Estimation of the energy of coordination K-O bonds in a potassium hydrophthalate crystal on the basis of electron-density distribution analysis
Journal Article
·
· Crystallography Reports
- Russian Academy of Sciences, Nesmeyanov Institute of Organoelement Compounds (Russian Federation)
Detailed study of the nature of weak coordination K-O interactions and strong O-H...O hydrogen bonds and estimation of their energy in a potassium hydrophthalate crystal have been performed on the basis of the topological analysis of the electron density distribution function, obtained from precise X-ray diffraction study at 100 K (R1 = 0.0110), within Bader's 'Atoms in Molecule' theory. It is shown that the charge transfer accompanying the formation of cation...anion associates in the crystal is only 0.05 e.
- OSTI ID:
- 21090616
- Journal Information:
- Crystallography Reports, Vol. 53, Issue 2; Other Information: DOI: 10.1007/s11445-008-2005-3; Copyright (c) 2008 Pleiades Publishing, Ltd; Country of input: International Atomic Energy Agency (IAEA); ISSN 1063-7745
- Country of Publication:
- United States
- Language:
- English
Similar Records
Estimation of the energy of coordination K-O bonds in a potassium hydrophthalate crystal on the basis of electron-density distribution analysis
Preparation and X-ray crystal structure of K[Nd(O-2,6-i-Pr[sub 2]C[sub 6]H[sub 3])[sub 4]]: A one-dimensional chain of lanthanide aryloxide anions joined by bis([eta][sup 6]-arene)-potassium interactions
Photoelectron spectroscopy of solvated dicarboxylate and alkali metal ion clusters, M+[O2C(CH 2)2CO2]2-[H2O]n(M = Na, K; n = 1–6)
Journal Article
·
Sat Mar 15 00:00:00 EDT 2008
· Crystallography Reports
·
OSTI ID:21090616
Preparation and X-ray crystal structure of K[Nd(O-2,6-i-Pr[sub 2]C[sub 6]H[sub 3])[sub 4]]: A one-dimensional chain of lanthanide aryloxide anions joined by bis([eta][sup 6]-arene)-potassium interactions
Journal Article
·
Wed Apr 29 00:00:00 EDT 1992
· Inorganic Chemistry; (United States)
·
OSTI ID:21090616
Photoelectron spectroscopy of solvated dicarboxylate and alkali metal ion clusters, M+[O2C(CH 2)2CO2]2-[H2O]n(M = Na, K; n = 1–6)
Journal Article
·
Mon Jan 01 00:00:00 EST 2018
· Physical Chemistry Chemical Physics. PCCP (Print)
·
OSTI ID:21090616
+2 more