Large reversible magnetic entropy change in rapidly solidified Ni0.895Cr0.105MnGe1.05 melt-spun ribbons

Aryal, Anil; Quetz, Abdiel; Sánchez-Valdés, C. F.; Ibarra-Gaytán, P. J.; Pandey, Sudip; Dubenko, Igor; Llamazares, Jose L. Sánchez; Stadler, Shane; Ali, Naushad

doi:10.1016/j.intermet.2018.04.003

Large reversible magnetic entropy change in rapidly solidified Ni_0.895C_r0.105MnGe_1.05 melt-spun ribbons

Journal Article · Tue Apr 10 00:00:00 EDT 2018 · Intermetallics

DOI:https://doi.org/10.1016/j.intermet.2018.04.003· OSTI ID:1872886

Aryal, Anil ^[1]; Quetz, Abdiel ^[2]; Sánchez-Valdés, C. F. ^[3]; Ibarra-Gaytán, P. J. ^[4]; ^[2]; Dubenko, Igor ^[2]; Llamazares, Jose L. Sánchez ^[4]; Stadler, Shane ^[5]; Ali, Naushad ^[2]

Southern Illinois Univ., Carbondale, IL (United States); Louisiana State University
Southern Illinois Univ., Carbondale, IL (United States)
Univ. Autónoma de Ciudad Juárez (UACJ), Chihuahua (Mexico)
Inst. Potosino de Investigación Científica y Tecnológica A.C., San Luis Potosi (Mexico)
Louisiana State Univ., Baton Rouge, LA (United States)

The crystal structure, and magnetic and magnetocaloric properties of rapidly solidified Ni_0.895Cr_0.105MnGe_1.05 melt-spun ribbons is reported. The ribbon samples crystallize into a single-phase hexagonal Ni₂In-type structure at room temperature. The as-quenched ribbons showed a second order magnetic transition at 192 ± 1 K at μ_oH = 5 mT. A magnetic-field-induced transition from an antiferromagnetic (AFM)-like to a ferromagnetic (FM) state of martensite structure was observed in annealed ribbons below the temperature of the martensitic transformation (T_M ~ 245 ± 1 K). The annealed ribbons undergo a first-order magnetostructural transition (MST) with a large maximum reversible magnetic entropy change of ΔS_M = 16.1 J kg^–1 K^–1 (this is about a four-fold increase compared to the ΔS_M observed for the bulk sample of the same nominal composition) and RC = 144 J kg^–1 for μ_oΔH = 5 T at temperature T = T_M ~ 245 ± 1 K. The increase in the ΔS_M peak value leads to an improved RC compared to that of the bulk sample (122 J kg1). Furthermore, the observed MCE and quasi-reversible character of ΔS_M at the MST illustrates the potential of Ni_0.895Cr_0.105MnGe_1.05 ribbons for magnetic cooling technology.

View Accepted Manuscript (DOE)

Research Organization:: Louisiana State Univ., Baton Rouge, LA (United States); Southern Illinois Univ., Carbondale, IL (United States)

Sponsoring Organization:: CONACYT; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0010521

OSTI ID:: 1872886

Alternate ID(s):: OSTI ID: 1538385
OSTI ID: 1548486

Journal Information:: Intermetallics, Journal Name: Intermetallics Vol. 97; ISSN 0966-9795

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (30)

Crystal and magnetic structure of NiMnGe Bazela, W.; Szytuła, A.; Todorović, J. Physica Status Solidi (a), Vol. 38, Issue 2 https://doi.org/10.1002/pssa.2210380235	journal	December 1976
Crystal and magnetic structure of the NiMnGe1−nSin System Bażela, W.; Szytula, A.; Todorović, J. Physica Status Solidi (a), Vol. 64, Issue 1 https://doi.org/10.1002/pssa.2210640140	journal	March 1981
On a generalised approach to first and second order magnetic transitions Banerjee, B. K. Physics Letters, Vol. 12, Issue 1 https://doi.org/10.1016/0031-9163(64)91158-8	journal	September 1964
On the magnetostructural transition in MnCoGeB alloy ribbons Quintana-Nedelcos, A.; Sánchez Llamazares, J. L.; Flores-Zuñiga, H. Journal of Alloys and Compounds, Vol. 644 https://doi.org/10.1016/j.jallcom.2015.05.008	journal	September 2015
Role of lanthanum in modifying the magnetic state in RNi2 solid solutions with R = Tb, Dy, Ho Ćwik, J.; Koshkid'ko, Y.; Tereshina, I. Journal of Alloys and Compounds, Vol. 649 https://doi.org/10.1016/j.jallcom.2015.07.014	journal	November 2015
On the correct estimation of the magnetic entropy change across the magneto-structural transition from the Maxwell relation: Study of MnCoGeBx alloy ribbons Quintana-Nedelcos, A.; Sánchez Llamazares, J. L.; Sánchez-Valdés, C. F. Journal of Alloys and Compounds, Vol. 694 https://doi.org/10.1016/j.jallcom.2016.10.116	journal	February 2017
Magnetocaloric effect in melt-spun MnCoGe ribbons Sánchez-Valdés, C. F.; Sánchez Llamazares, J. L.; Flores-Zúñiga, H. Scripta Materialia, Vol. 69, Issue 3 https://doi.org/10.1016/j.scriptamat.2013.03.022	journal	August 2013
Transition-metal-based magnetic refrigerants for room-temperature applications Tegus, O.; Brück, E.; Buschow, K. H. J. Nature, Vol. 415, Issue 6868 https://doi.org/10.1038/415150a	journal	January 2002
Reduction of hysteresis losses in the magnetic refrigerant Gd5Ge2Si2 by the addition of iron Provenzano, Virgil; Shapiro, Alexander J.; Shull, Robert D. Nature, Vol. 429, Issue 6994 https://doi.org/10.1038/nature02657	journal	June 2004
Magnetic-field-induced shape recovery by reverse phase transformation Kainuma, R.; Imano, Y.; Ito, W. Nature, Vol. 439, Issue 7079 https://doi.org/10.1038/nature04493	journal	February 2006
Stable magnetostructural coupling with tunable magnetoresponsive effects in hexagonal ferromagnets Liu, Enke; Wang, Wenhong; Feng, Lin Nature Communications, Vol. 3, Issue 1 https://doi.org/10.1038/ncomms1868	journal	January 2012
Inverse magnetocaloric effect in ferromagnetic Ni–Mn–Sn alloys Krenke, Thorsten; Duman, Eyüp; Acet, Mehmet Nature Materials, Vol. 4, Issue 6 https://doi.org/10.1038/nmat1395	journal	May 2005
Magnetocaloric effect and negative thermal expansion in hexagonal Fe doped MnNiGe compounds with a magnetoelastic AFM-FM-like transition Xu, Kun; Li, Zhe; Liu, Enke Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/srep41675	journal	January 2017
The giant magnetocaloric effect of optimally prepared Gd5Si2Ge2 Pecharsky, A. O.; Gschneidner, K. A.; Pecharsky, V. K. Journal of Applied Physics, Vol. 93, Issue 8 https://doi.org/10.1063/1.1558210	journal	April 2003
Large magnetoresistance in single-crystalline Ni50Mn50−xInx alloys (x=14–16) upon martensitic transformation Yu, S. Y.; Liu, Z. H.; Liu, G. D. Applied Physics Letters, Vol. 89, Issue 16 https://doi.org/10.1063/1.2362581	journal	October 2006
Magnetocaloric effect in melt spun Ni50.3Mn35.5Sn14.4 ribbons Hernando, B.; Sánchez Llamazares, J. L.; Santos, J. D. Applied Physics Letters, Vol. 92, Issue 13 https://doi.org/10.1063/1.2904625	journal	March 2008
Magnetostructural phase transition and magnetocaloric effect in off-stoichiometric Mn1.9−xNixGe alloys Zhang, C. L.; Wang, D. H.; Cao, Q. Q. Applied Physics Letters, Vol. 93, Issue 12 https://doi.org/10.1063/1.2990649	journal	September 2008
Magnetostructural phase transitions and magnetocaloric effects in MnNiGe _1−x Al _x Samanta, Tapas; Dubenko, Igor; Quetz, Abdiel Applied Physics Letters, Vol. 100, Issue 5 https://doi.org/10.1063/1.3681798	journal	January 2012
Magnetostructural transformation in Mn _1+x Ni _1−x Ge and Mn _1−x Ni _1+x Ge alloys Zhang, C. L.; Zhu, C.; Chen, J. Journal of Applied Physics, Vol. 112, Issue 12 https://doi.org/10.1063/1.4770442	journal	December 2012
Giant magnetocaloric effect in isostructural MnNiGe-CoNiGe system by establishing a Curie-temperature window Liu, E. K.; Zhang, H. G.; Xu, G. Z. Applied Physics Letters, Vol. 102, Issue 12 https://doi.org/10.1063/1.4798318	journal	March 2013
Magnetostructural transformation and magnetocaloric effect in MnNiGe _1-x Ga _x alloys Zhang, C. L.; Han, Z. D.; Qian, B. Journal of Applied Physics, Vol. 114, Issue 15 https://doi.org/10.1063/1.4826216	journal	October 2013
Magnetostrictive and magnetocaloric effects in Mn _0.89 Cr _0.11 NiGe Sivachenko, A. P.; Mityuk, V. I.; Kamenev, V. I. Low Temperature Physics, Vol. 39, Issue 12 https://doi.org/10.1063/1.4843196	journal	December 2013
Magnetostructural transition and magnetocaloric effect in MnNiGe _1.05 melt-spun ribbons Daniel-Pérez, Gerardo; Sánchez Llamazares, J. L.; Quintana-Nedelcos, A. Journal of Applied Physics, Vol. 115, Issue 17 https://doi.org/10.1063/1.4864435	journal	May 2014
The antiferromagnetic-ferromagnetic conversion and magnetostructural transformation in Mn-Ni-Fe-Ge ribbons Ma, S. C.; Hou, D.; Yang, F. Applied Physics Letters, Vol. 104, Issue 20 https://doi.org/10.1063/1.4879804	journal	May 2014
Phase diagram and magnetocaloric effects in Ni _1-x Cr _x MnGe _1.05 Aryal, Anil; Quetz, Abdiel; Pandey, Sudip Journal of Applied Physics, Vol. 117, Issue 17 https://doi.org/10.1063/1.4907765	journal	May 2015
Magnetic properties and transformation of crystal structure in the ErFe ₂ -ErAl ₂ system Ćwik, J.; Koshkid'ko, Y.; Mikhailova, A. Journal of Applied Physics, Vol. 117, Issue 12 https://doi.org/10.1063/1.4916353	journal	March 2015
The magnetostructural transformation and magnetocaloric effect in Co-doped MnNiGe _1.05 alloys Zhang, Chengliang; Wang, Dunhui; Cao, Qingqi Journal of Physics D: Applied Physics, Vol. 43, Issue 20 https://doi.org/10.1088/0022-3727/43/20/205003	journal	May 2010
Criterion for Ferromagnetism from Observations of Magnetic Isotherms Arrott, Anthony Physical Review, Vol. 108, Issue 6 https://doi.org/10.1103/PhysRev.108.1394	journal	December 1957
Coupled nature of magnetic and structural transition in MnNiGe under pressure Anzai, S.; Ozawa, K. Physical Review B, Vol. 18, Issue 5 https://doi.org/10.1103/PhysRevB.18.2173	journal	September 1978
Magnetostructural Transformation and Magnetoresponsive Properties of ${\rm MnNiGe}_{1-x}{\rm Sn}_{x}$ Alloys Liu, Enke; Du, Yin; Chen, Jinglan IEEE Transactions on Magnetics, Vol. 47, Issue 10 https://doi.org/10.1109/TMAG.2011.2159964	journal	October 2011

Similar Records

Phase diagram and magnetocaloric effects in Ni{sub 1-x}Cr{sub x}MnGe{sub 1.05}

Journal Article · Thu May 07 00:00:00 EDT 2015 · Journal of Applied Physics · OSTI ID:22403042

Direct and indirect measurements of the magnetic and magnetocaloric properties of Ni_0.895Cr_0.105MnGe_1.05 melt-spun ribbons in high magnetic fields

Journal Article · Wed May 22 20:00:00 EDT 2019 · Journal of Magnetism and Magnetic Materials · OSTI ID:1800356

Related Subjects

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION
36 MATERIALS SCIENCE
magnetocaloric effect
melt-spun ribbons
phase transitions

Large reversible magnetic entropy change in rapidly solidified Ni0.895Cr0.105MnGe1.05 melt-spun ribbons

Citation Formats

References (30)

Similar Records

Related Subjects

Large reversible magnetic entropy change in rapidly solidified Ni_0.895C_r0.105MnGe_1.05 melt-spun ribbons