Modification of LiMn2O4 surfaces by controlling the Acid–Base surface chemistry of atomic layer deposition

Kang, Donghyeon; Warburton, Robert E.; Mane, Anil U.; Greeley, Jeffrey; Elam, Jeffrey W.

doi:10.1016/j.apsusc.2022.153329

Title: Modification of LiMn₂O₄ surfaces by controlling the Acid–Base surface chemistry of atomic layer deposition

Journal Article · Wed Apr 06 00:00:00 EDT 2022 · Applied Surface Science

DOI:https://doi.org/10.1016/j.apsusc.2022.153329· OSTI ID:2007747

^[1];

^[2]; Mane, Anil U. ^[1]; Greeley, Jeffrey ^[2]; Elam, Jeffrey W. ^[1]

Argonne National Laboratory (ANL), Argonne, IL (United States)
Purdue Univ., West Lafayette, IN (United States)

In this combined theoretical and experimental study, we report the effects of Al precursor selection on the growth chemistry, interfacial structure, and electrochemistry of Al₂O₃ coatings on spinel LiMn₂O₄ (LMO) surfaces by atomic layer deposition (ALD). Five Al precursors, exhibiting a range of Lewis acid-base properties, were used to establish trends in the ALD Al₂O₃ growth chemistry on LMO powders in comparison to redox-inactive planar silicon substrates. We show that the Lewis acid-base properties of the Al precursor ligands can be used to tune both the Mn oxidation states and the Al₂O₃ coverage on the LMO surface. Density functional theory calculations are used to examine the reaction mechanism of each precursor on LMO surfaces, elucidating a correlation between the Lewis acidity of the ligands and the decomposition thermochemistry. In-depth X-ray photoelectron spectroscopy and in situ Fourier transform infrared spectroscopy measurements support these theoretical predictions and further reveal how different Al precursors modify the atomic and electronic structure near the LMO surface during ALD. While the Mn oxidation state is strongly influenced by the Lewis acidity of the precursor ligand, the surface coverage and thickness of the Al₂O₃ coating are a more representative descriptor of the electrochemical performance measured in coin cell experiments. Finally, we show how the ligand acid-base properties of ALD precursors can be used to rationally tailor atomic layer growth mechanisms, which may enable atomic level control over the structure of functionalized interfaces for various applications related to catalysis, semiconductors, and energy storage.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Electrical Energy Storage (CEES)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 2007747

Journal Information:: Applied Surface Science, Vol. 599; ISSN 0169-4332

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (102)

A Critical Review: The Impact of the Battery Electrode Material Substrate on the Composition and Properties of Atomic Layer Deposition (ALD) Coatings Tiurin, Ortal; Ein‐Eli, Yair Advanced Materials Interfaces, Vol. 6, Issue 24 https://doi.org/10.1002/admi.201901455	journal	October 2019
Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
Dissolution of Spinel Oxides and Capacity Losses in 4V Li / Li_xMn₂O₄ Cells Jang, Dong H.; Shin, Young J.; Oh, Seung M. Journal of The Electrochemical Society, Vol. 143, Issue 7, p. 2204-2211 https://doi.org/10.1149/1.1836981	journal	January 1996
Lithium Batteries and Cathode Materials Whittingham, M. Stanley Chemical Reviews, Vol. 104, Issue 10, p. 4271-4302 https://doi.org/10.1021/cr020731c	journal	October 2004
Aluminum Interdiffusion into LiCoO ₂ Using Atomic Layer Deposition for High Rate Lithium Ion Batteries Teranishi, Takashi; Yoshikawa, Yumi; Yoneda, Mika ACS Applied Energy Materials, Vol. 1, Issue 7 https://doi.org/10.1021/acsaem.8b00496	journal	June 2018
First-Principles Predictions and in Situ Experimental Validation of Alumina Atomic Layer Deposition on Metal Surfaces Lu, Junling; Liu, Bin; Guisinger, Nathan P. Chemistry of Materials, Vol. 26, Issue 23 https://doi.org/10.1021/cm503178j	journal	November 2014
On the Oxidation State of Manganese Ions in Li-Ion Battery Electrolyte Solutions Banerjee, Anjan; Shilina, Yuliya; Ziv, Baruch Journal of the American Chemical Society, Vol. 139, Issue 5 https://doi.org/10.1021/jacs.6b10781	journal	January 2017
Surface chemistry of LiNi0.5Mn1.5O4 particles coated by Al2O3 using atomic layer deposition for lithium-ion batteries Kim, Jin Wook; Kim, Dong Hyeon; Oh, Dae Yang Journal of Power Sources, Vol. 274 https://doi.org/10.1016/j.jpowsour.2014.10.207	journal	January 2015
LiMn ₂ O ₄ @Au Particles as Cathodes for Li-Ion Batteries Esbenshade, Jennifer L.; Fox, Mathew D.; Gewirth, Andrew A. Journal of The Electrochemical Society, Vol. 162, Issue 1 https://doi.org/10.1149/2.0241501jes	journal	November 2014
Effects of Atomic Layer Deposition of Al2O3 on the Li[Li0.20Mn0.54Ni0.13Co0.13]O2 Cathode for Lithium-Ion Batteries Seok Jung, Yoon; Cavanagh, Andrew S.; Yan, Yanfa Journal of The Electrochemical Society, Vol. 158, Issue 12 https://doi.org/10.1149/2.030112jes	journal	January 2011
Atomic Layer Deposition of Al₂O₃ Using Aluminum Triisopropoxide (ATIP): A Combined Experimental and Theoretical Study Tai, Truong Ba; Cao, LiAo; Mattelaer, Felix The Journal of Physical Chemistry C, Vol. 123, Issue 1 https://doi.org/10.1021/acs.jpcc.8b09198	journal	December 2018
Thermodynamic Stability of Low- and High-Index Spinel LiMn ₂ O ₄ Surface Terminations Warburton, Robert E.; Iddir, Hakim; Curtiss, Larry A. ACS Applied Materials & Interfaces, Vol. 8, Issue 17 https://doi.org/10.1021/acsami.6b01069	journal	April 2016
Acidity of Hydrocarbons. VIII. An HMO Examination of Exchange Rates of Methylarene-α-d's with Lithium Cyclohexylamide Streitwieser, A.; Langworthy, W. C.; Brauman, J. I. Journal of the American Chemical Society, Vol. 85, Issue 12 https://doi.org/10.1021/ja00895a014	journal	June 1963
Electron-energy-loss spectra and the structural stability of nickel oxide: An LSDA+U study Dudarev, S. L.; Botton, G. A.; Savrasov, S. Y. Physical Review B, Vol. 57, Issue 3, p. 1505-1509 https://doi.org/10.1103/PhysRevB.57.1505	journal	January 1998
Atomic layer epitaxy Suntola, Tuomo Materials Science Reports, Vol. 4, Issue 5 https://doi.org/10.1016/S0920-2307(89)80006-4	journal	January 1989
Battery materials for ultrafast charging and discharging Kang, Byoungwoo; Ceder, Gerbrand Nature, Vol. 458, Issue 7235, p. 190-193 https://doi.org/10.1038/nature07853	journal	March 2009
Density-functional theory and strong interactions: Orbital ordering in Mott-Hubbard insulators Liechtenstein, A. I.; Anisimov, V. I.; Zaanen, J. Physical Review B, Vol. 52, Issue 8 https://doi.org/10.1103/PhysRevB.52.R5467	journal	August 1995
Surface chemistry of atomic layer deposition: A case study for the trimethylaluminum/water process Puurunen, Riikka L. Journal of Applied Physics, Vol. 97, Issue 12, Article No. 121301 https://doi.org/10.1063/1.1940727	journal	June 2005
Thermodynamic Aspects of Cathode Coatings for Lithium-Ion Batteries Aykol, Muratahan; Kirklin, Scott; Wolverton, C. Advanced Energy Materials, Vol. 4, Issue 17 https://doi.org/10.1002/aenm.201400690	journal	August 2014
Li-ion battery materials: present and future Nitta, Naoki; Wu, Feixiang; Lee, Jung Tae Materials Today, Vol. 18, Issue 5 https://doi.org/10.1016/j.mattod.2014.10.040	journal	June 2015
New Insights on Graphite Anode Stability in Rechargeable Batteries: Li Ion Coordination Structures Prevail over Solid Electrolyte Interphases Ming, Jun; Cao, Zhen; Wahyudi, Wandi ACS Energy Letters, Vol. 3, Issue 2 https://doi.org/10.1021/acsenergylett.7b01177	journal	January 2018
Ab initiomolecular dynamics for liquid metals Kresse, G.; Hafner, J. Physical Review B, Vol. 47, Issue 1, p. 558-561 https://doi.org/10.1103/PhysRevB.47.558	journal	January 1993
Density-functional theory and NiO photoemission spectra Anisimov, V. I.; Solovyev, I. V.; Korotin, M. A. Physical Review B, Vol. 48, Issue 23 https://doi.org/10.1103/PhysRevB.48.16929	journal	December 1993
Dependence of atomic layer-deposited Al2O3 films characteristics on growth temperature and Al precursors of Al(CH3)3 and AlCl3 Yun, Sun Jin; Lee, Kyung-Ho; Skarp, Jarmo Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 15, Issue 6 https://doi.org/10.1116/1.580895	journal	November 1997
Structure and electrochemical characterization of Li1+xMn2−xO4 spinels for rechargeable lithium batteries Takada, Toshimi; Hayakawa, Hiroshi; Enoki, Hirotoshi Journal of Power Sources, Vol. 81-82 https://doi.org/10.1016/S0378-7753(98)00225-0	journal	September 1999
Effectively suppressing dissolution of manganese from spinel lithium manganate via a nanoscale surface-doping approach Lu, Jun; Zhan, Chun; Wu, Tianpin Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms6693	journal	December 2014
Simulating the atomic layer deposition of alumina from first principles Elliott, Simon D.; Greer, James C. Journal of Materials Chemistry, Vol. 14, Issue 21 https://doi.org/10.1039/b405776g	journal	January 2004
Structure and surface chemistry of Al2O3 coated LiMn2O4 nanostructured electrodes with improved lifetime Waller, G. H.; Brooke, P. D.; Rainwater, B. H. Journal of Power Sources, Vol. 306 https://doi.org/10.1016/j.jpowsour.2015.11.114	journal	February 2016
Three-Dimension Hierarchical Al ₂ O ₃ Nanosheets Wrapped LiMn ₂ O ₄ with Enhanced Cycling Stability as Cathode Material for Lithium Ion Batteries Lai, Feiyan; Zhang, Xiaohui; Wang, Hongqiang ACS Applied Materials & Interfaces, Vol. 8, Issue 33 https://doi.org/10.1021/acsami.6b05640	journal	August 2016
Preparation of fine single crystals of spinel-type lithium manganese oxide by LiCl flux method for rechargeable lithium batteries. Part 1. LiMn2O4 Tang, Weiping; Yang, Xiaojing; Liu, Zhonghui Journal of Materials Chemistry, Vol. 12, Issue 10 https://doi.org/10.1039/b203200g	journal	August 2002
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set Kresse, G.; Furthmüller, J. Computational Materials Science, Vol. 6, Issue 1, p. 15-50 https://doi.org/10.1016/0927-0256(96)00008-0	journal	July 1996
Manganese oxides for lithium batteries Thackeray, Michael M. Progress in Solid State Chemistry, Vol. 25, Issue 1-2 https://doi.org/10.1016/S0079-6786(97)81003-5	journal	January 1997
Tris(dimethylamido)aluminum(III): An overlooked atomic layer deposition precursor Buttera, Sydney C.; Mandia, David J.; Barry, Seán T. Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 35, Issue 1 https://doi.org/10.1116/1.4972469	journal	December 2016
Atomic layer deposition of Al2O3 films using AlCl3 and Al(OiPr)3 as precursors Räisänen, Petri I.; Ritala, Mikko; Leskelä, Markku Journal of Materials Chemistry, Vol. 12, Issue 5 https://doi.org/10.1039/b201385c	journal	March 2002
Unexpected Improved Performance of ALD Coated LiCoO ₂ /Graphite Li-Ion Batteries Jung, Yoon Seok; Lu, Peng; Cavanagh, Andrew S. Advanced Energy Materials, Vol. 3, Issue 2 https://doi.org/10.1002/aenm.201200370	journal	September 2012
Descriptor-Based Analysis of Atomic Layer Deposition Mechanisms on Spinel LiMn ₂ O ₄ Lithium-Ion Battery Cathodes Warburton, Robert E.; Young, Matthias J.; Letourneau, Steven Chemistry of Materials, Vol. 32, Issue 5 https://doi.org/10.1021/acs.chemmater.9b03809	journal	February 2020
A novel coating onto LiMn2O4 cathode with increased lithium ion battery performance Zeng, Jiesheng; Li, Minsi; Li, Xifei Applied Surface Science, Vol. 317 https://doi.org/10.1016/j.apsusc.2014.08.034	journal	October 2014
Roles of Surface Chemistry on Safety and Electrochemistry in Lithium Ion Batteries Lee, Kyu Tae; Jeong, Sookyung; Cho, Jaephil Accounts of Chemical Research, Vol. 46, Issue 5 https://doi.org/10.1021/ar200224h	journal	April 2012
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
A reflection on lithium-ion battery cathode chemistry Manthiram, Arumugam Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-15355-0	journal	March 2020
The state of understanding of the lithium-ion-battery graphite solid electrolyte interphase (SEI) and its relationship to formation cycling An, Seong Jin; Li, Jianlin; Daniel, Claus Carbon, Vol. 105 https://doi.org/10.1016/j.carbon.2016.04.008	journal	August 2016
Aluminum tri-isopropoxide as an alternative precursor for atomic layer deposition of aluminum oxide thin films Hashemi, Fatemeh S. M.; Cao, LiAo; Mattelaer, Felix Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 37, Issue 4 https://doi.org/10.1116/1.5093402	journal	July 2019
Enhanced cycleability of LiMn2O4 cathodes by atomic layer deposition of nanosized-thin Al2O3 coatings Guan, Dongsheng; Jeevarajan, Judith A.; Wang, Ying Nanoscale, Vol. 3, Issue 4 https://doi.org/10.1039/c0nr00939c	journal	January 2011
Band theory and Mott insulators: Hubbard U instead of Stoner I Anisimov, Vladimir I.; Zaanen, Jan; Andersen, Ole K. Physical Review B, Vol. 44, Issue 3, p. 943-954 https://doi.org/10.1103/PhysRevB.44.943	journal	July 1991
Layered Cathode Materials for Lithium-Ion Batteries: Review of Computational Studies on LiNi _{1– x – y} Co _x Mn _y O ₂ and LiNi _{1– x – y} Co _x Al _y O ₂ Chakraborty, Arup; Kunnikuruvan, Sooraj; Kumar, Sandeep Chemistry of Materials, Vol. 32, Issue 3 https://doi.org/10.1021/acs.chemmater.9b04066	journal	January 2020
Viscous flow reactor with quartz crystal microbalance for thin film growth by atomic layer deposition Elam, J. W.; Groner, M. D.; George, S. M. Review of Scientific Instruments, Vol. 73, Issue 8, p. 2981-2987 https://doi.org/10.1063/1.1490410	journal	August 2002
Ultrathin surface coatings to enhance cycling stability of LiMn2O4 cathode in lithium-ion batteries Guan, Dongsheng; Wang, Ying Ionics, Vol. 19, Issue 1 https://doi.org/10.1007/s11581-012-0717-9	journal	April 2012
Understanding the Role of Temperature and Cathode Composition on Interface and Bulk: Optimizing Aluminum Oxide Coatings for Li-Ion Cathodes Han, Binghong; Paulauskas, Tadas; Key, Baris ACS Applied Materials & Interfaces, Vol. 9, Issue 17 https://doi.org/10.1021/acsami.7b00595	journal	April 2017
Reaction and Growth Mechanisms in Al ₂ O ₃ deposited via Atomic Layer Deposition: Elucidating the Hydrogen Source Guerra-Nuñez, Carlos; Döbeli, Max; Michler, Johann Chemistry of Materials, Vol. 29, Issue 20 https://doi.org/10.1021/acs.chemmater.7b02759	journal	October 2017
High-throughput computational design of cathode coatings for Li-ion batteries Aykol, Muratahan; Kim, Soo; Hegde, Vinay I. Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms13779	journal	December 2016
Preparation of a new crystal form of manganese dioxide: λ-MnO₂ Hunter, James C. Journal of Solid State Chemistry, Vol. 39, Issue 2, p. 142-147 https://doi.org/10.1016/0022-4596(81)90323-6	journal	September 1981
First principles study of the atomic layer deposition of alumina by TMA–H ₂ O-process Weckman, Timo; Laasonen, Kari Physical Chemistry Chemical Physics, Vol. 17, Issue 26 https://doi.org/10.1039/C5CP01912E	journal	January 2015
Morphology regulation and carbon coating of LiMnPO4 cathode material for enhanced electrochemical performance Wang, Fei; Yang, Jun; Gao, Pengfei Journal of Power Sources, Vol. 196, Issue 23 https://doi.org/10.1016/j.jpowsour.2011.08.090	journal	December 2011
Quartz Crystal Microbalance Studies of Al ₂ O ₃ Atomic Layer Deposition Using Trimethylaluminum and Water at 125 °C ^† Wind, R. A.; George, S. M. The Journal of Physical Chemistry A, Vol. 114, Issue 3 https://doi.org/10.1021/jp9049268	journal	January 2010
Unearthing [3‐(Dimethylamino)propyl]aluminium(III) Complexes as Novel Atomic Layer Deposition (ALD) Precursors for Al₂O₃: Synthesis, Characterization and ALD Process Development Mai, Lukas; Gebhard, Maximilian; de los Arcos, Teresa Chemistry – A European Journal, Vol. 23, Issue 45 https://doi.org/10.1002/chem.201702939	journal	July 2017
The success story of graphite as a lithium-ion anode material – fundamentals, remaining challenges, and recent developments including silicon (oxide) composites Asenbauer, Jakob; Eisenmann, Tobias; Kuenzel, Matthias Sustainable Energy & Fuels, Vol. 4, Issue 11 https://doi.org/10.1039/D0SE00175A	journal	January 2020
Porous Alumina Protective Coatings on Palladium Nanoparticles by Self-Poisoned Atomic Layer Deposition Lu, Junling; Liu, Bin; Greeley, Jeffrey P. Chemistry of Materials, Vol. 24, Issue 11 https://doi.org/10.1021/cm300203s	journal	May 2012
Ultrathin Surface Modification by Atomic Layer Deposition on High Voltage Cathode LiNi _0.5 Mn _1.5 O ₄ for Lithium Ion Batteries Fang, Xin; Ge, Mingyuan; Rong, Jiepeng Energy Technology, Vol. 2, Issue 2 https://doi.org/10.1002/ente.201300102	journal	December 2013
Atomic layer deposition of Al2O3 thin films using dimethylaluminum isopropoxide and water Cho, Wontae; Sung, Kiwhan; An, Ki-Seok Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 21, Issue 4 https://doi.org/10.1116/1.1562184	journal	July 2003
Role of Disproportionation in the Dissolution of Mn from Lithium Manganate Spinel Benedek, Roy The Journal of Physical Chemistry C, Vol. 121, Issue 40 https://doi.org/10.1021/acs.jpcc.7b05940	journal	September 2017
The Influence of Ultrathin Amorphous ALD Alumina and Titania on the Rate Capability of Anatase TiO ₂ and LiMn ₂ O ₄ Lithium Ion Battery Electrodes Mattelaer, Felix; Vereecken, Philippe M.; Dendooven, Jolien Advanced Materials Interfaces, Vol. 4, Issue 13 https://doi.org/10.1002/admi.201601237	journal	March 2017
High-performance bilayer flexible resistive random access memory based on low-temperature thermal atomic layer deposition Fang, Run-Chen; Sun, Qing-Qing; Zhou, Peng Nanoscale Research Letters, Vol. 8, Issue 1 https://doi.org/10.1186/1556-276X-8-92	journal	January 2013
Reining in dissolved transition-metal ions Asl, Hooman Yaghoobnejad; Manthiram, Arumugam Science, Vol. 369, Issue 6500 https://doi.org/10.1126/science.abc5454	journal	July 2020
Practical guides for x-ray photoelectron spectroscopy: First steps in planning, conducting, and reporting XPS measurements Baer, Donald R.; Artyushkova, Kateryna; Richard Brundle, Christopher Journal of Vacuum Science & Technology A, Vol. 37, Issue 3 https://doi.org/10.1116/1.5065501	journal	May 2019
Operando Observations and First-Principles Calculations of Reduced Lithium Insertion in Au-Coated LiMn ₂ O ₄ Bassett, Kimberly L.; Warburton, Robert E.; Deshpande, Siddharth Advanced Materials Interfaces, Vol. 6, Issue 4 https://doi.org/10.1002/admi.201801923	journal	January 2019
Mechanism for Al2O3 Atomic Layer Deposition on LiMn2O4 from In Situ Measurements and Ab Initio Calculations Chen, Lin; Warburton, Robert E.; Chen, Kan-Sheng Chem, Vol. 4, Issue 10 https://doi.org/10.1016/j.chempr.2018.08.006	journal	October 2018
Mn(II) deposition on anodes and its effects on capacity fade in spinel lithium manganate–carbon systems Zhan, Chun; Lu, Jun; Jeremy Kropf, A. Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3437	journal	September 2013
Mechanisms of Degradation and Strategies for the Stabilization of Cathode–Electrolyte Interfaces in Li-Ion Batteries Cabana, Jordi; Kwon, Bob Jin; Hu, Linhua Accounts of Chemical Research, Vol. 51, Issue 2 https://doi.org/10.1021/acs.accounts.7b00482	journal	January 2018
Low-Temperature Al₂O₃ Atomic Layer Deposition Groner, M. D.; Fabreguette, F. H.; Elam, J. W. Chemistry of Materials, Vol. 16, Issue 4, p. 639-645 https://doi.org/10.1021/cm0304546	journal	February 2004
Enhanced Stability of LiCoO₂ Cathodes in Lithium-Ion Batteries Using Surface Modification by Atomic Layer Deposition Jung, Yoon Seok; Cavanagh, Andrew S.; Dillon, Anne C. Journal of The Electrochemical Society, Vol. 157, Issue 1, p. A75-A81 https://doi.org/10.1149/1.3258274	journal	January 2010
Improvement of the Cycling Performance and Thermal Stability of Lithium-Ion Batteries by Coating Cathode Materials with Al ₂ O ₃ Nano Layer Cao, Zhaoxia; Li, Yanlei; Shi, Mengjiao Journal of The Electrochemical Society, Vol. 164, Issue 2 https://doi.org/10.1149/2.1421702jes	journal	December 2016
Relationship between the electrochemical and particle properties of LiMn2O4 prepared by ultrasonic spray pyrolysis Matsuda, K.; Taniguchi, I. Journal of Power Sources, Vol. 132, Issue 1-2 https://doi.org/10.1016/j.jpowsour.2004.01.019	journal	May 2004
High voltage stability of LiCoO2 particles with a nano-scale Lipon coating Kim, Yoongu; Veith, Gabriel M.; Nanda, Jagjit Electrochimica Acta, Vol. 56, Issue 19 https://doi.org/10.1016/j.electacta.2011.03.070	journal	July 2011
Crystallographic facetting in solid-state reacted LiMn2O4 spinel powder Huang, Ming-Ren; Lin, Chi-Wen; Lu, Hong-Yang Applied Surface Science, Vol. 177, Issue 1-2 https://doi.org/10.1016/S0169-4332(01)00205-7	journal	June 2001
Lithium Titanate Epitaxial Coating on Spinel Lithium Manganese Oxide Surface for Improving the Performance of Lithium Storage Capability Li, Jili; Zhu, Youqi; Wang, Lin ACS Applied Materials & Interfaces, Vol. 6, Issue 21 https://doi.org/10.1021/am504319y	journal	October 2014
Particle morphology and electrochemical performances of spinel LiMn2O4 powders synthesized using ultrasonic spray pyrolysis method Taniguchi, I. Solid State Ionics, Vol. 146, Issue 3-4 https://doi.org/10.1016/S0167-2738(01)01016-5	journal	February 2002
Atomic Layer Deposition of AlN with Tris(Dimethylamido)Aluminum and NH₃ Liu, Guo; Deguns, Eric; Lecordier, Laurent ECS Transactions, Vol. 41, Issue 2 https://doi.org/10.1149/1.3633671	journal	October 2011
Improvement of the Thermal Stability of LiNi[sub 0.8]Co[sub 0.2]O[sub 2] Cathode by a SiO[sub x] Protective Coating Omanda, H.; Brousse, T.; Marhic, C. Journal of The Electrochemical Society, Vol. 151, Issue 6 https://doi.org/10.1149/1.1710892	journal	January 2004
From Coating to Dopant: How the Transition Metal Composition Affects Alumina Coatings on Ni-Rich Cathodes Han, Binghong; Key, Baris; Lapidus, Saul H. ACS Applied Materials & Interfaces, Vol. 9, Issue 47 https://doi.org/10.1021/acsami.7b13597	journal	November 2017
Ultrathin Coatings on Nano-LiCoO₂ for Li-Ion Vehicular Applications Scott, Isaac D.; Jung, Yoon Seok; Cavanagh, Andrew S. Nano Letters, Vol. 11, Issue 2, p. 414-418 https://doi.org/10.1021/nl1030198	journal	February 2011
Acid Ionization Constants of Alcohols. II. Acidities of Some Substituted Methanols and Related Compounds ^1,2 Ballinger, P.; Long, F. A. Journal of the American Chemical Society, Vol. 82, Issue 4 https://doi.org/10.1021/ja01489a008	journal	February 1960
Plasma-enhanced and thermal atomic layer deposition of Al ₂ O ₃ using dimethylaluminum isopropoxide, [Al(CH ₃ ) ₂ (μ-O ⁱ Pr)] ₂ , as an alternative aluminum precursor Potts, Stephen E.; Dingemans, Gijs; Lachaud, Christophe Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 30, Issue 2 https://doi.org/10.1116/1.3683057	journal	March 2012
Atomic Layer Deposition of Al ₂ O ₃ –Ga ₂ O ₃ Alloy Coatings for Li[Ni _0.5 Mn _0.3 Co _0.2 ]O ₂ Cathode to Improve Rate Performance in Li-Ion Battery Laskar, Masihhur R.; Jackson, David H. K.; Guan, Yingxin ACS Applied Materials & Interfaces, Vol. 8, Issue 16 https://doi.org/10.1021/acsami.5b11878	journal	April 2016
Core electron binding energies in some Group IIIA, VB, and VIB compounds McGuire, G. E.; Schweitzer, G. K.; Carlson, Thomas A. Inorganic Chemistry, Vol. 12, Issue 10 https://doi.org/10.1021/ic50128a045	journal	October 1973
Nonuniform Growth of Sub-2 Nanometer Atomic Layer Deposited Alumina Films on Lithium Nickel Manganese Cobalt Oxide Cathode Battery Materials Hoskins, Amanda L.; McNeary, W. Wilson; Millican, Samantha L. ACS Applied Nano Materials, Vol. 2, Issue 11 https://doi.org/10.1021/acsanm.9b01490	journal	October 2019
Direct Observation of Lattice Aluminum Environments in Li Ion Cathodes LiNi _{1– y – z} Co _y Al _z O ₂ and Al-Doped LiNi _x Mn _y Co _z O ₂ via ²⁷ Al MAS NMR Spectroscopy Dogan, Fulya; Vaughey, John T.; Iddir, Hakim ACS Applied Materials & Interfaces, Vol. 8, Issue 26 https://doi.org/10.1021/acsami.6b04516	journal	June 2016
Effects of ZnO coating on electrochemical performance and thermal stability of LiCoO2 as cathode material for lithium-ion batteries Chang, Wonyoung; Choi, Jung-Woo; Im, Jong-Choo Journal of Power Sources, Vol. 195, Issue 1 https://doi.org/10.1016/j.jpowsour.2009.06.104	journal	January 2010
High-Rate Spinel LiMn ₂ O ₄ (LMO) Following Carbonate Removal and Formation of Li-Rich Interface by ALD Treatment Young, Matthias J.; Letourneau, Steven; Warburton, Robert E. The Journal of Physical Chemistry C, Vol. 123, Issue 39 https://doi.org/10.1021/acs.jpcc.9b04418	journal	September 2019
A new method for the determination of the relative acidities of alcohols in alcoholic solutions. The nucleophilicities and competitive reactivities of alkoxides and phenoxides Reeve, Wilkins; Erikson, Charles M.; Aluotto, Patrick F. Canadian Journal of Chemistry, Vol. 57, Issue 20 https://doi.org/10.1139/v79-444	journal	October 1979
Catalyst Design with Atomic Layer Deposition O’Neill, Brandon J.; Jackson, David H. K.; Lee, Jechan ACS Catalysis, Vol. 5, Issue 3 https://doi.org/10.1021/cs501862h	journal	February 2015
Influence of annealing environment on the ALD-Al₂O₃/4H-SiC interface studied through XPS Usman, Muhammad; Arshad, Muhammad; Suvanam, Sethu Saveda Journal of Physics D: Applied Physics, Vol. 51, Issue 10 https://doi.org/10.1088/1361-6463/aaa9a1	journal	February 2018
Lithium transport through lithium-ion battery cathode coatings Xu, Shenzhen; Jacobs, Ryan M.; Nguyen, Ha M. Journal of Materials Chemistry A, Vol. 3, Issue 33 https://doi.org/10.1039/C5TA01664A	journal	January 2015
Conformal ZnO coatings on high surface area silica gel using atomic layer deposition Libera, J. A.; Elam, J. W.; Pellin, M. J. Thin Solid Films, Vol. 516, Issue 18 https://doi.org/10.1016/j.tsf.2007.11.044	journal	July 2008
Ionic and electronic conductivities of atomic layer deposition thin film coated lithium ion battery cathode particles Patel, Rajankumar L.; Park, Jonghyun; Liang, Xinhua RSC Advances, Vol. 6, Issue 101 https://doi.org/10.1039/C6RA20829K	journal	January 2016
On the Manganese Dissolution Process from LiMn₂O₄ Cathode Materials Tesfamhret, Yonas; Liu, Haidong; Chai, Zhigang ChemElectroChem, Vol. 8, Issue 8 https://doi.org/10.1002/celc.202001496	journal	April 2021
Review—Manganese Dissolution from Spinel Cathode: Few Unanswered Questions Bhandari, Arihant; Bhattacharya, Jishnu Journal of The Electrochemical Society, Vol. 164, Issue 2 https://doi.org/10.1149/2.0101614jes	journal	December 2016
Atomic-Scale Tracking of a Phase Transition from Spinel to Rocksalt in Lithium Manganese Oxide Gao, Peng; Ishikawa, Ryo; Tochigi, Eita Chemistry of Materials, Vol. 29, Issue 3 https://doi.org/10.1021/acs.chemmater.6b03659	journal	January 2017
On the chemical kinetics of cyclopentadiene oxidation Robinson, R. K.; Lindstedt, R. P. Combustion and Flame, Vol. 158, Issue 4 https://doi.org/10.1016/j.combustflame.2010.12.001	journal	April 2011
Atomic Layer Deposition: An Overview George, Steven M. Chemical Reviews, Vol. 110, Issue 1, p. 111-131 https://doi.org/10.1021/cr900056b	journal	January 2010
Crystallinity of inorganic films grown by atomic layer deposition: Overview and general trends Miikkulainen, Ville; Leskelä, Markku; Ritala, Mikko Journal of Applied Physics, Vol. 113, Issue 2, Article No. 021301 https://doi.org/10.1063/1.4757907	journal	January 2013
Atomic Layered Coating Enabling Ultrafast Surface Kinetics at Silicon Electrodes in Lithium Ion Batteries Li, Juchuan; Xiao, Xingcheng; Cheng, Yang-Tse The Journal of Physical Chemistry Letters, Vol. 4, Issue 20 https://doi.org/10.1021/jz4018255	journal	September 2013
Enhancing the High-Voltage Cycling Performance of LiNi _0.5 Mn _0.3 Co _0.2 O ₂ by Retarding Its Interfacial Reaction with an Electrolyte by Atomic-Layer-Deposited Al ₂ O ₃ Su, Yantao; Cui, Suihan; Zhuo, Zengqing ACS Applied Materials & Interfaces, Vol. 7, Issue 45 https://doi.org/10.1021/acsami.5b05500	journal	November 2015

Similar Records

Descriptor-Based Analysis of Atomic Layer Deposition Mechanisms on Spinel LiMn₂O₄ Lithium-Ion Battery Cathodes

Journal Article · Tue Feb 04 00:00:00 EST 2020 · Chemistry of Materials · OSTI ID:2007747

Warburton, Robert E.; Young, Matthias J.; Letourneau, Steven; +2 more

High-Rate Spinel LiMn₂O₄ (LMO) Following Carbonate Removal and Formation of Li-Rich Interface by ALD Treatment

Journal Article · Fri Sep 06 00:00:00 EDT 2019 · Journal of Physical Chemistry. C · OSTI ID:2007747

Young, Matthias J.; Letourneau, Steven; Warburton, Robert E.; +4 more

Beneficial Effects of La _0.5 Sr _0.5 CoO ₃ Coatings on Thin‐Film LiMn ₂ O ₄ Cathodes for Lithium Ion Batteries

Journal Article · Sat May 13 00:00:00 EDT 2023 · Advanced Sustainable Systems · OSTI ID:2007747

Yu, Xiankai; Scipioni, Roberto; Xu, Yao‐bin; +3 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
lithium ion battery
atomic layer deposition
density functional theory
lithium manganese oxide
cathode

Title: Modification of LiMn2O4 surfaces by controlling the Acid–Base surface chemistry of atomic layer deposition

Citation Formats

References (102)

Similar Records

Related Subjects

Title: Modification of LiMn₂O₄ surfaces by controlling the Acid–Base surface chemistry of atomic layer deposition