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Title: Methods for manufacturing electrochemical sensors, and related electrochemical sensors

Patent ·
OSTI ID:1998330

Methods for manufacturing an electrochemical sensor include forming at least one electrode by printing at least one conductive ink on a surface of at least one substrate. The conductive ink may comprise, e.g., a platinum-group metal, another transition-group metal with a high-temperature melting point, a conductive ceramic material, glass-like carbon, or a combination thereof. The electrochemical sensor may be free of another material over the at least one electrode. An electrochemical sensor, formed according to such methods, may be configured for use in harsh environments (e.g., a molten salt environment). Electrodes of the electrochemical sensor comprise conductive material formed from a printed, conductive ink. In some embodiments, at least a portion of the electrochemical sensor is free of silver, gold, copper, silicon, and polymer materials, such portion being that which is to be exposed to the harsh environment during use of the electrochemical sensor.

Research Organization:
Idaho National Laboratory (INL), Idaho Falls, ID (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC07-05ID14517
Assignee:
Battelle Energy Ailiance, LLC (Idaho Falls, ID)
Patent Number(s):
11,635,404
Application Number:
16/840,102
OSTI ID:
1998330
Resource Relation:
Patent File Date: 04/03/2020
Country of Publication:
United States
Language:
English

References (17)

Copper-Substituted Perovskite Compositions for Solid Oxide Fuel Cell Cathodes and Oxygen Reduction Electrodes in Other Electrochemical Devices patent-application June 2010
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Electrochemical cells and methods using perovskites patent July 1997
Low Sintering Lanthanum Ferrite Materials for Use as Solid Oxide Fuel Cell Cathodes and Oxygen Reduction Electrodes and Other Electrochemical Devices patent-application October 2004
Electrochemical ethylene sensor and method for monitoring ethylene patent December 2015
Resonant gas sensor patent December 2019
Electrochemical Sensors and Methods for Making Electrochemical Sensors Using Advanced Printing Technology patent-application April 2017
Inkjet printing of carbon supported platinum 3-D catalyst layers for use in fuel cells journal September 2007
Voltammetric detector for flow analysis patent July 1992
Sol-Gel Derived High Performance Catalyst Thin Films for Sensors, Oxygen Separation Devices, and Solid Oxide Fuel Cells patent-application December 2009
Defect mitigation of thin-film hybrid perovskite and direct writing on a curved surface patent October 2019
Inkjet Printing Perovskite Ink and Method of Making the Same patent-application February 2019
Exhaust Gas Oxygen Sensor patent-application October 2005
Solid sensor electrode patent October 1977
Oxide-Ion Sensor for Use in a Molten-Salt Based Electrochemical Reduction Process patent-application May 2011
Method for forming perovskite solar cell with printable carbon electrode patent May 2019

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