Electronic spectra, optical activity, and crystal-field energy-level structure of Dy{sup 3+} in trigonal Na{sub 3}[Dy(oda){sub 3}]{center_dot}2NaClO{sub 4}{center_dot}6H{sub 2}O crystals{dagger}
- Univ. of Virginia, Charlottesville, VA (United States)
Optical absorption and emission measurements are used to locate and assign 152 crystal-field energy levels split out of the 4f{sup 9} electronic configuration of Dy{sup 3+} in Na{sub 3}[Dy(oda){sub 3}]{center_dot}2NaClO{sub 4}{center_dot}6H{sub 2}O (where oda denotes an oxydiacetate ligand). The absorption measurements span the 230-1800 nm wavelength range, and they encompass all optical transitions that may occur between the {sup 6}H{sub 15/2} ground multiplet and 63 different excited multiplet manifolds of the 4f{sup 9}(Dy{sup 3+}) electronic configuration.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 210100
- Journal Information:
- Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 19 Vol. 34; ISSN 0020-1669; ISSN INOCAJ
- Country of Publication:
- United States
- Language:
- English
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