Textured Electrodes: Manipulating Built-In Crystallographic Heterogeneity of Metal Electrodes via Severe Plastic Deformation

Zheng, Jingxu; Deng, Yue; Yin, Jiefu; Tang, Tian; Garcia‐Mendez, Regina; Zhao, Qing; Archer, Lynden A.

doi:10.1002/adma.202106867

Textured Electrodes: Manipulating Built-In Crystallographic Heterogeneity of Metal Electrodes via Severe Plastic Deformation

Journal Article · Fri Oct 22 00:00:00 EDT 2021 · Advanced Materials

DOI:https://doi.org/10.1002/adma.202106867· OSTI ID:1976199

Zheng, Jingxu ^[1]; Deng, Yue ^[2]; Yin, Jiefu ^[2]; Tang, Tian ^[2]; ^[2]; Zhao, Qing ^[2]; ^[2]

Cornell University, Ithaca, NY (United States); Massachusetts Institute of Technology (MIT), Cambridge, MA (United States); OSTI
Cornell University, Ithaca, NY (United States)

Control of crystallography of metal electrodeposit films has recently emerged as a key to achieving long operating lifetimes in next-generation batteries. It is reported that the large crystallographic heterogeneity, e.g., broad orientational distribution, that appears characteristic of commercial metal foils, results in rough morphology upon plating/stripping. On this basis, an accumulative roll bonding (ARB) methodology—a severe plastic deformation process—is developed. Zn metal is used as a first example to interrogate the concept. It is demonstrated that the ARB process is highly effective in achieving uniform crystallographic control on macroscopic materials. After the ARB process, the Zn grains exhibit a strong (002) texture (i.e., [002]_Zn//ND). The texture transitions from a classical bipolar pattern to a nonclassical unipolar pattern under large nominal strain eliminate the orientational heterogeneity of the foil. The strongly (002)-textured Zn remarkably improves the plating/stripping performance by nearly two orders of magnitude under practical conditions. The performance improvements are readily scaled to achieve pouch-type full batteries that deliver exceptional reversibility. The ARB process can, in principle, be applied to any metal chemistry to achieve similar crystallographic uniformity, provided the appropriate temperature and accumulated strains are employed. Here this concept is evaluated using commercial Li and Na foils, which, unlike Zn (HCP), are BCC crystals. The simple process for creating strong textures in both hexagonal and cubic metals and illustrating the critical role such built-in crystallography plays underscores opportunities for developing highly reversible thin metal anodes (e.g., hexagonal Zn, Mg, and cubic Li, Na, Ca, Al).

View Accepted Manuscript (DOE)

Research Organization:: State University of New York (SUNY), Albany, NY (United States); Cornell University, Ithaca, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)

Grant/Contract Number:: SC0012673

OSTI ID:: 1976199

Alternate ID(s):: OSTI ID: 1830258

Journal Information:: Advanced Materials, Journal Name: Advanced Materials Journal Issue: 1 Vol. 34; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

References (54)

Designing Dendrite‐Free Zinc Anodes for Advanced Aqueous Zinc Batteries Hao, Junnan; Li, Xiaolong; Zhang, Shilin Advanced Functional Materials, Vol. 30, Issue 30 https://doi.org/10.1002/adfm.202001263	journal	June 2020
Surface‐Preferred Crystal Plane for a Stable and Reversible Zinc Anode Zhou, Miao; Guo, Shan; Li, Jialin Advanced Materials, Vol. 33, Issue 21 https://doi.org/10.1002/adma.202100187	journal	April 2021
Chemical Synthesis of 3D Graphene-Like Cages for Sodium-Ion Batteries Applications Cao, Xinxin; Pan, Anqiang; Liu, Sainan Advanced Energy Materials, Vol. 7, Issue 20 https://doi.org/10.1002/aenm.201700797	journal	July 2017
Plating/Stripping Behavior of Actual Lithium Metal Anode Liu, He; Cheng, Xin‐Bing; Xu, Rui Advanced Energy Materials, Vol. 9, Issue 44 https://doi.org/10.1002/aenm.201902254	journal	October 2019
Going beyond Intercalation Capacity of Aqueous Batteries by Exploiting Conversion Reactions of Mn and Zn electrodes for Energy‐Dense Applications Yadav, Gautam G.; Cho, Jungsang; Turney, Damon Advanced Energy Materials, Vol. 9, Issue 48 https://doi.org/10.1002/aenm.201902270	journal	November 2019
The Failure of Solid Electrolyte Interphase on Li Metal Anode: Structural Uniformity or Mechanical Strength? Shen, Xin; Zhang, Rui; Chen, Xiang Advanced Energy Materials, Vol. 10, Issue 10 https://doi.org/10.1002/aenm.201903645	journal	March 2020
Opportunities and Reality of Aqueous Rechargeable Batteries Shin, Jaeho; Choi, Jang Wook Advanced Energy Materials, Vol. 10, Issue 28 https://doi.org/10.1002/aenm.202001386	journal	June 2020
Anion Texturing Towards Dendrite‐Free Zn Anode for Aqueous Rechargeable Batteries Yuan, Du; Zhao, Jin; Ren, Hao Angewandte Chemie, Vol. 133, Issue 13 https://doi.org/10.1002/ange.202015488	journal	February 2021
Dendrite‐Free Epitaxial Growth of Lithium Metal during Charging in Li–O ₂ Batteries Xin, Xing; Ito, Kimihiko; Dutta, Arghya Angewandte Chemie International Edition, Vol. 57, Issue 40 https://doi.org/10.1002/anie.201808154	journal	October 2018
Stabilizing Zinc Electrodeposition in a Battery Anode by Controlling Crystal Growth Jin, Shuo; Zhang, Duhan; Sharma, Arpita Small, Vol. 17, Issue 33 https://doi.org/10.1002/smll.202101798	journal	July 2021
The effect of grain size on the high-strain, high-strain-rate behavior of copper Meyers, Marc A.; Andrade, Umberto R.; Chokshi, Atul H. Metallurgical and Materials Transactions A, Vol. 26, Issue 11 https://doi.org/10.1007/BF02669646	journal	November 1995
Large strain deformation of polycrystalline metals at low homologous temperatures Hockett, J. E.; Sherby, O. D. Journal of the Mechanics and Physics of Solids, Vol. 23, Issue 2 https://doi.org/10.1016/0022-5096(75)90018-6	journal	April 1975
A note on the deformation of fine grained magnesium alloys Lahaie, D.; Embury, J. D.; Chadwick, M. M. Scripta Metallurgica et Materialia, Vol. 27, Issue 2 https://doi.org/10.1016/0956-716X(92)90102-K	journal	July 1992
A new electropolishing technique for metallographic specimen preparation of zinc and zinc alloys Kovacheva, Rosiza; Gidikova, Neli; Lilova, Albena Materials Characterization, Vol. 28, Issue 4 https://doi.org/10.1016/1044-5803(92)90082-S	journal	June 1992
Texture analysis in hexagonal materials Wang, Y. N.; Huang, J. C. Materials Chemistry and Physics, Vol. 81, Issue 1 https://doi.org/10.1016/S0254-0584(03)00168-8	journal	July 2003
Corrosion resistance and microstructure of electrodeposited Zn and Zn alloy coatings Ramanauskas, R.; Quintana, P.; Maldonado, L. Surface and Coatings Technology, Vol. 92, Issue 1-2 https://doi.org/10.1016/S0257-8972(96)03125-8	journal	June 1997
Electrochemical Performance of Zn(002) and Zn(100) Single Crystals in 6.0mol·L−1 KOH Wang, Huaqing; Zhou, Shangqi; Chen, Changguo Chinese Journal of Chemical Engineering, Vol. 14, Issue 4 https://doi.org/10.1016/S1004-9541(06)60113-4	journal	August 2006
The onset of twinning in metals: a constitutive description Meyers, M. A.; Vöhringer, O.; Lubarda, V. A. Acta Materialia, Vol. 49, Issue 19 https://doi.org/10.1016/S1359-6454(01)00300-7	journal	November 2001
Texture, microstructure and mechanical properties of equiaxed ultrafine-grained Zr fabricated by accumulative roll bonding Jiang, L. Acta Materialia, Vol. 56, Issue 6 https://doi.org/10.1016/j.actamat.2007.11.017	journal	April 2008
Impact of anode substrates on electrodeposited zinc over cycling in zinc-anode rechargeable alkaline batteries Wei, Xia; Desai, Divyaraj; Yadav, Gautam G. Electrochimica Acta, Vol. 212 https://doi.org/10.1016/j.electacta.2016.07.041	journal	September 2016
Relationship between (00.2) and (20.1) texture components and corrosion resistance of hot-dip galvanized zinc coatings Asgari, H.; Toroghinejad, M. R.; Golozar, M. A. Journal of Materials Processing Technology, Vol. 198, Issue 1-3 https://doi.org/10.1016/j.jmatprotec.2007.06.068	journal	March 2008
The Age of Li-Ion Batteries Stephan, Alexandra K. Joule, Vol. 3, Issue 11 https://doi.org/10.1016/j.joule.2019.11.004	journal	November 2019
Electrodeposition of preferentially oriented zinc for flow-assisted alkaline batteries Desai, Divyaraj; Wei, Xia; Steingart, Daniel A. Journal of Power Sources, Vol. 256 https://doi.org/10.1016/j.jpowsour.2014.01.026	journal	June 2014
Artificial Interphases for Highly Stable Lithium Metal Anode Xu, Rui; Cheng, Xin-Bing; Yan, Chong Matter, Vol. 1, Issue 2 https://doi.org/10.1016/j.matt.2019.05.016	journal	August 2019
Microstructure and strength of severely deformed fcc metals Gubicza, J.; Chinh, N. Q.; Csanádi, T. Materials Science and Engineering: A, Vol. 462, Issue 1-2 https://doi.org/10.1016/j.msea.2006.02.455	journal	July 2007
Texture evolution maps for upset deformation of body-centered cubic metals Lee, Myoung-Gyu; Wang, Jue; Anderson, Peter M. Materials Science and Engineering: A, Vol. 463, Issue 1-2 https://doi.org/10.1016/j.msea.2006.11.159	journal	August 2007
Influences of crystallographic texture and nanostructural features on corrosion properties of electrogalvanized and chromate conversion coatings Jantaping, Narin; Schuh, Christopher A.; Boonyongmaneerat, Yuttanant Surface and Coatings Technology, Vol. 329 https://doi.org/10.1016/j.surfcoat.2017.09.022	journal	November 2017
Rechargeable Zinc Alkaline Anodes for Long-Cycle Energy Storage Turney, Damon E.; Gallaway, Joshua W.; Yadav, Gautam G. Chemistry of Materials, Vol. 29, Issue 11 https://doi.org/10.1021/acs.chemmater.7b00754	journal	May 2017
Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review Cheng, Xin-Bing; Zhang, Rui; Zhao, Chen-Zi Chemical Reviews, Vol. 117, Issue 15 https://doi.org/10.1021/acs.chemrev.7b00115	journal	July 2017
Deeply Rechargeable and Hydrogen-Evolution-Suppressing Zinc Anode in Alkaline Aqueous Electrolyte Zhang, Yamin; Wu, Yutong; You, Wenqin Nano Letters, Vol. 20, Issue 6 https://doi.org/10.1021/acs.nanolett.0c01776	journal	May 2020
Material Failure Mechanisms of Alkaline Zn Rechargeable Conversion Electrodes D’Ambrose, Michael J.; Turney, Damon E.; Yadav, Gautam G. ACS Applied Energy Materials, Vol. 4, Issue 4 https://doi.org/10.1021/acsaem.0c03144	journal	April 2021
Thermodynamic Overpotentials and Nucleation Rates for Electrodeposition on Metal Anodes Nagy, Kyle S.; Kazemiabnavi, Saeed; Thornton, Katsuyo ACS Applied Materials & Interfaces, Vol. 11, Issue 8 https://doi.org/10.1021/acsami.8b19787	journal	January 2019
Non-Dendritic Zn Electrodeposition Enabled by Zincophilic Graphene Substrates Foroozan, Tara; Yurkiv, Vitaliy; Sharifi-Asl, Soroosh ACS Applied Materials & Interfaces, Vol. 11, Issue 47 https://doi.org/10.1021/acsami.9b13174	journal	November 2019
Physical Orphaning versus Chemical Instability: Is Dendritic Electrodeposition of Li Fatal? Zheng, Jingxu; Tang, Tian; Zhao, Qing ACS Energy Letters, Vol. 4, Issue 6 https://doi.org/10.1021/acsenergylett.9b00750	journal	May 2019
Breaking the 2 V Barrier in Aqueous Zinc Chemistry: Creating 2.45 and 2.8 V MnO ₂ –Zn Aqueous Batteries Yadav, Gautam G.; Turney, Damon; Huang, Jinchao ACS Energy Letters, Vol. 4, Issue 9 https://doi.org/10.1021/acsenergylett.9b01643	journal	August 2019
Electrochemical Energy Storage for Green Grid Yang, Zhenguo; Zhang, Jianlu; Kintner-Meyer, Michael C. W. Chemical Reviews, Vol. 111, Issue 5, p. 3577-3613 https://doi.org/10.1021/cr100290v	journal	May 2011
Regenerable Cu-intercalated MnO2 layered cathode for highly cyclable energy dense batteries Yadav, Gautam G.; Gallaway, Joshua W.; Turney, Damon E. Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14424	journal	March 2017
Nanostructuring of metals by severe plastic deformation for advanced properties Valiev, Ruslan Nature Materials, Vol. 3, Issue 8 https://doi.org/10.1038/nmat1180	journal	August 2004
Reviving the lithium metal anode for high-energy batteries Lin, Dingchang; Liu, Yayuan; Cui, Yi Nature Nanotechnology, Vol. 12, Issue 3 https://doi.org/10.1038/nnano.2017.16	journal	March 2017
Aqueous rechargeable zinc/sodium vanadate batteries with enhanced performance from simultaneous insertion of dual carriers Wan, Fang; Zhang, Linlin; Dai, Xi Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-04060-8	journal	April 2018
Fluorinated interphase enables reversible aqueous zinc battery chemistries Cao, Longsheng; Li, Dan; Pollard, Travis Nature Nanotechnology, Vol. 16, Issue 8 https://doi.org/10.1038/s41565-021-00905-4	journal	May 2021
Regulating electrodeposition morphology of lithium: towards commercially relevant secondary Li metal batteries Zheng, Jingxu; Kim, Mun Sek; Tu, Zhengyuan Chemical Society Reviews, Vol. 49, Issue 9 https://doi.org/10.1039/C9CS00883G	journal	January 2020
Understanding additive controlled lithium morphology in lithium metal batteries Kasse, Robert M.; Geise, Natalie R.; Ko, Jesse S. Journal of Materials Chemistry A, Vol. 8, Issue 33 https://doi.org/10.1039/D0TA06020H	journal	January 2020
Strong texturing of lithium metal in batteries Shi, Feifei; Pei, Allen; Vailionis, Arturas Proceedings of the National Academy of Sciences, Vol. 114, Issue 46 https://doi.org/10.1073/pnas.1708224114	journal	October 2017
Quantitative phase-field modeling of dendritic electrodeposition Cogswell, Daniel A. Physical Review E, Vol. 92, Issue 1 https://doi.org/10.1103/PhysRevE.92.011301	journal	July 2015
Controlling electrochemical growth of metallic zinc electrodes: Toward affordable rechargeable energy storage systems Zheng, Jingxu; Archer, Lynden A. Science Advances, Vol. 7, Issue 2 https://doi.org/10.1126/sciadv.abe0219	journal	January 2021
Electrical Energy Storage and Intercalation Chemistry Whittingham, M. S. Science, Vol. 192, Issue 4244 https://doi.org/10.1126/science.192.4244.1126	journal	June 1976
Aircraft Gas Turbine Materials and Processes Kear, B. H.; Thompson, E. R. Science, Vol. 208, Issue 4446 https://doi.org/10.1126/science.208.4446.847	journal	May 1980
Singular angular magnetoresistance in a magnetic nodal semimetal Suzuki, T.; Savary, L.; Liu, J. -P. Science, Vol. 365, Issue 6451 https://doi.org/10.1126/science.aat0348	journal	June 2019
Reversible epitaxial electrodeposition of metals in battery anodes Zheng, Jingxu; Zhao, Qing; Tang, Tian Science, Vol. 366, Issue 6465 https://doi.org/10.1126/science.aax6873	journal	October 2019
The Ruben Cell—A New Alkaline Primary Dry Cell Battery Friedman, Maurice; McCauley, Charles E. Transactions of The Electrochemical Society, Vol. 92, Issue 1 https://doi.org/10.1149/1.3071815	journal	January 1947
Understanding the Dynamics of Primary Zn-MnO ₂ Alkaline Battery Gassing with Operando Visualization and Pressure Cells Faegh, Ehsan; Omasta, Travis; Hull, Matthew Journal of The Electrochemical Society, Vol. 165, Issue 11 https://doi.org/10.1149/2.0321811jes	journal	January 2018
Anode Characterization in Zinc-Manganese Dioxide AA Alkaline Batteries Using Electrochemical-Acoustic Time-of-Flight Analysis Bhadra, S.; Hsieh, A. G.; Wang, M. J. Journal of The Electrochemical Society, Vol. 163, Issue 6 https://doi.org/10.1149/2.1201606jes	journal	January 2016
Texture Evolution in Severe Plastic Deformation Processes Suwas, Satyam; Mondal, Soumita MATERIALS TRANSACTIONS, Vol. 60, Issue 8 https://doi.org/10.2320/matertrans.MF201933	journal	January 2019

Similar Records

Design principles for heterointerfacial alloying kinetics at metallic anodes in rechargeable batteries

Journal Article · Fri Nov 04 00:00:00 EDT 2022 · Science Advances · OSTI ID:2420258

Reversible epitaxial electrodeposition of metals in battery anodes

Journal Article · Thu Oct 31 00:00:00 EDT 2019 · Science · OSTI ID:1572594

Related Subjects

36 MATERIALS SCIENCE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
71 CLASSICAL AND QUANTUM MECHANICS
GENERAL PHYSICS

Textured Electrodes: Manipulating Built-In Crystallographic Heterogeneity of Metal Electrodes via Severe Plastic Deformation

Citation Formats

References (54)

Similar Records

Related Subjects