Energy transfer in a type-I van der Waals heterostructure of WSe 2 /PtSe 2

Wang, Pengzhi; Wang, Yongsheng; Bian, Ang; Hao, Shengcai; Miao, Qing; Zhang, Xiaoxian; He, Jiaqi; He, Dawei; Zhao, Hui

doi:10.1088/2053-1583/ac75f2

Energy transfer in a type-I van der Waals heterostructure of WSe ₂ /PtSe ₂

Journal Article · 20 June 2022 · 2D Materials

DOI:https://doi.org/10.1088/2053-1583/ac75f2· OSTI ID:1979459

; Wang, Yongsheng; ; Hao, Shengcai; Miao, Qing; Zhang, Xiaoxian; He, Jiaqi; He, Dawei;

Abstract

Energy transfer of a van der Waals heterostructure formed by monolayers of WSe₂and PtSe₂is studied by steady-state photoluminescence (PL) and time-resolved transient absorption spectroscopy. The heterostructure sample is fabricated by transferring a mechanically exfoliated WSe₂monolayer onto a PtSe₂monolayer film obtained by chemical vapor deposition. The sample is thermally annealed to improve the interface quality. PL of the heterostructure is quenched by four times compared to the individual WSe₂monolayer, indicating excitation transfer from WSe₂to PtSe₂. Femtosecond transient absorption measurements with two configurations show that both the electrons and the holes can transfer from WSe₂to PtSe₂on a sub-picosecond time scale, while neither can transfer from PtSe₂to WSe₂. These results indicate that WSe₂and PtSe₂monolayers form a type-I band alignment with both the conduction band minimum and the valence band maximum in the PtSe₂layer.

Research Organization:: Univ. of Kansas, Lawrence, KS (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0020995

OSTI ID:: 1979459

Journal Information:: 2D Materials, Vol. 9, Issue 3; ISSN 2053-1583

Publisher:: IOP Publishing

Country of Publication:: United States

Language:: English

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