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Universal Relationship between Magnetization and Changes in the Local Structure of La{sub 1-x}Ca{sub x}MnO{sub 3}: Evidence for Magnetic Dimers

Journal Article · · Physical Review Letters
; ;  [1];  [2];  [3];  [4]
  1. Physics Department, University of California, Santa Cruz, California 95064 (United States)
  2. Department of Physics, Montana State University, Bozeman, Montana 59717 (United States)
  3. Quantum Design Inc., 11578 Sorrento Valley Road, San Diego, California 92121-1311 (United States)
  4. Stanford Synchrotron Radiation Laboratory, Stanford Linear Accelerator Center, Menlo Park, California 94025 (United States)

We present extensive x-ray absorption fine structure measurements on La{sub 1-x}Ca{sub x}MnO{sub 3} as a function of the B field (to 11 T) and Ca concentration, x (21%-45%). These results reveal local structure changes (associated with polaron formation) that depend only on the magnetization for a given sample, irrespective of whether the magnetization is achieved through a decrease in temperature or an applied magnetic field. Furthermore, the relationship between local structure and magnetization depends on the hole doping. A model is proposed in which a filamentary magnetization initially develops via the aggregation of pairs of Mn atoms involving a hole and an electron site. These pairs have little distortion and it is likely that they form at temperature T{sup *} above T{sub c}.

OSTI ID:
20699401
Journal Information:
Physical Review Letters, Journal Name: Physical Review Letters Journal Issue: 10 Vol. 95; ISSN 0031-9007; ISSN PRLTAO
Country of Publication:
United States
Language:
English