Impact of hydrogen bonding pendant groups in polymer grafted nanoparticles on interlayer adhesion and mechanical properties in material extrusion printing

Ledford, William K.; Kilbey, S. Michael

doi:10.1016/j.addma.2023.103419

Title: Impact of hydrogen bonding pendant groups in polymer grafted nanoparticles on interlayer adhesion and mechanical properties in material extrusion printing

Journal Article · Fri Jan 20 00:00:00 EST 2023 · Additive Manufacturing

DOI:https://doi.org/10.1016/j.addma.2023.103419· OSTI ID:1969178

Ledford, William K. ^[1]; Kilbey, S. Michael ^[1]

University of Tennessee, Knoxville, TN (United States)

The addition of nanoparticles or copolymer grafted nanoparticles (CPGNPs) to polymeric matrices greatly improves thermomechanical properties of the resulting nanocomposite, but corresponding studies of nanocomposite systems created by 3D printing are few, especially in the realm of functional polymeric materials. Here we describe how silica nanoparticle-grafted, random copolymers of poly(methyl methacrylate-random-2-uriedo-[1H]-pyrimidinone methacrylate) (P(MMA-r-UPyMA) dramatically increases the mechanical properties of poly(methyl methacrylate) (PMMA) based nanocomposite specimens created by melt extrusion printing. Most notably, when these novel CPGNPs are combined with PMMA matrix chains via a solution-based process, printed specimens containing only 0.5 wt% additive show significant increases in Young’s modulus (90%), storage modulus (93%), tensile modulus (148%) and ultimate tensile strength (110%). These improvements are ascribed to strengthening of adhesion across interfaces due to multi-point hydrogen bonding between UPyMA groups, the reinforcement effect of the P(MMA-r-UPyMA)-grafted silica nanoparticles, as well as hydrogen bonding interactions and entanglements between graft and matrix chains. Imaging of fracture surfaces after tensile testing reveals that in comparison to nanocomposites created by simple mechanical mixing of solids, the solution-casting process improves the dispersion of nanoparticles and reduces the void spaces between printed roads. These studies demonstrate that introducing functionality into polymer grafts, such as hydrogen bonding interactions, and intimate mixing of polymer-modified nanomaterials can greatly improve interlayer adhesion and mechanical properties, thereby advancing this method of polymer additive manufacturing

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Research Organization:: Kansas City Nuclear Security Campus (KCNSC), Kansas City, MO (United States); Univ. of Tennessee, Knoxville, TN (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: NA0002839

OSTI ID:: 1969178

Report Number(s):: NSC-614-4948

Journal Information:: Additive Manufacturing, Vol. 63; ISSN 2214-8604

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (52)

Effect of Infill Parameters on Tensile Mechanical Behavior in Desktop 3D Printing Fernandez-Vicente, Miguel; Calle, Wilson; Ferrandiz, Santiago 3D Printing and Additive Manufacturing, Vol. 3, Issue 3 https://doi.org/10.1089/3dp.2015.0036	journal	September 2016
Self-Complementary Multiple Hydrogen-Bonding Additives Enhance Thermomechanical Properties of 3D-Printed PMMA Structures Street, Dayton P.; Ledford, William K.; Allison, Abigail A. Macromolecules, Vol. 52, Issue 15 https://doi.org/10.1021/acs.macromol.9b00546	journal	July 2019
Interfacial interactions in PMMA/silica nanocomposites enhance the performance of parts created by Fused Filament Fabrication Street, Dayton P.; Mah, Adeline Huizhen; Patterson, Steven Polymer, Vol. 157 https://doi.org/10.1016/j.polymer.2018.10.004	journal	November 2018
Correlation of surface treatment, dispersion and mechanical properties of HDPE/CNT nanocomposites Ferreira, Filipe V.; Francisco, Wesley; Menezes, Beatriz R. C. Applied Surface Science, Vol. 389 https://doi.org/10.1016/j.apsusc.2016.07.164	journal	December 2016
Comparison between flexural and tensile modulus of fibre composites Tolf, Göran; Clarin, Per Fibre Science and Technology, Vol. 21, Issue 4 https://doi.org/10.1016/0015-0568(84)90035-6	journal	January 1984
Quadruple Hydrogen Bonding Supramolecular Elastomers for Melt Extrusion Additive Manufacturing Chen, Xi; Zawaski, Callie E.; Spiering, Glenn A. ACS Applied Materials & Interfaces, Vol. 12, Issue 28 https://doi.org/10.1021/acsami.0c08958	journal	June 2020
Stability and Lifetime of Quadruply Hydrogen Bonded 2-Ureido-4[1 H ]-pyrimidinone Dimers Söntjens, Serge H. M.; Sijbesma, Rint P.; van Genderen, Marcel H. P. Journal of the American Chemical Society, Vol. 122, Issue 31 https://doi.org/10.1021/ja000435m	journal	August 2000
Printable Electrolytes: Tuning 3D‐Printing by Multiple Hydrogen Bonds and Added Inorganic Lithium‐Salts Rupp, Harald; Bhandary, Rajesh; Kulkarni, Amit Advanced Materials Technologies, Vol. 7, Issue 8 https://doi.org/10.1002/admt.202200088	journal	April 2022
Enhanced Glassy State Mechanical Properties of Polymer Nanocomposites via Supramolecular Interactions Hashemi, Amir; Jouault, Nicolas; Williams, Gregory A. Nano Letters, Vol. 15, Issue 8 https://doi.org/10.1021/acs.nanolett.5b01859	journal	July 2015
High performance polymer nanocomposites for additive manufacturing applications de Leon, Al C.; Chen, Qiyi; Palaganas, Napolabel B. Reactive and Functional Polymers, Vol. 103 https://doi.org/10.1016/j.reactfunctpolym.2016.04.010	journal	June 2016
Functional fillers in composite filaments for fused filament fabrication; a review Angelopoulos, Panagiotis M.; Samouhos, Michail; Taxiarchou, Maria Materials Today: Proceedings, Vol. 37 https://doi.org/10.1016/j.matpr.2020.07.069	journal	January 2021
On the Mechanical Response of Silicon Dioxide Nanofiller Concentration on Fused Filament Fabrication 3D Printed Isotactic Polypropylene Nanocomposites Vidakis, Nectarios; Petousis, Markos; Velidakis, Emmanouil Polymers, Vol. 13, Issue 12 https://doi.org/10.3390/polym13122029	journal	June 2021
Tuning the wetting–dewetting and dispersion–aggregation transitions in polymer nanocomposites using composition of graft and matrix polymers Martin, Tyler B.; Jayaraman, Arthi Materials Research Express, Vol. 3, Issue 3 https://doi.org/10.1088/2053-1591/3/3/034001	journal	March 2016
Additive manufacturing (3D printing): A review of materials, methods, applications and challenges Ngo, Tuan D.; Kashani, Alireza; Imbalzano, Gabriele Composites Part B: Engineering, Vol. 143 https://doi.org/10.1016/j.compositesb.2018.02.012	journal	June 2018
Additive manufacturing for COVID-19: Devices, materials, prospects, and challenges Advincula, Rigoberto C.; Dizon, John Ryan C.; Chen, Qiyi MRS Communications, Vol. 10, Issue 3 https://doi.org/10.1557/mrc.2020.57	journal	September 2020
Study on optimization of 3D printing parameters Wu, Junhui IOP Conference Series: Materials Science and Engineering, Vol. 392 https://doi.org/10.1088/1757-899X/392/6/062050	journal	August 2018
Dynamic mechanical analysis and non-isothermal kinetics of EVA/PPy carbon black nanocomposites Al Naim, Abdullah; Abd Elbary, A. M.; Ibrahim, S. S. Materials Science and Technology, Vol. 35, Issue 5 https://doi.org/10.1080/02670836.2019.1572319	journal	January 2019
Wetting–Dewetting and Dispersion–Aggregation Transitions Are Distinct for Polymer Grafted Nanoparticles in Chemically Dissimilar Polymer Matrix Martin, Tyler B.; Mongcopa, Katrina Irene S.; Ashkar, Rana Journal of the American Chemical Society, Vol. 137, Issue 33 https://doi.org/10.1021/jacs.5b05291	journal	August 2015
Fabrication of ABS/Graphene Oxide Composite Filament for Fused Filament Fabrication (FFF) 3D Printing Aumnate, C.; Pongwisuthiruchte, A.; Pattananuwat, P. Advances in Materials Science and Engineering, Vol. 2018 https://doi.org/10.1155/2018/2830437	journal	November 2018
Thermoreversible Poly(alkyl acrylates) Consisting of Self-Complementary Multiple Hydrogen Bonding Yamauchi, Koji; Lizotte, Jeremy R.; Long, Timothy E. Macromolecules, Vol. 36, Issue 4 https://doi.org/10.1021/ma0212801	journal	February 2003
Enhancing nanomaterial dispersion and performance of parts printed via FFF by a solution casting method Ledford, William K.; Sabury, Sina; Kilbey, S. Michael MRS Communications, Vol. 11, Issue 2 https://doi.org/10.1557/s43579-020-00008-6	journal	January 2021
Rheology of polymer layered silicate nanocomposites Krishnamoorti, Ramanan; Yurekli, Koray Current Opinion in Colloid & Interface Science, Vol. 6, Issue 5-6 https://doi.org/10.1016/S1359-0294(01)00121-2	journal	November 2001
Fused Filament Fabrication of PEEK: A Review of Process-Structure-Property Relationships Zanjanijam, Ali Reza; Major, Ian; Lyons, John G. Polymers, Vol. 12, Issue 8 https://doi.org/10.3390/polym12081665	journal	July 2020
Additive manufacturing of carbon fiber reinforced thermoplastic composites using fused deposition modeling Ning, Fuda; Cong, Weilong; Qiu, Jingjing Composites Part B: Engineering, Vol. 80 https://doi.org/10.1016/j.compositesb.2015.06.013	journal	October 2015
Design and Synthesis of Triblock Copolymers for Creating Complex Secondary Structures by Orthogonal Self-Assembly Altintas, Ozcan; Artar, Müge; ter Huurne, Gijs Macromolecules, Vol. 48, Issue 24 https://doi.org/10.1021/acs.macromol.5b01990	journal	December 2015
Entropic Effects on the Supramolecular Self-Assembly of Macromolecules Pahnke, Kai; Altintas, Ozcan; Schmidt, Friedrich G. ACS Macro Letters, Vol. 4, Issue 7 https://doi.org/10.1021/acsmacrolett.5b00335	journal	July 2015
Controlling the Location of Bare Nanoparticles in Polymer-Nanoparticle Blend Films by Adding Polymer-Grafted Nanoparticles Sriramoju, Kishore Kumar; Padmanabhan, Venkat Physical Review Letters, Vol. 114, Issue 25 https://doi.org/10.1103/PhysRevLett.114.258301	journal	June 2015
Influence of Random Branching on Multiple Hydrogen Bonding in Poly(alkyl methacrylate)s McKee, Matthew G.; Elkins, Casey L.; Park, Taigyoo Macromolecules, Vol. 38, Issue 14 https://doi.org/10.1021/ma050667b	journal	June 2005
Structure–property relationships of polymer-grafted nanospheres for designing advanced nanocomposites Lenart, William R.; Hore, Michael J. A. Nano-Structures & Nano-Objects, Vol. 16 https://doi.org/10.1016/j.nanoso.2017.11.005	journal	October 2018
Additive manufacturing of CNTs/PLA composites and the correlation between microstructure and functional properties Zhou, Xing; Deng, Jingrui; Fang, Changqing Journal of Materials Science & Technology, Vol. 60 https://doi.org/10.1016/j.jmst.2020.04.038	journal	January 2021
Synthesis, Rheology, and Assessment of 3D Printability of Multifunctional Polyesters for Extrusion-Based Direct-Write 3D Printing Jain, Tanmay; Tseng, Yen-Ming; Tantisuwanno, Chinnapatch ACS Applied Polymer Materials, Vol. 3, Issue 12 https://doi.org/10.1021/acsapm.1c01275	journal	November 2021
Polymer-Grafted-Nanoparticles Nanocomposites: Dispersion, Grafted Chain Conformation, and Rheological Behavior Chevigny, Chloé; Dalmas, Florent; Di Cola, Emanuela Macromolecules, Vol. 44, Issue 1 https://doi.org/10.1021/ma101332s	journal	January 2011
The Influence of Hydrogen Bonding Side-Groups on Viscoelastic Behavior of Linear and Network Polymers Lewis, Christopher L.; Stewart, Kathleen; Anthamatten, Mitchell Macromolecules, Vol. 47, Issue 2 https://doi.org/10.1021/ma402368s	journal	January 2014
Effect of Silica Nanoparticles on the Mechanical Performances of Poly(Lactic Acid) Dorigato, A.; Sebastiani, M.; Pegoretti, A. Journal of Polymers and the Environment, Vol. 20, Issue 3 https://doi.org/10.1007/s10924-012-0425-6	journal	April 2012
Effect of Hydrogen Bonding on Linear and Nonlinear Rheology of Entangled Polymer Melts Shabbir, Aamir; Goldansaz, Hadi; Hassager, Ole Macromolecules, Vol. 48, Issue 16 https://doi.org/10.1021/acs.macromol.5b00757	journal	August 2015
Nanocomposites: Structure, Phase Behavior, and Properties Kumar, Sanat K.; Krishnamoorti, Ramanan Annual Review of Chemical and Biomolecular Engineering, Vol. 1, Issue 1 https://doi.org/10.1146/annurev-chembioeng-073009-100856	journal	June 2010
Some basic aspects of polymer nanocomposites: A critical review Fu, Shaoyun; Sun, Zheng; Huang, Pei Nano Materials Science, Vol. 1, Issue 1 https://doi.org/10.1016/j.nanoms.2019.02.006	journal	March 2019
Synthesis and characterization of poly(2-ethylhexyl methacrylate) copolymers containing pendant, self-complementary multiple-hydrogen-bonding sites Elkins, Casey L.; Park, Taigyoo; McKee, Matthew G. Journal of Polymer Science Part A: Polymer Chemistry, Vol. 43, Issue 19 https://doi.org/10.1002/pola.20961	journal	January 2005
The modelling of the toughening of epoxy polymers via silica nanoparticles: The effects of volume fraction and particle size Bray, D. J.; Dittanet, P.; Guild, F. J. Polymer, Vol. 54, Issue 26 https://doi.org/10.1016/j.polymer.2013.10.034	journal	December 2013
3D printing with polymers: Challenges among expanding options and opportunities Stansbury, Jeffrey W.; Idacavage, Mike J. Dental Materials, Vol. 32, Issue 1 https://doi.org/10.1016/j.dental.2015.09.018	journal	January 2016
“Gel-like” Mechanical Reinforcement in Polymer Nanocomposite Melts Akcora, Pinar; Kumar, Sanat K.; Moll, Joseph Macromolecules, Vol. 43, Issue 2 https://doi.org/10.1021/ma902072d	journal	January 2010
Fracture resistance measurement of fused deposition modeling 3D printed polymers Aliheidari, Nahal; Tripuraneni, Rajasekhar; Ameli, Amir Polymer Testing, Vol. 60 https://doi.org/10.1016/j.polymertesting.2017.03.016	journal	July 2017
Influences of Air-Voids on the Performance of 3D Printing Cementitious Materials Che, Yujun; Tang, Shengwen; Yang, Huashan Materials, Vol. 14, Issue 16 https://doi.org/10.3390/ma14164438	journal	August 2021
Nanocomposites with Polymer Grafted Nanoparticles Kumar, Sanat K.; Jouault, Nicolas; Benicewicz, Brian Macromolecules, Vol. 46, Issue 9 https://doi.org/10.1021/ma4001385	journal	April 2013
Thermally Reversible Aggregation of Gold Nanoparticles in Polymer Nanocomposites through Hydrogen Bonding Heo, Kyuyoung; Miesch, Caroline; Emrick, Todd Nano Letters, Vol. 13, Issue 11 https://doi.org/10.1021/nl402813q	journal	October 2013
Wetting and Chain Packing across Interfacial Zones Affect Distribution of Relaxations in Polymer and Polymer-Grafted Nanocomposites Mapesa, Emmanuel U.; Street, Dayton P.; Heres, Maximilian F. Macromolecules, Vol. 53, Issue 13 https://doi.org/10.1021/acs.macromol.0c00399	journal	June 2020
Polymer grafted nanoparticles: Effect of chemical and physical heterogeneity in polymer grafts on particle assembly and dispersion Jayaraman, Arthi Journal of Polymer Science Part B: Polymer Physics, Vol. 51, Issue 7 https://doi.org/10.1002/polb.23260	journal	February 2013
Engineering interfacial entropic effects to generate giant viscosity changes in nanoparticle embedded polymer thin films Swain, Aparna; Begam, Nafisa; Chandran, Sivasurender Soft Matter, Vol. 16, Issue 16 https://doi.org/10.1039/D0SM00019A	journal	January 2020
A Versatile Method To Prepare RAFT Agent Anchored Substrates and the Preparation of PMMA Grafted Nanoparticles Li, Chunzhao; Han, Junwon; Ryu, Chang Y. Macromolecules, Vol. 39, Issue 9 https://doi.org/10.1021/ma051983t	journal	May 2006
Controlling the miscibility of polyethylene/layered silicate nanocomposites by altering the polymer/surface interactions Chrissopoulou, K.; Altintzi, I.; Anastasiadis, S. H. Polymer, Vol. 46, Issue 26 https://doi.org/10.1016/j.polymer.2005.10.106	journal	December 2005
Tailoring Interfacial Interactions via Polymer-Grafted Nanoparticles Improves Performance of Parts Created by 3D Printing Street, Dayton P.; Mah, Adeline Huizhen; Ledford, William K. ACS Applied Polymer Materials, Vol. 2, Issue 3 https://doi.org/10.1021/acsapm.9b01195	journal	February 2020
Impact of Hydrogen Bonding Interactions on Graft–Matrix Wetting and Structure in Polymer Nanocomposites Kulshreshtha, Arjita; Modica, Kevin J.; Jayaraman, Arthi Macromolecules, Vol. 52, Issue 7 https://doi.org/10.1021/acs.macromol.8b02666	journal	March 2019

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Title: Impact of hydrogen bonding pendant groups in polymer grafted nanoparticles on interlayer adhesion and mechanical properties in material extrusion printing

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