P-V-T equation of state of boron carbide

Somayazulu, Maddury; Ahart, Muhtar; Meng, Yue; Ciezak, Jennifer; Velisavlevic, Nenad; Hemley, Russell J.

doi:10.1098/rsta.2022.0331

P-V-T equation of state of boron carbide

Journal Article · Mon Aug 28 00:00:00 EDT 2023 · Philosophical Transactions of the Royal Society. A, Mathematical, Physical and Engineering Sciences

DOI:https://doi.org/10.1098/rsta.2022.0331· OSTI ID:2006510

^[1]; Ahart, Muhtar ^[2]; Meng, Yue ^[3]; Ciezak, Jennifer ^[4]; Velisavlevic, Nenad ^[5]; Hemley, Russell J. ^[2]

Argonne National Laboratory (ANL), Argonne, IL (United States); University of Illinois Chicago
University of Illinois, Chicago, IL (United States)
Argonne National Laboratory (ANL), Argonne, IL (United States)
Army Research Laboratory, Aberdeen, MD (United States)
Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

We report the P-V-T equation of state measurements of B₄C to 50 GPa and approximately 2500 K in laser-heated diamond anvil cells. We obtain an ambient temperature, third-order Birch–Murnaghan fit to the P-V data that yields a bulk modulus K₀ of 221(2) GPa and derivative, (dK/dP)₀ of 3.3(1). These were used in fits with both a Mie–Grüneisen–Debye model and a temperature-dependent, Birch–Murnaghan equation of state that includes thermal pressure estimated by thermal expansion (α) and a temperature-dependent bulk modulus (dK₀/dT). The ambient pressure thermal expansion coefficient (α₀ + α₁T), Grüneisen γ(V) = γ₀(V/V₀)^q and volume-dependent Debye temperature, were used as input parameters for these fits and found to be sufficient to describe the data in the whole P-T range of this study.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States); University of Illinois, Chicago, IL (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities (SUF)

Grant/Contract Number:: AC02-06CH11357; AC52-07NA27344; NA0003975

OSTI ID:: 2006510

Alternate ID(s):: OSTI ID: 2404928

Journal Information:: Philosophical Transactions of the Royal Society. A, Mathematical, Physical and Engineering Sciences, Journal Name: Philosophical Transactions of the Royal Society. A, Mathematical, Physical and Engineering Sciences Journal Issue: 2258 Vol. 381; ISSN 1364-503X

Publisher:: The Royal Society PublishingCopyright Statement

Country of Publication:: United States

Language:: English

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36 MATERIALS SCIENCE
P-V-T equation of state
boron carbide
laser heating
synchrotron X-ray diffraction

P-V-T equation of state of boron carbide

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