[C{sub 2}N{sub 2}H{sub 10}]{sub 1.5}[Nd(SO{sub 4}){sub 3}(H{sub 2}O)].2H{sub 2}O: The first organically templated neodymium sulfate with a layer structure

Journal Article · Fri Apr 15 04:00:00 EDT 2005 · Journal of Solid State Chemistry

DOI:https://doi.org/10.1016/j.jssc.2004.11.019· OSTI ID:20725865

Li, Liu ^[1]; He, Meng ^[1]; Guanghua, Li ^[1]; Yanjie, Cui ^[1]; Xiaofeng, Wang ^[1]; Wenqin, Pang ^[1]

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1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012 (China)

The first organically templated neodymium sulfate has been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction analysis. [C{sub 2}N{sub 2}H{sub 10}]{sub 1.5}[Nd(SO{sub 4}){sub 3}(H{sub 2}O)].2H{sub 2}O crystallizes in the monoclinic space group P2{sub 1}/c with crystal data a=6.5896(5)A, b=26.539(3)A, c=9.9889(8)A, {beta}=104.399(5){sup o}, V=1692.0(2)A{sup 3}, Z=4. Refinement gave R{sub 1}[I>2{sigma}(I)]=0.0471, and wR{sub 2}[I>2{sigma}(I)]=0.0899. The compound exhibits an infinite zigzag anionic layer structure, which consists of {l_brace}Nd(SO{sub 4}){sub 3}(H{sub 2}O){r_brace}{sup 3-} structural units connected together to form interesting eight-membered rings via corner-sharing and edge-sharing modes. The compound has the antiferromagnetic behavior and exhibits intense photoluminescence upon photo-excitation at 450nm.

• OSTI ID: 20725865
• Journal Information: Journal of Solid State Chemistry, Journal Name: Journal of Solid State Chemistry Journal Issue: 4 Vol. 178; ISSN 0022-4596; ISSN JSSCBI
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
ANTIFERROMAGNETISM
EXCITATION
HYDROTHERMAL SYNTHESIS
LAYERS
MAGNETIC PROPERTIES
MONOCLINIC LATTICES
MONOCRYSTALS
NEODYMIUM SULFATES
PHOTOLUMINESCENCE
SPACE GROUPS
X-RAY DIFFRACTION