Thixotropic spectra and Ashby-style charts for thixotropy

Sen, Samya; Ewoldt, Randy H.

doi:10.1122/8.0000446

Thixotropic spectra and Ashby-style charts for thixotropy

Journal Article · Mon Aug 29 00:00:00 EDT 2022 · Journal of Rheology

DOI:https://doi.org/10.1122/8.0000446· OSTI ID:1884345

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There is no universal model for thixotropy, and comparing thixotropic effects between different fluids is a subtle yet challenging problem. We introduce a generalized (model-insensitive) framework for comparing thixotropic properties based on thixotropic spectra. A superposition of exponential stress modes distributed over thixotropic time scales is used to quantify buildup and breakdown times and mode strengths in response to step-change input. This mathematical framework is tested with several experimental step-shear rate data on colloidal suspensions. Low-dimensional metrics based on moments of the distribution reveal characteristic average thixotropic properties, which are visualized on Ashby-style diagrams. This method outlines a framework for describing thixotropy across a diverse range of microstructures, supporting scientific studies as well as material selection for engineering design applications.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

OSTI ID:: 1884345

Alternate ID(s):: OSTI ID: 1982940

Journal Information:: Journal of Rheology, Journal Name: Journal of Rheology Journal Issue: 5 Vol. 66; ISSN 0148-6055

Publisher:: Society of RheologyCopyright Statement

Country of Publication:: United States

Language:: English

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