Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Isolation of C1 through C4 derivatives from CO using heteroleptic uranium( iii ) metallocene aryloxide complexes

Journal Article · · Chemical Science
DOI:https://doi.org/10.1039/D2SC06375A· OSTI ID:1923577

Functionalization of CO from C1 to C4 is acheived using a heteroleptic uranium( iii ) complex.

Research Organization:
Univ. of Missouri, Columbia, MO (United States)
Sponsoring Organization:
USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
SC0021273
OSTI ID:
1923577
Alternate ID(s):
OSTI ID: 2421870
Journal Information:
Chemical Science, Journal Name: Chemical Science Journal Issue: 8 Vol. 14; ISSN 2041-6520; ISSN CSHCBM
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

References (94)

Ueber einige merkwürdige, bei der Darstellung des Kaliums nach der Brunner'schen Methode, erhaltene Substanzen journal January 1825
A Crystallizable f-Element Tuck-In Complex: The Tuck-in Tuck-over Uranium Metallocene [(C 5 Me 5 )U{μ-η 511 -C 5 Me 3 (CH 2 ) 2 }(μ-H) 2 U(C 5 Me 5 ) 2 ] journal June 2008
Catching Gaseous SO2 in Cone-Type Lanthanide Complexes: An Unexpected Coordination Mode for SO2 in f-Element Chemistry journal April 2012
Two-Electron Reductive Carbonylation of Terminal Uranium(V) and Uranium(VI) Nitrides to Cyanate by Carbon Monoxide journal July 2014
Reductive Cleavage of Carbon Monoxide by a Disilenide journal June 2015
Alkaline-Earth-Promoted CO Homologation and Reductive Catalysis journal July 2015
Functionalization of Carbon Monoxide and tert -Butyl Nitrile by Intramolecular Proton Transfer in a Bis(Phosphido) Thorium Complex journal November 2018
Reduction of Carbon Oxides by an Acyclic Silylene: Reductive Coupling of CO journal January 2019
Reductive Hexamerization of CO Involving Cooperativity Between Magnesium(I) Reductants and [Mo(CO) 6 ]: Synthesis of Well‐Defined Magnesium Benzenehexolate Complexes** journal November 2020
Functionalization and Hydrogenation of Carbon Chains Derived from CO** journal March 2022
Synthesis and Reactivity of a Silylalkyl Double Tuck-in Uranium Metallocene [(η 51 -C 5 Me 4 SiMe 2 CH 2 ) 2 U] and its Conversion to Bis(tethered) Metallocenes journal December 2009
Activation of SO 2 with [(η 5 ‐C 5 Me 5 ) 2 Ln(THF) 2 ] (Ln=Eu, Yb) Leading to Dithionite and Sulfinate Complexes journal September 2014
Activation of SO 2 and CO 2 by Trivalent Uranium Leading to Sulfite/Dithionite and Carbonate/Oxalate Complexes journal August 2014
Backbonding in Thorium(IV) and Uranium(IV) Diarsenido Complexes with t BuNC and CO journal September 2021
Zur Kenntnis der sogenannten «Alkalicarbonyle» III. Die «Alkalicarbonyle» als Substangemische einer metalloganischen Verbindung und Metallacetylendiolaten journal January 1963
Analyse der Harnsäure journal January 1834
Réactivité des liaisons σ uranium-carbone: réactions du méthyltris(hexaméthyldisilylamido)uranium journal August 1987
Synthesis and characterisation of uranyl substituted malonato complexes journal January 2002
Synthesis and characterisation of uranyl substituted malonato complexes journal January 2002
Homogeneous syngas conversion journal April 2011
Fischer–Tropsch, organometallics, and other friends journal November 2004
Approaches to homogeneously catalyzed CO hydrogenation: A personal retrospective journal October 2017
Sterically encumbered mixed sandwich compounds of uranium(III): Synthesis and reactivity with small molecules journal February 2018
Activation of N2O and SO2 by the P–B Bond System. Reversible Binding of SO2 by the P–O–B Geminal Frustrated Lewis Pair journal April 2020
Synthesis and Reduction of Heteroleptic Bis(cyclopentadienyl) Uranium(III) Complexes journal May 2022
Schematic Design of Metal-Free NHC-Mediated Sequestering and Complete Conversion of SO2 to Thiocarbonyl S-Oxide Derivatives at Room Temperature journal January 2022
Comparative Insertion Reactivity of CO, CO 2 , t BuCN, and t BuNC into Thorium– and Uranium–Phosphorus Bonds journal May 2020
Isolation of a [Fe(CO)4]2–-Bridged Diuranium Complex Obtained via Reduction of Fe(CO)5 with Uranium(III) journal May 2021
Reduction of CO2 and CS2 with Uranium(III) Metallocene Aryloxides journal June 2022
Carbon Dioxide Activation by a Uranium(III) Complex Derived from a Chelating Bis(aryloxide) Ligand journal May 2017
The Bis Metallacyclic Anion [U(N{SiMe 3 } 2 )(CH 2 SiMe 2 N{SiMe 3 }) 2 ] journal September 2010
Mechanisms of Reactions of Open-Shell, Heavier Group 14 Derivatives with Small Molecules: n−π* Back-Bonding in Isocyanide Complexes, C–H Activation under Ambient Conditions, CO Coupling, and Ancillary Molecular Interactions†This Award Article summarizes, including more recent results, one of the themes of a lecture presented on March 26th, 2012, at the 243rd Chemical Society National Meeting American in San Diego, CA, in receipt of the 2012 Award in Organometallic Chemistry sponsored by the Dow Corporation. journal May 2013
Synthesis and Single Crystal X-ray Diffraction Study on the First Isolable Carbonyl Complex of an Actinide, (C5Me4H)3U(CO) journal March 1995
Uranium alkoxide chemistry. 1. Synthesis and the novel dimeric structure of the first homoleptic uranium(III) aryloxide complex journal August 1988
A synthetic and mechanistic study of oxycarbene-like coupling reaction patterns of actinide .eta.2-acyl complexes with carbon monoxide and isocyanides journal January 1986
Preparation of the first molecular carbon monoxide complex of uranium, (Me3SiC5H4)3UCO journal January 1986
Reductive homologation of carbon monoxide to a ketenecarboxylate by a low-valent organolanthanide complex: synthesis and x-ray crystal structure of [(C5Me5)4Sm2(O2CCCO)(THF)]2 journal June 1985
Organoactinide carbonylation and carboxylation chemistry. Structural electronic, bond energy, and photochemical effects on migratory insertion in the tris(cyclopentadienyl)thorium hydrocarbyl series journal June 1984
Carbon monoxide activation by organoactinides. .eta.2-Acyl-carbon monoxide coupling and the formation of metal-bound ketenes journal August 1983
Insertion of carbon monoxide into metal-nitrogen bonds. Synthesis, chemistry, structures, and structural dynamics of bis(pentamethylcyclopentadienyl) organoactinide dialkylamides and .eta.2-carbamoyls journal May 1981
Carbon monoxide activation by organoactinides. Migratory carbon monoxide insertion into metal-hydrogen bonds to produce mononuclear formyls journal November 1981
Bis(pentamethylcyclopentadienyl)actinide alkyls: facile activation of carbon monoxide, carbon-carbon double bond formation, and the production of unusual oxygen-bonded migratory insertion products journal October 1978
Carbon monoxide activation by f-element organometallics. An unusually distorted, carbenelike dihaptoacyl and CO tetramerization journal July 1980
Comparative Reactivity of Sterically Crowded nf 3 (C 5 Me 5 ) 3 Nd and (C 5 Me 5 ) 3 U Complexes with CO:  Formation of a Nonclassical Carbonium Ion versus an f Element Metal Carbonyl Complex journal November 2003
Carbon Dioxide Reduction and Carbon Monoxide Activation Employing a Reactive Uranium(III) Complex journal August 2005
Reductive Cyclotetramerization of CO to Squarate by a U(III) Complex:  The X-ray Crystal Structure of [(U (η-C 8 H 6 {Si i Pr 3 -1,4} 2 )(η-C 5 Me 4 H)] 2 (μ-η 2 : η 2 -C 4 O 4 ) journal August 2006
Trivalent [(C 5 Me 5 ) 2 (THF)Ln] 2- η 2 2 -N 2 ) Complexes as Reducing Agents Including the Reductive Homologation of CO to a Ketene Carboxylate, (μ-η 4 -O 2 CCCO) 2 - journal November 2006
Functionalization of Carbon Dioxide and Carbon Disulfide Using a Stable Uranium(III) Alkyl Complex journal April 2011
Small Molecule Activation by Uranium Tris(aryloxides): Experimental and Computational Studies of Binding of N 2 , Coupling of CO, and Deoxygenation Insertion of CO 2 under Ambient Conditions journal June 2011
Isolation of (CO) 1– and (CO 2 ) 1– Radical Complexes of Rare Earths via Ln(NR 2 ) 3 /K Reduction and [K 2 (18-crown-6) 2 ] 2+ Oligomerization journal March 2012
Mechanistic Studies on the Reductive Cyclooligomerisation of CO by U(III) Mixed Sandwich Complexes; the Molecular Structure of [(U(η-C 8 H 6 {Si i Pr 3 -1,4} 2 )(η-Cp*)] 2 (μ-η 11 -C 2 O 2 ) journal October 2008
Room-Temperature Reaction of Carbon Monoxide with a Stable Diarylgermylene journal May 2009
Coordination and Homologation of CO at Al(I): Mechanism and Chain Growth, Branching, Isomerization, and Reduction journal July 2022
Identification of Oxidation State +1 in a Molecular Uranium Complex journal September 2022
Synthesis, Characterization, and Stoichiometric U–O Bond Scission in Uranyl Species Supported by Pyridine(diimine) Ligand Radicals journal August 2015
Activation of CO by Hydrogenated Magnesium(I) Dimers: Sterically Controlled Formation of Ethenediolate and Cyclopropanetriolate Complexes journal July 2015
Carbon Chain Growth by Sequential Reactions of CO and CO 2 with [W(CO) 6 ] and an Aluminum(I) Reductant journal October 2018
Reductive Trimerization of CO to the Deltate Dianion Using Activated Magnesium(I) Compounds journal May 2019
Homoleptic Actinide Complexes with Chelating Diphosphinophosphido Ligands: New Mode of Reactivity with Carbon Monoxide and the X-ray Crystal Structure of U{P(CH2CH2PMe2)2}4 journal August 1995
Reactions of a Uranium(IV) Tertiary Alkyl Bond: Facile Ligand-Assisted Reduction and Insertion of Ethylene and Carbon Monoxide journal August 1995
Carbon monoxide activation by organoactinides. Formyl pathways in CO homologation and hydrogenation journal December 1982
Formation of Trivalent U–C, U–N, and U–S Bonds and Their Reactivity toward Carbon Dioxide and Acetone journal November 2011
Steric Effects in the Reductive Coupling of CO by Mixed-Sandwich Uranium(III) Complexes journal December 2012
The Bond between CO and Cp′ 3 U in Cp′ 3 U(CO) Involves Back-bonding from the Cp′ 3 U Ligand-Based Orbitals of π-Symmetry, where Cp′ Represents a Substituted Cyclopentadienyl Ligand journal July 2009
Insertion Reactivity of CO 2 , PhNCO, Me 3 CC≡N, and Me 3 CN≡C with the Uranium−Alkynyl Bonds in (C 5 Me 5 ) 2 U(C≡CPh) 2 journal February 2010
Nitrogen reduction and functionalization by a multimetallic uranium nitride complex journal July 2017
Metal-free binding and coupling of carbon monoxide at a boron–boron triple bond journal October 2013
Carbon oxygenate transformations by actinide compounds and catalysts journal January 2017
Carbon monoxide coupling and functionalisation at a simple uranium coordination complex journal January 2011
Carbon monoxide and carbon dioxide insertion chemistry of f-block N-heterocyclic carbene complexes journal January 2013
Direct conversion of carbon monoxide to a coordinated secondary alcohol derivative by a thorium phosphido complex journal January 1994
Dithionite and sulfinate complexes from the reaction of SO 2 with decamethylsamarocene journal January 2015
Samarocene oxide: from an undesired decomposition product to a new reagent journal January 2016
Activation of SO2 by [Zn(Cp*)2] and [(Cp*)ZnI–ZnI(Cp*)] journal January 2016
SO2 and SO3 reactions with [(C5Me5)2Sm-O-Sm(C5Me5)2]: a DFT investigation and comparison with CO2 reactivity journal January 2017
Crystalline, room-temperature stable phosphine–SO2 adducts: generation of sulfur monoxide from sulfur dioxide journal January 2018
Homocoupling of CO and isocyanide mediated by a C , C ′-bis(silylenyl)-substituted ortho -carborane journal January 2020
Tuning the structure, reactivity and magnetic communication of nitride-bridged uranium complexes with the ancillary ligands journal January 2019
The importance of the counter-cation in reductive rare-earth metal chemistry: 18-crown-6 instead of 2,2,2-cryptand allows isolation of [Y II (NR 2 ) 3 ] 1− and ynediolate and enediolate complexes from CO reactions journal January 2020
Cooperative strategies for CO homologation journal January 2020
Sterically controlled reductive oligomerisations of CO by activated magnesium( i ) compounds: deltate vs. ethenediolate formation journal January 2020
Systematic reductive oligomerization of isocyanides with a vanadium(ii) complex journal January 2021
Exploring the reactivity of homoleptic organozincs towards SO2: synthesis and structure of a homologous series of organozinc sulfinates journal January 2022
CO reductive oligomerization by a divalent thulium complex and CO2-induced functionalization journal January 2022
Uranium-mediated activation of small molecules journal January 2011
Reductive coupling of carbon monoxide by U(iii) complexes—a computational study journal January 2011
Computational insight into the reductive oligomerisation of CO at uranium(iii) mixed-sandwich complexes journal January 2012
Radical-anion chemistry of carbon monoxide journal January 1983
Infrared study of carbon monoxide adsorption on calcium and strontium oxides
  • Coluccia, Salvatore; Garrone, Edoardo; Guglielminotti, Eugenio
  • Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 77, Issue 5 https://doi.org/10.1039/f19817701063
journal January 1981
Homologation and functionalization of carbon monoxide by a recyclable uranium complex journal May 2012
Structural variations in cyclopentadienyl uranium(III) iodide complexes journal December 2020
Reductive Cyclotrimerization of Carbon Monoxide to the Deltate Dianion by an Organometallic Uranium Complex journal February 2006
Building Molecules with Carbon Monoxide Reductive Coupling journal February 2006
Synthesis and X-ray Crystallographic Study of [(UO2)2(C3H2O4)(Cl)2(C4H9NO)4] journal March 2018

Similar Records

Correction: Isolation of C1 through C4 derivatives from CO using heteroleptic uranium( iii ) metallocene aryloxide complexes
Journal Article · Tue Mar 21 20:00:00 EDT 2023 · Chemical Science · OSTI ID:1960609

Four-electron reduction chemistry using a uranium( iii ) phosphido complex
Journal Article · Sun Dec 31 23:00:00 EST 2017 · Dalton Transactions · OSTI ID:1540028