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Title: Experiences in long-term evaluation of mercury emission monitoring systems

Abstract

Six mercury continuous emission monitoring (CEM) systems provided by two leading mercury (Hg) CEM system manufacturers were tested at five coal combustion utilities. The linearity, response time, day-to-day stability, efficiency of the Hg speciation modules, and ease of use were evaluated by following procedures specified in the Code of Federal Regulation Title 40 Part 75 (40 CFR Part 75). Mercury monitoring results from Hg CEM systems were compared to an EPA-recognized reference method. A sorbent trap sampling system was also evaluated in this study to compare the relative accuracy to the reference method as well as to Hg CEM systems. A conceptual protocol proposed by U.S. EPA (Method 30A) for using an Hg CEM system as the reference method for the Hg relative accuracy (RA) test was also followed to evaluate the workability of the protocol. This paper discusses the operational experience obtained from these field studies and the remaining challenges to overcome while using Hg CEM systems and the sorbent trap method for continuous Hg emission monitoring. 3 refs., 5 figs., 11 tabs.

Authors:
; ; ; ; ; ; ;  [1]
  1. Western Kentucky University, Bowling Green, KY (United States). Institute for Combustion Science and Environmental Technology
Publication Date:
OSTI Identifier:
21107437
Resource Type:
Journal Article
Resource Relation:
Journal Name: Energy and Fuels; Journal Volume: 22; Journal Issue: 5; Other Information: chin-min-cheng@wku.edu
Country of Publication:
United States
Language:
English
Subject:
01 COAL, LIGNITE, AND PEAT; MERCURY; AIR POLLUTION MONITORS; PERFORMANCE TESTING; CALIBRATION; ACCURACY

Citation Formats

Chin-Min Cheng, Hung-Ta Lin, Qiang Wang, Chien-Wei Chen, Chia-Wei Wang, Ming-Chung Liu, Chi-Kuan Chen, and Wei-Ping Pan. Experiences in long-term evaluation of mercury emission monitoring systems. United States: N. p., 2008. Web. doi:10.1021/ef7006744.
Chin-Min Cheng, Hung-Ta Lin, Qiang Wang, Chien-Wei Chen, Chia-Wei Wang, Ming-Chung Liu, Chi-Kuan Chen, & Wei-Ping Pan. Experiences in long-term evaluation of mercury emission monitoring systems. United States. doi:10.1021/ef7006744.
Chin-Min Cheng, Hung-Ta Lin, Qiang Wang, Chien-Wei Chen, Chia-Wei Wang, Ming-Chung Liu, Chi-Kuan Chen, and Wei-Ping Pan. 2008. "Experiences in long-term evaluation of mercury emission monitoring systems". United States. doi:10.1021/ef7006744.
@article{osti_21107437,
title = {Experiences in long-term evaluation of mercury emission monitoring systems},
author = {Chin-Min Cheng and Hung-Ta Lin and Qiang Wang and Chien-Wei Chen and Chia-Wei Wang and Ming-Chung Liu and Chi-Kuan Chen and Wei-Ping Pan},
abstractNote = {Six mercury continuous emission monitoring (CEM) systems provided by two leading mercury (Hg) CEM system manufacturers were tested at five coal combustion utilities. The linearity, response time, day-to-day stability, efficiency of the Hg speciation modules, and ease of use were evaluated by following procedures specified in the Code of Federal Regulation Title 40 Part 75 (40 CFR Part 75). Mercury monitoring results from Hg CEM systems were compared to an EPA-recognized reference method. A sorbent trap sampling system was also evaluated in this study to compare the relative accuracy to the reference method as well as to Hg CEM systems. A conceptual protocol proposed by U.S. EPA (Method 30A) for using an Hg CEM system as the reference method for the Hg relative accuracy (RA) test was also followed to evaluate the workability of the protocol. This paper discusses the operational experience obtained from these field studies and the remaining challenges to overcome while using Hg CEM systems and the sorbent trap method for continuous Hg emission monitoring. 3 refs., 5 figs., 11 tabs.},
doi = {10.1021/ef7006744},
journal = {Energy and Fuels},
number = 5,
volume = 22,
place = {United States},
year = 2008,
month = 9
}
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