Effects of doping, hydrostatic pressure, and thermal quenching on the phase transitions and magnetocaloric properties in Mn1–xCoxNiGe

Chhetri, Tej Poudel; Chen, Jing-Han; Grant, Anthony T.; Young, David P.; Dubenko, Igor; Talapatra, Saikat; Ali, Naushad; Stadler, Shane

doi:10.1063/5.0100987

Title: Effects of doping, hydrostatic pressure, and thermal quenching on the phase transitions and magnetocaloric properties in Mn_1–xCo_xNiGe

Journal Article · Wed Jul 27 00:00:00 EDT 2022 · Journal of Applied Physics

DOI:https://doi.org/10.1063/5.0100987· OSTI ID:1975225

^[1];

^[1]; Grant, Anthony T. ^[1]; Young, David P. ^[1]; Dubenko, Igor ^[2]; Talapatra, Saikat ^[2]; Ali, Naushad ^[2]; Stadler, Shane ^[1]

Louisiana State University, Baton Rouge, LA (United States)
Southern Illinois University, Carbondale, IL (United States)

The effects of doping, hydrostatic pressure, and thermal quenching on the phase transitions and magnetocaloric properties of the Mn_1–xCo_xNiGe system have been investigated. Cobalt doping on the Mn site shifted the martensitic structural transition toward lower temperature until it was ultimately absent, leaving only a magnetic transition from a ferromagnetic (FM) to a paramagnetic (PM) state in the high-temperature hexagonal phase. Co-occurrence of the magnetic and structural transitions to form a first-order magnetostructural transition (MST) from the FM orthorhombic to the PM hexagonal phase was observed in samples with 0.05 < x < 0.20. An additional antiferromagnetic–ferromagnetic-like transition was observed in the martensite phase for 0.05 < x < 0.10, which gradually vanished with increasing Co concentration (x > 0.10) or magnetic field (H > 0.5 T). The application of external hydrostatic pressure shifted the structural transition to lower temperature until an MST was formed in samples with x = 0.03 and 0.05, inducing large magnetic entropy changes up to –80.3 J kg^–1 K^–1 (x = 0.03) for a 7-T field change under 10.6-kbar pressure. Similar to the effects of the application of hydrostatic pressure, an MST was formed near room temperature in the sample with x = 0.03 by annealing at high temperature (1200 °C) followed by quenching, resulting in a large magnetic entropy change of –56.2 J kg^–1 K^–1. Furthermore, these experimental results show that the application of pressure and thermal quenching, in addition to compositional variations, are effective methods to create magnetostructural transitions in the MnNiGe system, resulting in large magnetocaloric effects.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Louisiana State Univ., Baton Rouge, LA (United States); Southern Illinois Univ., Carbondale, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: FG02-13ER46946; SC0010521

OSTI ID:: 1975225

Alternate ID(s):: OSTI ID: 1878255

Journal Information:: Journal of Applied Physics, Vol. 132, Issue 4; ISSN 0021-8979

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

References (55)

Giant magnetocaloric effect of MnAs1−xSbx Wada, H.; Tanabe, Y. Applied Physics Letters, Vol. 79, Issue 20 https://doi.org/10.1063/1.1419048	journal	November 2001
Giant barocaloric effect in hexagonal Ni2In-type Mn-Co-Ge-In compounds around room temperature Wu, Rong-Rong; Bao, Li-Fu; Hu, Feng-Xia Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep18027	journal	December 2015
Giant magnetocaloric effect driven by structural transitions Liu, Jian; Gottschall, Tino; Skokov, Konstantin P. Nature Materials, Vol. 11, Issue 7 https://doi.org/10.1038/nmat3334	journal	May 2012
Giant magnetocaloric effects by tailoring the phase transitions Trung, N. T.; Zhang, L.; Caron, L. Applied Physics Letters, Vol. 96, Issue 17 https://doi.org/10.1063/1.3399773	journal	April 2010
Large negative magnetoresistance in a ferromagnetic shape memory alloy: Ni2+xMn1−xGa Biswas, C.; Rawat, R.; Barman, S. R. Applied Physics Letters, Vol. 86, Issue 20 https://doi.org/10.1063/1.1925757	journal	May 2005
Transition-metal-based magnetic refrigerants for room-temperature applications Tegus, O.; Brück, E.; Buschow, K. H. J. Nature, Vol. 415, Issue 6868 https://doi.org/10.1038/415150a	journal	January 2002
Giant magnetocaloric effect in isostructural MnNiGe-CoNiGe system by establishing a Curie-temperature window Liu, E. K.; Zhang, H. G.; Xu, G. Z. Applied Physics Letters, Vol. 102, Issue 12 https://doi.org/10.1063/1.4798318	journal	March 2013
Realization of magnetostructural coupling by modifying structural transitions in MnNiSi-CoNiGe system with a wide Curie-temperature window Liu, Jun; Gong, Yuanyuan; Xu, Guizhou Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep23386	journal	March 2016
Tuning martensitic transitions in (MnNiSi) _0.65 (Fe ₂ Ge) _0.35 through heat treatment and hydrostatic pressure Chen, Jing-Han; Us Saleheen, Ahmad; Karna, Sunil K. Journal of Applied Physics, Vol. 124, Issue 20 https://doi.org/10.1063/1.5051551	journal	November 2018
Magnetocaloric effect and negative thermal expansion in hexagonal Fe doped MnNiGe compounds with a magnetoelastic AFM-FM-like transition Xu, Kun; Li, Zhe; Liu, Enke Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/srep41675	journal	January 2017
Inverse magnetocaloric effect in ferromagnetic Ni50Mn37+xSb13−x Heusler alloys Khan, Mahmud; Ali, Naushad; Stadler, Shane Journal of Applied Physics, Vol. 101, Issue 5 https://doi.org/10.1063/1.2710779	journal	March 2007
The influence of hydrostatic pressure and annealing conditions on the magnetostructural transitions in MnCoGe Chen, Jing-Han; Poudel Chhetri, Tej; Chang, Chung-Kai Journal of Applied Physics, Vol. 129, Issue 21 https://doi.org/10.1063/5.0053671	journal	June 2021
Effects of heat treatments on magneto-structural phase transitions in MnNiSi-FeCoGe alloys Chen, Jing-Han; Poudel Chhetri, Tej; Us Saleheen, Ahmad Intermetallics, Vol. 112 https://doi.org/10.1016/j.intermet.2019.106547	journal	September 2019
Itinerant-electron metamagnetic transition and large magnetocaloric effects in $La ({Fe}_{x} {Si}_{1 - x})_{13}$ compounds and their hydrides Fujita, A.; Fujieda, S.; Hasegawa, Y. Physical Review B, Vol. 67, Issue 10 https://doi.org/10.1103/PhysRevB.67.104416	journal	March 2003
Large magnetic‐field‐induced strains in Ni ₂ MnGa single crystals Ullakko, K.; Huang, J. K.; Kantner, C. Applied Physics Letters, Vol. 69, Issue 13 https://doi.org/10.1063/1.117637	journal	September 1996
Crystal and magnetic structure of CoxNi1-xMnGe system Nizioł, S.; Bombik, A.; Baz̊ela, W. Journal of Magnetism and Magnetic Materials, Vol. 27, Issue 3 https://doi.org/10.1016/0304-8853(82)90087-7	journal	June 1982
On the crystal structure and magnetic properties of MnNiGe Fjellvåg, H.; Andresen, A. F. Journal of Magnetism and Magnetic Materials, Vol. 50, Issue 3 https://doi.org/10.1016/0304-8853(85)90065-4	journal	July 1985
An efficient scheme to tailor the magnetostructural transitions by staged quenching and cyclical ageing in hexagonal martensitic alloys Li, Yong; Zeng, Qingqi; Wei, Zhiyang Acta Materialia, Vol. 174 https://doi.org/10.1016/j.actamat.2019.05.042	journal	August 2019
Magnetostrictive and magnetocaloric effects in Mn _0.89 Cr _0.11 NiGe Sivachenko, A. P.; Mityuk, V. I.; Kamenev, V. I. Low Temperature Physics, Vol. 39, Issue 12 https://doi.org/10.1063/1.4843196	journal	December 2013
Giant magnetocaloric effects near room temperature in Mn _1 − x Cu _x CoGe Samanta, Tapas; Dubenko, Igor; Quetz, Abdiel Applied Physics Letters, Vol. 101, Issue 24 https://doi.org/10.1063/1.4770379	journal	December 2012
Designed materials with the giant magnetocaloric effect near room temperature Biswas, Anis; Pathak, Arjun K.; Zarkevich, Nikolai A. Acta Materialia, Vol. 180 https://doi.org/10.1016/j.actamat.2019.09.023	journal	November 2019
Taming the First-Order Transition in Giant Magnetocaloric Materials Guillou, François; Porcari, Giacomo; Yibole, Hargen Advanced Materials, Vol. 26, Issue 17 https://doi.org/10.1002/adma.201304788	journal	February 2014
Crystal and magnetic structure of NiMnGe Bazela, W.; Szytuła, A.; Todorović, J. Physica Status Solidi (a), Vol. 38, Issue 2 https://doi.org/10.1002/pssa.2210380235	journal	December 1976
Magnetic and martensitic transformations of NiMnX(X=In,Sn,Sb) ferromagnetic shape memory alloys Sutou, Y.; Imano, Y.; Koeda, N. Applied Physics Letters, Vol. 85, Issue 19 https://doi.org/10.1063/1.1808879	journal	January 2004
Influence of magnetic field, chemical pressure and hydrostatic pressure on the structural and magnetocaloric properties of the Mn–Ni–Ge system Taubel, Andreas; Gottschall, Tino; Fries, Maximilian Journal of Physics D: Applied Physics, Vol. 50, Issue 46 https://doi.org/10.1088/1361-6463/aa8e89	journal	October 2017
On the determination of the magnetic entropy change in materials with first-order transitions Caron, L.; Ou, Z. Q.; Nguyen, T. T. Journal of Magnetism and Magnetic Materials, Vol. 321, Issue 21 https://doi.org/10.1016/j.jmmm.2009.06.086	journal	November 2009
The magnetostructural transformation and magnetocaloric effect in Co-doped MnNiGe _1.05 alloys Zhang, Chengliang; Wang, Dunhui; Cao, Qingqi Journal of Physics D: Applied Physics, Vol. 43, Issue 20 https://doi.org/10.1088/0022-3727/43/20/205003	journal	May 2010
La(Fe,Si)13-based magnetic refrigerants obtained by novel processing routes Lyubina, Julia; Gutfleisch, Oliver; Kuz’min, Michael D. Journal of Magnetism and Magnetic Materials, Vol. 320, Issue 18 https://doi.org/10.1016/j.jmmm.2008.04.116	journal	September 2008
A coupling of martensitic and metamagnetic transitions with collective magneto-volume and table-like magnetocaloric effects Liu, E. K.; Wei, Z. Y.; Li, Y. Applied Physics Letters, Vol. 105, Issue 6 https://doi.org/10.1063/1.4892167	journal	August 2014
Magnetostructural transformation and magnetocaloric effect in MnNiGe _1-x Ga _x alloys Zhang, C. L.; Han, Z. D.; Qian, B. Journal of Applied Physics, Vol. 114, Issue 15 https://doi.org/10.1063/1.4826216	journal	October 2013
EXPGUI , a graphical user interface for GSAS Toby, Brian H. Journal of Applied Crystallography, Vol. 34, Issue 2 https://doi.org/10.1107/S0021889801002242	journal	April 2001
Large reversible magnetocaloric effect in Ni-Mn-In-Co Gottschall, Tino; Skokov, Konstantin P.; Frincu, Bianca Applied Physics Letters, Vol. 106, Issue 2 https://doi.org/10.1063/1.4905371	journal	January 2015
Magnetic properties of the CoxNi1−xMnGe system Nizioł, S.; Wesełucha, A.; Bażela, W. Solid State Communications, Vol. 39, Issue 10 https://doi.org/10.1016/0038-1098(81)90213-1	journal	September 1981
Influence of negative lattice expansion and metamagnetic transition on magnetic entropy change in the compound LaFe11.4Si1.6 Hu, Feng-xia; Shen, Bao-gen; Sun, Ji-rong Applied Physics Letters, Vol. 78, Issue 23 https://doi.org/10.1063/1.1375836	journal	June 2001
The influence of Au substitution and hydrostatic pressure on the phase transitions and magnetocaloric properties of MnCoGe alloys Chen, Jing-Han; Trigg, Aaron; Poudel Chhetri, Tej Journal of Applied Physics, Vol. 127, Issue 21 https://doi.org/10.1063/5.0007172	journal	June 2020
Magnetostructural phase transition and magnetocaloric effect in off-stoichiometric Mn1.9−xNixGe alloys Zhang, C. L.; Wang, D. H.; Cao, Q. Q. Applied Physics Letters, Vol. 93, Issue 12 https://doi.org/10.1063/1.2990649	journal	September 2008
Phase diagram and magnetocaloric effects in aluminum doped MnNiGe alloys Quetz, Abdiel; Samanta, Tapas; Dubenko, Igor Journal of Applied Physics, Vol. 114, Issue 15 https://doi.org/10.1063/1.4826260	journal	October 2013
Heat treatment effect on the magnetic properties and martensitic transformations of MnCoGe Noguchi, Kohei; Kobayashi, Ryota; Mitsui, Yoshifuru Journal of Magnetism and Magnetic Materials, Vol. 499 https://doi.org/10.1016/j.jmmm.2019.166199	journal	April 2020
Giant Magnetocaloric Effect in ${Gd}_{5} ({Si}_{2} {Ge}_{2})$ Pecharsky, V. K.; Gschneidner, Jr., K. A. Physical Review Letters, Vol. 78, Issue 23, p. 4494-4497 https://doi.org/10.1103/PhysRevLett.78.4494	journal	June 1997
Magnetic superelasticity and inverse magnetocaloric effect in Ni-Mn-In Krenke, Thorsten; Duman, Eyüp; Acet, Mehmet Physical Review B, Vol. 75, Issue 10 https://doi.org/10.1103/PhysRevB.75.104414	journal	March 2007
Magnetocaloric effect in Ni-Mn-X (X = Ga, In, Sn, Sb) Heusler alloys Buchelnikov, V. D.; Sokolovskiy, V. V. The Physics of Metals and Metallography, Vol. 112, Issue 7 https://doi.org/10.1134/S0031918X11070052	journal	December 2011
Magnetocaloric properties of Ni2Mn1−xCuxGa Stadler, Shane; Khan, Mahmud; Mitchell, Joseph Applied Physics Letters, Vol. 88, Issue 19 https://doi.org/10.1063/1.2202751	journal	May 2006
Coupled nature of magnetic and structural transition in MnNiGe under pressure Anzai, S.; Ozawa, K. Physical Review B, Vol. 18, Issue 5 https://doi.org/10.1103/PhysRevB.18.2173	journal	September 1978
Large magnetoresistance in single-crystalline Ni50Mn50−xInx alloys (x=14–16) upon martensitic transformation Yu, S. Y.; Liu, Z. H.; Liu, G. D. Applied Physics Letters, Vol. 89, Issue 16 https://doi.org/10.1063/1.2362581	journal	October 2006
Stable magnetostructural coupling with tunable magnetoresponsive effects in hexagonal ferromagnets Liu, Enke; Wang, Wenhong; Feng, Lin Nature Communications, Vol. 3, Issue 1 https://doi.org/10.1038/ncomms1868	journal	January 2012
Large magnetic entropy change in Ni50Mn50−xInx Heusler alloys Pathak, Arjun Kumar; Khan, Mahmud; Dubenko, Igor Applied Physics Letters, Vol. 90, Issue 26 https://doi.org/10.1063/1.2752720	journal	June 2007
A profile refinement method for nuclear and magnetic structures Rietveld, H. M. Journal of Applied Crystallography, Vol. 2, Issue 2, p. 65-71 https://doi.org/10.1107/S0021889869006558	journal	June 1969
Giant reversible magnetocaloric effect in MnNiGe-based materials: Minimizing thermal hysteresis via crystallographic compatibility modulation Liu, Jun; Gong, Yuanyuan; You, Yurong Acta Materialia, Vol. 174 https://doi.org/10.1016/j.actamat.2019.05.066	journal	August 2019
Giant low field magnetocaloric effect near room temperature in isostructurally alloyed MnNiGe-FeCoGe systems Kuang, Yafei; Yang, Bo; Hao, Xiaowen Journal of Magnetism and Magnetic Materials, Vol. 506 https://doi.org/10.1016/j.jmmm.2020.166782	journal	July 2020
On entropy determination from magnetic and calorimetric experiments in conventional giant magnetocaloric materials Chen, Jing-Han; Us Saleheen, Ahmad; Adams, Philip W. Journal of Applied Physics, Vol. 123, Issue 14 https://doi.org/10.1063/1.5016858	journal	April 2018
Low-pressure-induced large reversible barocaloric effect near room temperature in (MnNiGe)-(FeCoGe) alloys Kuang, Yafei; Qi, Ji; Xu, Haijian Scripta Materialia, Vol. 200 https://doi.org/10.1016/j.scriptamat.2021.113908	journal	July 2021
Magnetic-field-induced shape recovery by reverse phase transformation Kainuma, R.; Imano, Y.; Ito, W. Nature, Vol. 439, Issue 7079 https://doi.org/10.1038/nature04493	journal	February 2006
Diffusionless orthorhombic to hexagonal transitions in ternary silicides and germanides Johnson, V. Inorganic Chemistry, Vol. 14, Issue 5 https://doi.org/10.1021/ic50147a032	journal	May 1975
Magnetostructural phase transitions and magnetocaloric effects in MnNiGe _1−x Al _x Samanta, Tapas; Dubenko, Igor; Quetz, Abdiel Applied Physics Letters, Vol. 100, Issue 5 https://doi.org/10.1063/1.3681798	journal	January 2012
Tuning magnetostructural transition and the associated giant magnetocaloric effect via thermal treatment in MnCoGe-based alloys Zhang, C. L.; Nie, Y. G.; Shi, H. F. Journal of Magnetism and Magnetic Materials, Vol. 469 https://doi.org/10.1016/j.jmmm.2018.09.016	journal	January 2019

Similar Records

Enhanced magnetocaloric effects in metastable phases of Mn_1-xCo_xNiGe generated through thermal quenching and high-pressure annealing

Journal Article · Wed Feb 08 00:00:00 EST 2023 · Journal of Applied Physics · OSTI ID:1975225

Chhetri, Tej Poudel; Chen, Jing-Han; Grant, Anthony T.; +5 more

Large reversible magnetic entropy change in rapidly solidified Ni_0.895C_r0.105MnGe_1.05 melt-spun ribbons

Journal Article · Tue Apr 10 00:00:00 EDT 2018 · Intermetallics · OSTI ID:1975225

Aryal, Anil; Quetz, Abdiel; Sánchez-Valdés, C. F.; +6 more

Barocaloric and magnetocaloric effects in (MnNiSi)_1-x(FeCoGe)_x

Journal Article · Thu Jan 11 00:00:00 EST 2018 · Applied Physics Letters · OSTI ID:1975225

Samanta, Tapas; Lloveras, Pol; Us Saleheen, Ahmad; +9 more

Related Subjects

36 MATERIALS SCIENCE
75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION
magnetocaloric
barocaloric
magnetic refrigeration
phase transitions
magnetism
alloys
materials heat treatment

Title: Effects of doping, hydrostatic pressure, and thermal quenching on the phase transitions and magnetocaloric properties in Mn1–xCoxNiGe

Citation Formats

References (55)

Similar Records

Related Subjects

Title: Effects of doping, hydrostatic pressure, and thermal quenching on the phase transitions and magnetocaloric properties in Mn_1–xCo_xNiGe