A novel organically templated three-dimensional open framework vanadium tellurite: (NH{sub 3}CH{sub 2}CH{sub 2}NH{sub 3}){sub 2}V{sub 2}Te{sub 6}O{sub 18}
- Department of Chemistry, Institute of Polyoxometalate Chemistry, Northeast Normal University, Changchun, Jilin 130024 (China)
- Changchun Institute of Applied Chemistry, Academia Sinica, Changchun 130022 (China)
A novel organically templated vanadium tellurite (NH{sub 3}CH{sub 2}CH{sub 2}NH{sub 3}){sub 2}V{sub 2}Te{sub 6}O{sub 18} (1) has been hydrothermally synthesized and characterized by elemental analyses, IR, thermal stability analysis, magnetic susceptibilities and single crystal X-ray diffraction. Compound 1 crystallizes in the monoclinic system, space group P2{sub 1}/n, a=8.891(2)A, b=8.834(2)A, c=15.906(4)A, {beta}=94.789(4){sup o}, V=1181.5(5)A{sup 3}, Z=2, R{sub 1}[I>2{sigma}(I)]=0.0187, wR{sub 2}[I>2{sigma}(I)]=0.0482. Compound 1 exhibits a novel three-dimensional (3D) vanadium tellurite anion framework composed of vanadium, tellurium, and oxygen atoms through covalent bonds, with the [NH{sub 3}CH{sub 2}CH{sub 2}NH{sub 3}]{sup 2+} cations residing in the channels.
- OSTI ID:
- 20725967
- Journal Information:
- Journal of Solid State Chemistry, Journal Name: Journal of Solid State Chemistry Journal Issue: 6 Vol. 178; ISSN 0022-4596; ISSN JSSCBI
- Country of Publication:
- United States
- Language:
- English
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