Reversible epitaxial electrodeposition of metals in battery anodes

Zheng, Jingxu; Zhao, Qing; Tang, Tian; Yin, Jiefu; Quilty, Calvin D.; Renderos, Genesis D.; Liu, Xiaotun; Deng, Yue; Wang, Lei; Bock, David C.; Jaye, Cherno; Zhang, Duhan; Takeuchi, Esther S.; Takeuchi, Kenneth J.; Marschilok, Amy C.; Archer, Lynden A.

doi:10.1126/science.aax6873

Title: Reversible epitaxial electrodeposition of metals in battery anodes

Journal Article · Thu Oct 31 00:00:00 EDT 2019 · Science

DOI:https://doi.org/10.1126/science.aax6873· OSTI ID:1572594

^[1];

^[2];

^[1]; Yin, Jiefu ^[2];

^[3];

^[2];

^[1];

^[4];

^[5];

^[6]; Takeuchi, Esther S. ^[7]; Takeuchi, Kenneth J. ^[8];

^[7];

^[9]

Department of Materials Science and Engineering, Cornell University, Ithaca, NY 14853, USA.
Robert Frederick Smith School of Chemical and Biomolecular Engineering, Cornell University, Ithaca, NY 14853, USA.
Department of Chemistry, Stony Brook University, Stony Brook, NY 11794, USA.
Energy Sciences Directorate, Brookhaven National Laboratory, Interdisciplinary Sciences Building, Building 734, Upton, NY 11973, USA.
Material Measurement Laboratory, National Institute of Standards and Technology, Gaithersburg, MD 20899, USA.
Sibley School of Mechanical and Aerospace Engineering, Cornell University, Ithaca, NY 14853, USA.
Department of Chemistry, Stony Brook University, Stony Brook, NY 11794, USA., Energy Sciences Directorate, Brookhaven National Laboratory, Interdisciplinary Sciences Building, Building 734, Upton, NY 11973, USA., Department of Materials Science and Chemical Engineering, Stony Brook, NY 11794, USA.
Department of Chemistry, Stony Brook University, Stony Brook, NY 11794, USA., Energy Sciences Directorate, Brookhaven National Laboratory, Interdisciplinary Sciences Building, Building 734, Upton, NY 11973, USA.
Department of Materials Science and Engineering, Cornell University, Ithaca, NY 14853, USA., Robert Frederick Smith School of Chemical and Biomolecular Engineering, Cornell University, Ithaca, NY 14853, USA.

The propensity of metals to form irregular and nonplanar electrodeposits at liquid-solid interfaces has emerged as a fundamental barrier to high-energy, rechargeable batteries that use metal anodes. We report an epitaxial mechanism to regulate nucleation, growth, and reversibility of metal anodes. The crystallographic, surface texturing, and electrochemical criteria for reversible epitaxial electrodeposition of metals are defined and their effectiveness demonstrated by using zinc (Zn), a safe, low-cost, and energy-dense battery anode material. Graphene, with a low lattice mismatch for Zn, is shown to be effective in driving deposition of Zn with a locked crystallographic orientation relation. The resultant epitaxial Zn anodes achieve exceptional reversibility over thousands of cycles at moderate and high rates. Reversible electrochemical epitaxy of metals provides a general pathway toward energy-dense batteries with high reversibility.

View Journal Article

Cite

Export

Save

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2mt); Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division

Grant/Contract Number:: SC0012673; SC0012704; SC00112704; AC02-98CH10886; DMR-1719875; DMR-1338010

OSTI ID:: 1572594

Alternate ID(s):: OSTI ID: 1580222

Report Number(s):: BNL-212445-2019-JAAM; /sci/366/6465/645.atom

Journal Information:: Science, Journal Name: Science Vol. 366 Journal Issue: 6465; ISSN 0036-8075

Publisher:: American Association for the Advancement of Science (AAAS)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 699 works

Citation information provided by
Web of Science

References (36)

Cryo-STEM mapping of solid–liquid interfaces and dendrites in lithium-metal batteries Zachman, Michael J.; Tu, Zhengyuan; Choudhury, Snehashis Nature, Vol. 560, Issue 7718 https://doi.org/10.1038/s41586-018-0397-3	journal	August 2018
Physical Orphaning versus Chemical Instability: Is Dendritic Electrodeposition of Li Fatal? Zheng, Jingxu; Tang, Tian; Zhao, Qing ACS Energy Letters, Vol. 4, Issue 6 https://doi.org/10.1021/acsenergylett.9b00750	journal	May 2019
Epitaxial deposition of metals on uniaxial oriented semi-crystalline polymers Petermann, J.; Broza, G. Journal of Materials Science, Vol. 22, Issue 3 https://doi.org/10.1007/BF01103557	journal	March 1987
Mass Synthesis of Large, Single-Crystal Au Nanosheets Based on a Polyol Process Li, C. C.; Cai, W. P.; Cao, B. Q. Advanced Functional Materials, Vol. 16, Issue 1 https://doi.org/10.1002/adfm.200500209	journal	January 2006
Solid electrolyte interphases for high-energy aqueous aluminum electrochemical cells Zhao, Qing; Zachman, Michael J.; Al Sadat, Wajdi I. Science Advances, Vol. 4, Issue 11 https://doi.org/10.1126/sciadv.aau8131	journal	November 2018
Origin of Electrochemical, Structural, and Transport Properties in Nonaqueous Zinc Electrolytes Han, Sang-Don; Rajput, Nav Nidhi; Qu, Xiaohui ACS Applied Materials & Interfaces, Vol. 8, Issue 5 https://doi.org/10.1021/acsami.5b10024	journal	January 2016
Avoiding short circuits from zinc metal dendrites in anode by backside-plating configuration Higashi, Shougo; Lee, Seok Woo; Lee, Jang Soo Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms11801	journal	June 2016
An ultrafast rechargeable aluminium-ion battery Lin, Meng-Chang; Gong, Ming; Lu, Bingan Nature, Vol. 520, Issue 7547 https://doi.org/10.1038/nature14340	journal	April 2015
Electrodeposition of Epitaxial Cu(111) Thin Films on Au(111) Using Defect-Mediated Growth Hwang, Seongpil; Oh, Ilwhan; Kwak, Juhyoun Journal of the American Chemical Society, Vol. 123, Issue 29 https://doi.org/10.1021/ja015666n	journal	July 2001
Conductive graphite fiber as a stable host for zinc metal anodes Wang, Li-Ping; Li, Nian-Wu; Wang, Tai-Shan Electrochimica Acta, Vol. 244 https://doi.org/10.1016/j.electacta.2017.05.072	journal	August 2017
Computer Simulation of Dendritic Electrodeposition Voss, Richard F. Journal of The Electrochemical Society, Vol. 132, Issue 2 https://doi.org/10.1149/1.2113841	journal	January 1985
Nanoscale Nucleation and Growth of Electrodeposited Lithium Metal Pei, Allen; Zheng, Guangyuan; Shi, Feifei Nano Letters, Vol. 17, Issue 2 https://doi.org/10.1021/acs.nanolett.6b04755	journal	January 2017
Highly Reversible and Rechargeable Safe Zn Batteries Based on a Triethyl Phosphate Electrolyte Naveed, Ahmad; Yang, Huijun; Yang, Jun Angewandte Chemie, Vol. 131, Issue 9 https://doi.org/10.1002/ange.201813223	journal	January 2019
Metal electrodeposition on single crystal metal surfaces mechanisms, structure and applications Allongue, P.; Maroun, F. Current Opinion in Solid State and Materials Science, Vol. 10, Issue 3-4 https://doi.org/10.1016/j.cossms.2007.04.001	journal	June 2006
Reviving the lithium metal anode for high-energy batteries Lin, Dingchang; Liu, Yayuan; Cui, Yi Nature Nanotechnology, Vol. 12, Issue 3 https://doi.org/10.1038/nnano.2017.16	journal	March 2017
Orientation dynamics of dilute functionalized graphene suspensions in oscillatory flow Natale, Giovanniantonio; Reddy, Naveen K.; Prud'homme, Robert K. Physical Review Fluids, Vol. 3, Issue 6 https://doi.org/10.1103/PhysRevFluids.3.063303	journal	June 2018
Electrical Energy Storage and Intercalation Chemistry Whittingham, M. S. Science, Vol. 192, Issue 4244 https://doi.org/10.1126/science.192.4244.1126	journal	June 1976
Electrochemical Epitaxial Growth of a Pt(111) Phase on an Au(111) Electrode Uosaki, Kohei; Ye, Shen; Naohara, Hideo The Journal of Physical Chemistry B, Vol. 101, Issue 38 https://doi.org/10.1021/jp9717406	journal	September 1997
Design principles for electrolytes and interfaces for stable lithium-metal batteries Tikekar, Mukul D.; Choudhury, Snehashis; Tu, Zhengyuan Nature Energy, Vol. 1, Issue 9 https://doi.org/10.1038/nenergy.2016.114	journal	September 2016
Rechargeable aqueous zinc-manganese dioxide batteries with high energy and power densities Zhang, Ning; Cheng, Fangyi; Liu, Junxiang Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-00467-x	journal	September 2017
“Water-in-deep eutectic solvent” electrolytes enable zinc metal anodes for rechargeable aqueous batteries Zhao, Jingwen; Zhang, Jian; Yang, Wuhai Nano Energy, Vol. 57 https://doi.org/10.1016/j.nanoen.2018.12.086	journal	March 2019
A high-capacity and long-life aqueous rechargeable zinc battery using a metal oxide intercalation cathode Kundu, Dipan; Adams, Brian D.; Duffort, Victor Nature Energy, Vol. 1, Issue 10 https://doi.org/10.1038/nenergy.2016.119	journal	August 2016
Transformation of Leaf-like Zinc Dendrite in Oxidation and Reduction Cycle Nakata, Akiyoshi; Murayama, Haruno; Fukuda, Katsutoshi Electrochimica Acta, Vol. 166 https://doi.org/10.1016/j.electacta.2015.03.076	journal	June 2015
Suppression of Dendrite Formation and Corrosion on Zinc Anode of Secondary Aqueous Batteries Sun, Kyung E. K.; Hoang, Tuan K. A.; Doan, The Nam Long ACS Applied Materials & Interfaces, Vol. 9, Issue 11 https://doi.org/10.1021/acsami.6b16560	journal	March 2017
Nonplanar Electrode Architectures for Ultrahigh Areal Capacity Batteries Zheng, Jingxu; Zhao, Qing; Liu, Xiaotun ACS Energy Letters, Vol. 4, Issue 1 https://doi.org/10.1021/acsenergylett.8b02131	journal	December 2018
Electrodeposited Epitaxial Cu(100) on Si(100) and Lift-Off of Single Crystal-like Cu(100) Foils Hull, Caleb M.; Switzer, Jay A. ACS Applied Materials & Interfaces, Vol. 10, Issue 44 https://doi.org/10.1021/acsami.8b13188	journal	October 2018
An overview of progress in electrolytes for secondary zinc-air batteries and other storage systems based on zinc Mainar, Aroa R.; Iruin, Elena; Colmenares, Luis C. Journal of Energy Storage, Vol. 15 https://doi.org/10.1016/j.est.2017.12.004	journal	February 2018
Atomic structure of sensitive battery materials and interfaces revealed by cryo–electron microscopy Li, Yuzhang; Li, Yanbin; Pei, Allen Science, Vol. 358, Issue 6362 https://doi.org/10.1126/science.aam6014	journal	October 2017
Highly reversible zinc metal anode for aqueous batteries Wang, Fei; Borodin, Oleg; Gao, Tao Nature Materials, Vol. 17, Issue 6 https://doi.org/10.1038/s41563-018-0063-z	journal	April 2018
Dendrite-Free Nanocrystalline Zinc Electrodeposition from an Ionic Liquid Containing Nickel Triflate for Rechargeable Zn-Based Batteries Liu, Zhen; Cui, Tong; Pulletikurthi, Giridhar Angewandte Chemie International Edition, Vol. 55, Issue 8 https://doi.org/10.1002/anie.201509364	journal	January 2016
Transition of lithium growth mechanisms in liquid electrolytes Bai, Peng; Li, Ju; Brushett, Fikile R. Energy & Environmental Science, Vol. 9, Issue 10 https://doi.org/10.1039/C6EE01674J	journal	January 2016
Regenerable Cu-intercalated MnO2 layered cathode for highly cyclable energy dense batteries Yadav, Gautam G.; Gallaway, Joshua W.; Turney, Damon E. Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14424	journal	March 2017
Rechargeable nickel–3D zinc batteries: An energy-dense, safer alternative to lithium-ion Parker, Joseph F.; Chervin, Christopher N.; Pala, Irina R. Science, Vol. 356, Issue 6336 https://doi.org/10.1126/science.aak9991	journal	April 2017
Crystal Growth of Electrodeposited Zinc Sato, Ryoitiro Journal of The Electrochemical Society, Vol. 106, Issue 3 https://doi.org/10.1149/1.2427309	journal	January 1959
Status and challenges in enabling the lithium metal electrode for high-energy and low-cost rechargeable batteries Albertus, Paul; Babinec, Susan; Litzelman, Scott Nature Energy, Vol. 3, Issue 1 https://doi.org/10.1038/s41560-017-0047-2	journal	December 2017
The rechargeable aluminum-ion battery Jayaprakash, N.; Das, S. K.; Archer, L. A. Chemical Communications, Vol. 47, Issue 47 https://doi.org/10.1039/c1cc15779e	journal	January 2011

Cited By (5)

Highly Reversible Zn Anode Enabled by Controllable Formation of Nucleation Sites for Zn‐Based Batteries Liang, Pengcheng; Yi, Jin; Liu, Xiaoyu Advanced Functional Materials, Vol. 30, Issue 13 https://doi.org/10.1002/adfm.201908528	journal	March 2020
Proton Intercalation/De‐Intercalation Dynamics in Vanadium Oxides for Aqueous Aluminum Electrochemical Cells Zhao, Qing; Liu, Luojia; Yin, Jiefu Angewandte Chemie, Vol. 132, Issue 8 https://doi.org/10.1002/ange.201912634	journal	January 2020
Proton Insertion Chemistry of a Zinc–Organic Battery Tie, Zhiwei; Liu, Luojia; Deng, Shenzhen Angewandte Chemie, Vol. 132, Issue 12 https://doi.org/10.1002/ange.201916529	journal	February 2020
Proton Intercalation/De‐Intercalation Dynamics in Vanadium Oxides for Aqueous Aluminum Electrochemical Cells Zhao, Qing; Liu, Luojia; Yin, Jiefu Angewandte Chemie International Edition, Vol. 59, Issue 8 https://doi.org/10.1002/anie.201912634	journal	February 2020
Proton Insertion Chemistry of a Zinc–Organic Battery Tie, Zhiwei; Liu, Luojia; Deng, Shenzhen Angewandte Chemie International Edition, Vol. 59, Issue 12 https://doi.org/10.1002/anie.201916529	journal	February 2020

Similar Records

Regulating the growth of aluminum electrodeposits: towards anode-free Al batteries

Journal Article · Fri Sep 25 00:00:00 EDT 2020 · Journal of Materials Chemistry. A · OSTI ID:1572594

Zhao, Qing; Zheng, Jingxu; Deng, Yue; +1 more

On the Reversibility and Fragility of Sodium Metal Electrodes

Journal Article · Tue Aug 27 00:00:00 EDT 2019 · Advanced Energy Materials · OSTI ID:1572594

Deng, Yue; Zheng, Jingxu; Warren, Alexander; +5 more

Spontaneous and field-induced crystallographic reorientation of metal electrodeposits at battery anodes

Journal Article · Wed Jun 17 00:00:00 EDT 2020 · Science Advances · OSTI ID:1572594

Zheng, Jingxu; Yin, Jiefu; Zhang, Duhan; +13 more

Related Subjects

25 ENERGY STORAGE

Title: Reversible epitaxial electrodeposition of metals in battery anodes

Citation Formats

References (36)

Cited By (5)

Similar Records

Related Subjects