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Title: Performance measurements of C{sub 1}-C{sub 3} carbonyl compounds using DNPH-coated silica gel and C{sub 18} cartridges

Conference ·
OSTI ID:197351
; ;  [1];  [2]
  1. ManTech Environmental Technology, Inc., Research Triangle Park, NC (United States)
  2. Environmental Protection Agency, Research Triangle Park, NC (United States). Atmospheric Research and Exposure Assessment Lab.

Measurements have been conducted to examine the performance of formaldehyde, acetaldehyde, and acetone using silica and C{sub 18} cartridges coated with 2,4-dinitrophenylhydrazine. Laboratory measurements for formaldehyde were conducted using a paraformaldehyde generator to produce reproducible and constant concentrations of the compound. For acetaldehyde and acetone, known concentrations were generated in Teflon chambers. The compounds were routed into a sampling manifold where simultaneous measurements could be made with multiple cartridges. Typical concentrations employed in the study were as follows. HCHO: 0.5--25 ppbv; CH{sub 3}CHO; 0.5--10 ppbv; CH{sub 3}C(O)CH{sub 3}: 0.5--10 ppbv. Additional measurements were conducted for these compounds in the presence of potentially interfering compounds such as ozone and water vapor. Serial cartridge collections were periodically used to investigate breakthrough of the carbonyl compounds.

OSTI ID:
197351
Report Number(s):
CONF-9405167-; TRN: IM9612%%125
Resource Relation:
Conference: Measurement of toxic and related air pollutants, Durham, NC (United States), 3-6 May 1994; Other Information: PBD: 1994; Related Information: Is Part Of Measurement of toxic and related air pollutants. Proceedings of the 1994 U.S. EPA/A and WMA international symposium; PB: 1075 p.
Country of Publication:
United States
Language:
English