Large reversible magnetic entropy change in rapidly solidified Ni0.895Cr0.105MnGe1.05 melt-spun ribbons

Aryal, Anil; Quetz, Abdiel; Sánchez-Valdés, C. F.; Ibarra-Gaytán, P. J.; Pandey, Sudip; Dubenko, Igor; Llamazares, Jose L. Sánchez; Stadler, Shane; Ali, Naushad

doi:10.1016/j.intermet.2018.04.003

Title: Large reversible magnetic entropy change in rapidly solidified Ni_0.895C_r0.105MnGe_1.05 melt-spun ribbons

Journal Article · Tue Apr 10 00:00:00 EDT 2018 · Intermetallics

DOI:https://doi.org/10.1016/j.intermet.2018.04.003· OSTI ID:1872886

Aryal, Anil ^[1]; Quetz, Abdiel ^[1]; Sánchez-Valdés, C. F. ^[2]; Ibarra-Gaytán, P. J. ^[3];

^[1]; Dubenko, Igor ^[1]; Llamazares, Jose L. Sánchez ^[3]; Stadler, Shane ^[4]; Ali, Naushad ^[1]

Southern Illinois Univ., Carbondale, IL (United States)
Univ. Autónoma de Ciudad Juárez (UACJ), Chihuahua (Mexico)
Inst. Potosino de Investigación Científica y Tecnológica A.C., San Luis Potosi (Mexico)
Louisiana State Univ., Baton Rouge, LA (United States)

The crystal structure, and magnetic and magnetocaloric properties of rapidly solidified Ni_0.895Cr_0.105MnGe_1.05 melt-spun ribbons is reported. The ribbon samples crystallize into a single-phase hexagonal Ni₂In-type structure at room temperature. The as-quenched ribbons showed a second order magnetic transition at 192 ± 1 K at μ_oH = 5 mT. A magnetic-field-induced transition from an antiferromagnetic (AFM)-like to a ferromagnetic (FM) state of martensite structure was observed in annealed ribbons below the temperature of the martensitic transformation (T_M ~ 245 ± 1 K). The annealed ribbons undergo a first-order magnetostructural transition (MST) with a large maximum reversible magnetic entropy change of ΔS_M = 16.1 J kg^–1 K^–1 (this is about a four-fold increase compared to the ΔS_M observed for the bulk sample of the same nominal composition) and RC = 144 J kg^–1 for μ_oΔH = 5 T at temperature T = T_M ~ 245 ± 1 K. The increase in the ΔS_M peak value leads to an improved RC compared to that of the bulk sample (122 J kg1). Furthermore, the observed MCE and quasi-reversible character of ΔS_M at the MST illustrates the potential of Ni_0.895Cr_0.105MnGe_1.05 ribbons for magnetic cooling technology.

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Research Organization:: Louisiana State Univ., Baton Rouge, LA (United States); Southern Illinois Univ., Carbondale, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); CONACYT

Grant/Contract Number:: FG02-13ER46946; SC0010521; FG02-06ER46291 (SIU); FG02-13ER46946 (LSU)

OSTI ID:: 1872886

Alternate ID(s):: OSTI ID: 1548486

Journal Information:: Intermetallics, Vol. 97; ISSN 0966-9795

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 9 works

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magnetocaloric effect
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Title: Large reversible magnetic entropy change in rapidly solidified Ni0.895Cr0.105MnGe1.05 melt-spun ribbons

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Title: Large reversible magnetic entropy change in rapidly solidified Ni_0.895C_r0.105MnGe_1.05 melt-spun ribbons