Thixotropic spectra and Ashby-style charts for thixotropy

Sen, Samya; Ewoldt, Randy H.

doi:10.1122/8.0000446

Thixotropic spectra and Ashby-style charts for thixotropy

Journal Article · Thu Sep 01 04:00:00 EDT 2022 · Journal of Rheology

DOI:https://doi.org/10.1122/8.0000446· OSTI ID:1982940

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Department of Mechanical Science and Engineering, University of Illinois Urbana-Champaign, Urbana, Illinois 61801, USA; Beckman Institute for Advanced Science and Technology, University of Illinois Urbana-Champaign, Urbana, Illinois 61801, USA; Joint Center for Energy Storage Research, Argonne National Laboratory, Lemont, Illinois 60439, USA
Department of Mechanical Science and Engineering, University of Illinois Urbana-Champaign, Urbana, Illinois 61801, USA; Beckman Institute for Advanced Science and Technology, University of Illinois Urbana-Champaign, Urbana, Illinois 61801, USA; Joint Center for Energy Storage Research, Argonne National Laboratory, Lemont, Illinois 60439, USA; Materials Research Laboratory, University of Illinois Urbana-Champaign, Urbana, Illinois 61801, USA

There is no universal model for thixotropy, and comparing thixotropic effects between different fluids is a subtle yet challenging problem. We introduce a generalized (model-insensitive) framework for comparing thixotropic properties based on thixotropic spectra. A superposition of exponential stress modes distributed over thixotropic time scales is used to quantify buildup and breakdown times and mode strengths in response to step-change input. This mathematical framework is tested with several experimental step-shear rate data on colloidal suspensions. Low-dimensional metrics based on moments of the distribution reveal characteristic average thixotropic properties, which are visualized on Ashby-style diagrams. This method outlines a framework for describing thixotropy across a diverse range of microstructures, supporting scientific studies as well as material selection for engineering design applications.

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Joint Center for Energy Storage Research (JCESR)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC02-06CH11357

OSTI ID:: 1982940

Journal Information:: Journal of Rheology, Journal Name: Journal of Rheology Journal Issue: 5 Vol. 66; ISSN 0148-6055

Publisher:: Society of Rheology

Country of Publication:: United States

Language:: English

References (54)

Dye-sensitized solar cell based on blood mimetic thixotropy sol–gel electrolyte Jin, Liguo; Wu, Ze; Wei, Tianxin Chem. Commun., Vol. 47, Issue 3 https://doi.org/10.1039/C0CC04285D	journal	January 2011
Graphs in Statistical Analysis Anscombe, F. J. The American Statistician, Vol. 27, Issue 1 https://doi.org/10.1080/00031305.1973.10478966	journal	February 1973
On fitting data for parameter estimates: residual weighting and data representation Singh, Piyush K.; Soulages, Johannes M.; Ewoldt, Randy H. Rheologica Acta, Vol. 58, Issue 6-7 https://doi.org/10.1007/s00397-019-01135-1	journal	June 2019
Orthogonal versus parallel superposition measurements Vermant, J.; Walker, L.; Moldenaers, P. Journal of Non-Newtonian Fluid Mechanics, Vol. 79, Issue 2-3 https://doi.org/10.1016/S0377-0257(98)00105-0	journal	November 1998
A comprehensive constitutive law for waxy crude oil: a thixotropic yield stress fluid Dimitriou, Christopher J.; McKinley, Gareth H. Soft Matter, Vol. 10, Issue 35 https://doi.org/10.1039/C4SM00578C	journal	January 2014
Shear Banding of Soft Glassy Materials in Large Amplitude Oscillatory Shear Radhakrishnan, Rangarajan; Fielding, Suzanne M. Physical Review Letters, Vol. 117, Issue 18 https://doi.org/10.1103/PhysRevLett.117.188001	journal	October 2016
A model system for thixotropy studies Dullaert, Konraad; Mewis, Jan Rheologica Acta, Vol. 45, Issue 1 https://doi.org/10.1007/s00397-005-0439-2	journal	July 2005
New insights on carbon black suspension rheology—Anisotropic thixotropy and antithixotropy Wang, Yilin; Ewoldt, Randy H. Journal of Rheology, Vol. 66, Issue 5 https://doi.org/10.1122/8.0000455	journal	September 2022
Orthogonal superposition rheometry of colloidal gels: time-shear rate superposition Sung, Sang Hoon; Kim, Sunhyung; Hendricks, Jan Soft Matter, Vol. 14, Issue 42 https://doi.org/10.1039/C8SM01512K	journal	January 2018
The Mnemosyne number and the rheology of remembrance Jamali, Safa; McKinley, Gareth H. Journal of Rheology, Vol. 66, Issue 5 https://doi.org/10.1122/8.0000432	journal	September 2022
Time-Resolved Mechanical Spectroscopy of Soft Materials via Optimally Windowed Chirps Geri, Michela; Keshavarz, Bavand; Divoux, Thibaut Physical Review X, Vol. 8, Issue 4 https://doi.org/10.1103/PhysRevX.8.041042	journal	December 2018
Experimental Challenges of Shear Rheology: How to Avoid Bad Data Ewoldt, Randy H.; Johnston, Michael T.; Caretta, Lucas M. Complex Fluids in Biological Systems https://doi.org/10.1007/978-1-4939-2065-5_6	book	October 2014
Mechanical History Dependence in Carbon Black Suspensions for Flow Batteries: A Rheo-Impedance Study Narayanan, Aditya; Mugele, Frieder; Duits, Michael H. G. Langmuir, Vol. 33, Issue 7 https://doi.org/10.1021/acs.langmuir.6b04322	journal	February 2017
Viscoplastic drop impact on thin films Sen, Samya; Morales, Anthony G.; Ewoldt, Randy H. Journal of Fluid Mechanics, Vol. 891 https://doi.org/10.1017/jfm.2020.147	journal	March 2020
Characterization of physical aging by time-resolved rheometry: fundamentals and application to bituminous binders Laukkanen, Olli-Ville; Winter, H. Henning; Seppälä, Jukka Rheologica Acta, Vol. 57, Issue 11 https://doi.org/10.1007/s00397-018-1114-8	journal	September 2018
Quantitative rheological model selection: Good fits versus credible models using Bayesian inference Freund, Jonathan B.; Ewoldt, Randy H. Journal of Rheology, Vol. 59, Issue 3 https://doi.org/10.1122/1.4915299	journal	May 2015
Thixotropic rheology of semisolid metal suspensions Burgos, Gilmer R.; Alexandrou, Andreas N.; Entov, Vladimir Journal of Materials Processing Technology, Vol. 110, Issue 2 https://doi.org/10.1016/S0924-0136(00)00731-7	journal	March 2001
Investigations on the Thixotropy of Bentonite Suspensions Kelessidis, V. C. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, Vol. 30, Issue 18 https://doi.org/10.1080/15567030701456261	journal	July 2008
The Phenomenological Theory of Linear Viscoelastic Behavior Tschoegl, Nicholas W. Springer Berlin, Heidelberg https://doi.org/10.1007/978-3-642-73602-5	book	January 1989
Continuous relaxation spectra for constitutive models in medium-amplitude oscillatory shear Martinetti, Luca; Soulages, Johannes M.; Ewoldt, Randy H. Journal of Rheology, Vol. 62, Issue 5 https://doi.org/10.1122/1.5025080	journal	September 2018
Sticking and splashing in yield-stress fluid drop impacts on coated surfaces Blackwell, Brendan C.; Deetjen, Marc E.; Gaudio, Joseph E. Physics of Fluids, Vol. 27, Issue 4 https://doi.org/10.1063/1.4916620	journal	April 2015
Time-strain separability in medium-amplitude oscillatory shear Martinetti, Luca; Ewoldt, Randy H. Physics of Fluids, Vol. 31, Issue 2 https://doi.org/10.1063/1.5085025	journal	February 2019
Quantitative nonlinear thixotropic model with stretched exponential response in transient shear flows Wei, Yufei; Solomon, Michael J.; Larson, Ronald G. Journal of Rheology, Vol. 60, Issue 6 https://doi.org/10.1122/1.4965228	journal	November 2016
Simultaneous Rheoelectric Measurements of Strongly Conductive Complex Fluids Helal, Ahmed; Divoux, Thibaut; McKinley, Gareth H. Physical Review Applied, Vol. 6, Issue 6 https://doi.org/10.1103/PhysRevApplied.6.064004	journal	December 2016
Stretched exponential relaxation arising from a continuous sum of exponential decays Johnston, D. C. Physical Review B, Vol. 74, Issue 18 https://doi.org/10.1103/PhysRevB.74.184430	journal	November 2006
Thixotropy Mewis, Jan; Wagner, Norman J. Advances in Colloid and Interface Science, Vol. 147-148 https://doi.org/10.1016/j.cis.2008.09.005	journal	March 2009
Thixotropy in viscoplastic drop impact on thin films Sen, Samya; Morales, Anthony G.; Ewoldt, Randy H. Physical Review Fluids, Vol. 6, Issue 4 https://doi.org/10.1103/PhysRevFluids.6.043301	journal	April 2021
A thermodynamically consistent model for the thixotropic behavior of concentrated star polymer suspensions Beris, A. N.; Stiakakis, E.; Vlassopoulos, D. Journal of Non-Newtonian Fluid Mechanics, Vol. 152, Issue 1-3 https://doi.org/10.1016/j.jnnfm.2007.10.016	journal	June 2008
Thixotropy - a general review Mewis, J. Journal of Non-Newtonian Fluid Mechanics, Vol. 6, Issue 1 https://doi.org/10.1016/0377-0257(79)87001-9	journal	January 1979
3D printing with 2D colloids: designing rheology protocols to predict ‘printability’ of soft-materials Corker, Andrew; Ng, Henry C. -H.; Poole, Robert J. Soft Matter, Vol. 15, Issue 6 https://doi.org/10.1039/C8SM01936C	journal	January 2019
Microstructural and Rheological Properties of White Chocolate During Processing Glicerina, Virginia; Balestra, Federica; Rosa, Marco Dalla Food and Bioprocess Technology, Vol. 8, Issue 4 https://doi.org/10.1007/s11947-014-1443-2	journal	November 2014
A structural kinetics model for thixotropy Dullaert, Konraad; Mewis, Jan Journal of Non-Newtonian Fluid Mechanics, Vol. 139, Issue 1-2 https://doi.org/10.1016/j.jnnfm.2006.06.002	journal	November 2006
A methodology for adding thixotropy to Oldroyd-8 family of viscoelastic models for characterization of human blood Armstrong, Matthew; Tussing, Joseph Physics of Fluids, Vol. 32, Issue 9 https://doi.org/10.1063/5.0022501	journal	September 2020
Video: Stick or Splash? Thixotropy Decides! Sen, Samya; Ewoldt, Randy H. 71th Annual Meeting of the APS Division of Fluid Dynamics - Gallery of Fluid Motion https://doi.org/10.1103/APS.DFD.2018.GFM.V0036	conference	November 2018
Calculation of relaxation spectra from mechanical spectra in MATLAB Kontogiorgos, Vassilis Polymer Testing, Vol. 29, Issue 8 https://doi.org/10.1016/j.polymertesting.2010.09.007	journal	December 2010
Mathematical functions for the analysis of luminescence decays with underlying distributions 1. Kohlrausch decay function (stretched exponential) Berberan-Santos, M. N.; Bodunov, E. N.; Valeur, B. Chemical Physics, Vol. 315, Issue 1-2 https://doi.org/10.1016/j.chemphys.2005.04.006	journal	August 2005
A multimode structural kinetics constitutive equation for the transient rheology of thixotropic elasto-viscoplastic fluids Wei, Yufei; Solomon, Michael J.; Larson, Ronald G. Journal of Rheology, Vol. 62, Issue 1 https://doi.org/10.1122/1.4996752	journal	January 2018
Mapping linear viscoelasticity for design and tactile intuition Corman, R. E.; Ewoldt, Randy H. Applied Rheology, Vol. 29, Issue 1 https://doi.org/10.1515/arh-2019-0013	journal	January 2019
Thixotropy—a review Barnes, Howard A. Journal of Non-Newtonian Fluid Mechanics, Vol. 70, Issue 1-2 https://doi.org/10.1016/S0377-0257(97)00004-9	journal	May 1997
Constitutive equations for thixotropic fluids Larson, R. G. Journal of Rheology, Vol. 59, Issue 3 https://doi.org/10.1122/1.4913584	journal	May 2015
Yield stress materials in soft condensed matter Bonn, Daniel; Denn, Morton M.; Berthier, Ludovic Reviews of Modern Physics, Vol. 89, Issue 3 https://doi.org/10.1103/RevModPhys.89.035005	journal	August 2017
The measurement of thixotropy in absolute units Goodeve, C. F.; Whitfield, G. W. Transactions of the Faraday Society, Vol. 34 https://doi.org/10.1039/tf9383400511	journal	January 1938
Polysulfide Flow Batteries Enabled by Percolating Nanoscale Conductor Networks Fan, Frank Y.; Woodford, William H.; Li, Zheng Nano Letters, Vol. 14, Issue 4, p. 2210-2218 https://doi.org/10.1021/nl500740t	journal	March 2014
The Kinetics of Thixotropic Behaviour in Clay/Kaolin Aqueous Suspensions Alessandrini, Aldo; Lapasin, Romano; Sturzi, Franco Chemical Engineering Communications, Vol. 17, Issue 1-6 https://doi.org/10.1080/00986448208911610	journal	September 1982
Thixotropy, nonmonotonic stress relaxation, and the second law of thermodynamics Joshi, Yogesh M. Journal of Rheology, Vol. 66, Issue 1 https://doi.org/10.1122/8.0000363	journal	January 2022
Designing Complex Fluids Ewoldt, Randy H.; Saengow, Chaimongkol Annual Review of Fluid Mechanics, Vol. 54, Issue 1 https://doi.org/10.1146/annurev-fluid-031821-104935	journal	January 2022
Dynamic shear rheology of a thixotropic suspension: Comparison of an improved structure-based model with large amplitude oscillatory shear experiments Armstrong, Matthew J.; Beris, Antony N.; Rogers, Simon A. Journal of Rheology, Vol. 60, Issue 3 https://doi.org/10.1122/1.4943986	journal	May 2016
Multiscale Nature of Thixotropy and Rheological Hysteresis in Attractive Colloidal Suspensions under Shear Jamali, Safa; Armstrong, Robert C.; McKinley, Gareth H. Physical Review Letters, Vol. 123, Issue 24 https://doi.org/10.1103/PhysRevLett.123.248003	journal	December 2019
A review of thixotropy and its rheological modeling Larson, Ronald G.; Wei, Yufei Journal of Rheology, Vol. 63, Issue 3 https://doi.org/10.1122/1.5055031	journal	May 2019
Time-resolved rheometry Mours, M.; Winter, H. H. Rheologica Acta, Vol. 33, Issue 5 https://doi.org/10.1007/BF00366581	journal	January 1994
Carbopol gels: Elastoviscoplastic and slippery glasses made of individual swollen sponges Piau, J. M. Journal of Non-Newtonian Fluid Mechanics, Vol. 144, Issue 1 https://doi.org/10.1016/j.jnnfm.2007.02.011	journal	June 2007
Rheological Hysteresis in Soft Glassy Materials Divoux, Thibaut; Grenard, Vincent; Manneville, Sébastien Physical Review Letters, Vol. 110, Issue 1 https://doi.org/10.1103/PhysRevLett.110.018304	journal	January 2013
Video: Fire suppression with yield-stress fluids Blackwell, Brendan; Nadhan, Athrey; Wu, Alex 68th Annual Meeting of the APS Division of Fluid Dynamics - Gallery of Fluid Motion https://doi.org/10.1103/APS.DFD.2015.GFM.V0007	conference	November 2015
Solutions of Ill-Posed Problems (A. N. Tikhonov and V. Y. Arsenin) Willoughby, Ralph A. SIAM Review, Vol. 21, Issue 2 https://doi.org/10.1137/1021044	journal	April 1979

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