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Low-background instrumental neutron activation analysis of silicon semiconductor materials

Journal Article · · Journal of the Electrochemical Society
DOI:https://doi.org/10.1149/1.1836433· OSTI ID:201413
; ; ; ; ;  [1];  [2]
  1. Lawrence Berkeley National Lab., CA (United States)
  2. Charles Evans and Associates, Redwood City, CA (United States)

Samples of silicon wafers, some implanted with zinc, some with memory circuits fabricated on them, and some with oxide coatings were activated with neutrons and analyzed for trace element impurities with low-background germanium gamma-ray spectrometers. Results are presented for these samples as well as for a reference material. Because the silicon matrix activation is so small, reduced spectrometer system background permits the detection of significantly lower impurity concentrations than would otherwise be possible. For the highest efficiency and lowest background system, limits on the lowest levels of trace element concentrations have been measured for wafer sized (1 to 10 g) samples and inferred for bulk sized (365 g) samples. For wafer-sized samples, part-per-trillion detection capabilities are demonstrated for a variety of elemental contaminants important in semiconductor fabrication.

Sponsoring Organization:
USDOE
DOE Contract Number:
AC03-76SF00098
OSTI ID:
201413
Journal Information:
Journal of the Electrochemical Society, Journal Name: Journal of the Electrochemical Society Journal Issue: 1 Vol. 143; ISSN 0013-4651; ISSN JESOAN
Country of Publication:
United States
Language:
English

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