-edge photoluminescence of ZnO nanowires: Important role of hydrogen incorporation versus plasmon resonances

Journal Article · · Applied Physics Letters
DOI:https://doi.org/10.1063/1.3569951· OSTI ID:21518349
; ; ;  [1]; ;  [2]
  1. Institute of Solid State Physics, University of Bremen, D-28359 Bremen (Germany)
  2. Institute for Applied Physics, Karlsruhe Institute of Technology, D-76131 Karlsruhe (Germany)
We investigated the photoluminescence properties of ZnO nanowires coated with Au, Ag, and Pt nanoparticles deposited by dc sputtering. A strong enhancement of the near-band-edge emission was observed in all metal-coated samples but also if the samples were treated with Ar plasma without any nanoparticle deposition. High-resolution photoluminescence spectroscopy revealed hydrogen-donor-bound-exciton emission in all samples indicating unintentional hydrogen incorporation. A shorter decay time of the near-band-edge emission was observed in all cases. The results indicate that unintentional hydrogen incorporation plays a dominant role when metal deposition is performed by sputtering.
OSTI ID:
21518349
Journal Information:
Applied Physics Letters, Journal Name: Applied Physics Letters Journal Issue: 13 Vol. 98; ISSN APPLAB; ISSN 0003-6951
Country of Publication:
United States
Language:
English