Ueber einige merkwürdige, bei der Darstellung des Kaliums nach der Brunner'schen Methode, erhaltene Substanzen
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January 1825
A Crystallizable f-Element Tuck-In Complex: The Tuck-in Tuck-over Uranium Metallocene [(C 5 Me 5 )U{μ-η 5 :η 1 :η 1 -C 5 Me 3 (CH 2 ) 2 }(μ-H) 2 U(C 5 Me 5 ) 2 ]
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June 2008
Catching Gaseous SO2 in Cone-Type Lanthanide Complexes: An Unexpected Coordination Mode for SO2 in f-Element Chemistry
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April 2012
Two-Electron Reductive Carbonylation of Terminal Uranium(V) and Uranium(VI) Nitrides to Cyanate by Carbon Monoxide
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July 2014
Reductive Cleavage of Carbon Monoxide by a Disilenide
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June 2015
Alkaline-Earth-Promoted CO Homologation and Reductive Catalysis
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July 2015
Functionalization of Carbon Monoxide and tert -Butyl Nitrile by Intramolecular Proton Transfer in a Bis(Phosphido) Thorium Complex
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November 2018
Reduction of Carbon Oxides by an Acyclic Silylene: Reductive Coupling of CO
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January 2019
Reductive Hexamerization of CO Involving Cooperativity Between Magnesium(I) Reductants and [Mo(CO) 6 ]: Synthesis of Well‐Defined Magnesium Benzenehexolate Complexes**
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November 2020
Functionalization and Hydrogenation of Carbon Chains Derived from CO**
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March 2022
Synthesis and Reactivity of a Silylalkyl Double Tuck-in Uranium Metallocene [(η 5 :η 1 -C 5 Me 4 SiMe 2 CH 2 ) 2 U] and its Conversion to Bis(tethered) Metallocenes
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December 2009
Activation of SO 2 with [(η 5 ‐C 5 Me 5 ) 2 Ln(THF) 2 ] (Ln=Eu, Yb) Leading to Dithionite and Sulfinate Complexes
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September 2014
Activation of SO 2 and CO 2 by Trivalent Uranium Leading to Sulfite/Dithionite and Carbonate/Oxalate Complexes
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August 2014
Backbonding in Thorium(IV) and Uranium(IV) Diarsenido Complexes with t BuNC and CO
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September 2021
Zur Kenntnis der sogenannten «Alkalicarbonyle» III. Die «Alkalicarbonyle» als Substangemische einer metalloganischen Verbindung und Metallacetylendiolaten
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January 1963
Analyse der Harnsäure
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January 1834
Réactivité des liaisons σ uranium-carbone: réactions du méthyltris(hexaméthyldisilylamido)uranium
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August 1987
Synthesis and characterisation of uranyl substituted malonato complexes
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January 2002
Synthesis and characterisation of uranyl substituted malonato complexes
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January 2002
Homogeneous syngas conversion
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April 2011
Fischer–Tropsch, organometallics, and other friends
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November 2004
Approaches to homogeneously catalyzed CO hydrogenation: A personal retrospective
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October 2017
Sterically encumbered mixed sandwich compounds of uranium(III): Synthesis and reactivity with small molecules
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February 2018
Activation of N2 O and SO2 by the P–B Bond System. Reversible Binding of SO2 by the P–O–B Geminal Frustrated Lewis Pair
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April 2020
Synthesis and Reduction of Heteroleptic Bis(cyclopentadienyl) Uranium(III) Complexes
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May 2022
Schematic Design of Metal-Free NHC-Mediated Sequestering and Complete Conversion of SO2 to Thiocarbonyl S -Oxide Derivatives at Room Temperature
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January 2022
Comparative Insertion Reactivity of CO, CO 2 , t BuCN, and t BuNC into Thorium– and Uranium–Phosphorus Bonds
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May 2020
Isolation of a [Fe(CO)4 ]2– -Bridged Diuranium Complex Obtained via Reduction of Fe(CO)5 with Uranium(III)
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May 2021
Reduction of CO2 and CS2 with Uranium(III) Metallocene Aryloxides
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June 2022
Carbon Dioxide Activation by a Uranium(III) Complex Derived from a Chelating Bis(aryloxide) Ligand
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May 2017
The Bis Metallacyclic Anion [U(N{SiMe 3 } 2 )(CH 2 SiMe 2 N{SiMe 3 }) 2 ] −
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September 2010
Mechanisms of Reactions of Open-Shell, Heavier Group 14 Derivatives with Small Molecules: n−π* Back-Bonding in Isocyanide Complexes, C–H Activation under Ambient Conditions, CO Coupling, and Ancillary Molecular Interactions†This Award Article summarizes, including more recent results, one of the themes of a lecture presented on March 26th, 2012, at the 243rd Chemical Society National Meeting American in San Diego, CA, in receipt of the 2012 Award in Organometallic Chemistry sponsored by the Dow Corporation.
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May 2013
Synthesis and Single Crystal X-ray Diffraction Study on the First Isolable Carbonyl Complex of an Actinide, (C5Me4H)3U(CO)
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March 1995
Uranium alkoxide chemistry. 1. Synthesis and the novel dimeric structure of the first homoleptic uranium(III) aryloxide complex
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August 1988
A synthetic and mechanistic study of oxycarbene-like coupling reaction patterns of actinide .eta.2-acyl complexes with carbon monoxide and isocyanides
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January 1986
Preparation of the first molecular carbon monoxide complex of uranium, (Me3SiC5H4)3UCO
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January 1986
Reductive homologation of carbon monoxide to a ketenecarboxylate by a low-valent organolanthanide complex: synthesis and x-ray crystal structure of [(C5Me5)4Sm2(O2CCCO)(THF)]2
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June 1985
Organoactinide carbonylation and carboxylation chemistry. Structural electronic, bond energy, and photochemical effects on migratory insertion in the tris(cyclopentadienyl)thorium hydrocarbyl series
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June 1984
Carbon monoxide activation by organoactinides. .eta.2-Acyl-carbon monoxide coupling and the formation of metal-bound ketenes
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August 1983
Insertion of carbon monoxide into metal-nitrogen bonds. Synthesis, chemistry, structures, and structural dynamics of bis(pentamethylcyclopentadienyl) organoactinide dialkylamides and .eta.2-carbamoyls
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May 1981
Carbon monoxide activation by organoactinides. Migratory carbon monoxide insertion into metal-hydrogen bonds to produce mononuclear formyls
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November 1981
Bis(pentamethylcyclopentadienyl)actinide alkyls: facile activation of carbon monoxide, carbon-carbon double bond formation, and the production of unusual oxygen-bonded migratory insertion products
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October 1978
Carbon monoxide activation by f-element organometallics. An unusually distorted, carbenelike dihaptoacyl and CO tetramerization
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July 1980
Comparative Reactivity of Sterically Crowded nf 3 (C 5 Me 5 ) 3 Nd and (C 5 Me 5 ) 3 U Complexes with CO: Formation of a Nonclassical Carbonium Ion versus an f Element Metal Carbonyl Complex
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November 2003
Carbon Dioxide Reduction and Carbon Monoxide Activation Employing a Reactive Uranium(III) Complex
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August 2005
Reductive Cyclotetramerization of CO to Squarate by a U(III) Complex: The X-ray Crystal Structure of [(U (η-C 8 H 6 {Si i Pr 3 -1,4} 2 )(η-C 5 Me 4 H)] 2 (μ-η 2 : η 2 -C 4 O 4 )
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August 2006
Trivalent [(C 5 Me 5 ) 2 (THF)Ln] 2 (μ - η 2 :η 2 -N 2 ) Complexes as Reducing Agents Including the Reductive Homologation of CO to a Ketene Carboxylate, (μ-η 4 -O 2 CCCO) 2 -
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November 2006
Functionalization of Carbon Dioxide and Carbon Disulfide Using a Stable Uranium(III) Alkyl Complex
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April 2011
Small Molecule Activation by Uranium Tris(aryloxides): Experimental and Computational Studies of Binding of N 2 , Coupling of CO, and Deoxygenation Insertion of CO 2 under Ambient Conditions
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June 2011
Isolation of (CO) 1– and (CO 2 ) 1– Radical Complexes of Rare Earths via Ln(NR 2 ) 3 /K Reduction and [K 2 (18-crown-6) 2 ] 2+ Oligomerization
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March 2012
Mechanistic Studies on the Reductive Cyclooligomerisation of CO by U(III) Mixed Sandwich Complexes; the Molecular Structure of [(U(η-C 8 H 6 {Si i Pr 3 -1,4} 2 )(η-Cp*)] 2 (μ-η 1 :η 1 -C 2 O 2 )
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October 2008
Room-Temperature Reaction of Carbon Monoxide with a Stable Diarylgermylene
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May 2009
Coordination and Homologation of CO at Al(I): Mechanism and Chain Growth, Branching, Isomerization, and Reduction
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July 2022
Identification of Oxidation State +1 in a Molecular Uranium Complex
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September 2022
Synthesis, Characterization, and Stoichiometric U–O Bond Scission in Uranyl Species Supported by Pyridine(diimine) Ligand Radicals
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August 2015
Activation of CO by Hydrogenated Magnesium(I) Dimers: Sterically Controlled Formation of Ethenediolate and Cyclopropanetriolate Complexes
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July 2015
Carbon Chain Growth by Sequential Reactions of CO and CO 2 with [W(CO) 6 ] and an Aluminum(I) Reductant
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October 2018
Reductive Trimerization of CO to the Deltate Dianion Using Activated Magnesium(I) Compounds
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May 2019
Homoleptic Actinide Complexes with Chelating Diphosphinophosphido Ligands: New Mode of Reactivity with Carbon Monoxide and the X-ray Crystal Structure of U{P(CH2CH2PMe2)2}4
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August 1995
Reactions of a Uranium(IV) Tertiary Alkyl Bond: Facile Ligand-Assisted Reduction and Insertion of Ethylene and Carbon Monoxide
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August 1995
Carbon monoxide activation by organoactinides. Formyl pathways in CO homologation and hydrogenation
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December 1982
Formation of Trivalent U–C, U–N, and U–S Bonds and Their Reactivity toward Carbon Dioxide and Acetone
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November 2011
Steric Effects in the Reductive Coupling of CO by Mixed-Sandwich Uranium(III) Complexes
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December 2012
The Bond between CO and Cp′ 3 U in Cp′ 3 U(CO) Involves Back-bonding from the Cp′ 3 U Ligand-Based Orbitals of π-Symmetry, where Cp′ Represents a Substituted Cyclopentadienyl Ligand
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July 2009
Insertion Reactivity of CO 2 , PhNCO, Me 3 CC≡N, and Me 3 CN≡C with the Uranium−Alkynyl Bonds in (C 5 Me 5 ) 2 U(C≡CPh) 2
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February 2010
Nitrogen reduction and functionalization by a multimetallic uranium nitride complex
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July 2017
Metal-free binding and coupling of carbon monoxide at a boron–boron triple bond
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October 2013
Carbon oxygenate transformations by actinide compounds and catalysts
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January 2017
Carbon monoxide coupling and functionalisation at a simple uranium coordination complex
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January 2011
Carbon monoxide and carbon dioxide insertion chemistry of f-block N-heterocyclic carbene complexes
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January 2013
Direct conversion of carbon monoxide to a coordinated secondary alcohol derivative by a thorium phosphido complex
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January 1994
Dithionite and sulfinate complexes from the reaction of SO 2 with decamethylsamarocene
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January 2015
Samarocene oxide: from an undesired decomposition product to a new reagent
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January 2016
Activation of SO2 by [Zn(Cp*)2 ] and [(Cp*)ZnI –ZnI (Cp*)]
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January 2016
SO2 and SO3 reactions with [(C5 Me5 )2 Sm-O-Sm(C5 Me5 )2 ]: a DFT investigation and comparison with CO2 reactivity
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January 2017
Crystalline, room-temperature stable phosphine–SO2 adducts: generation of sulfur monoxide from sulfur dioxide
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January 2018
Homocoupling of CO and isocyanide mediated by a C , C ′-bis(silylenyl)-substituted ortho -carborane
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January 2020
Tuning the structure, reactivity and magnetic communication of nitride-bridged uranium complexes with the ancillary ligands
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January 2019
The importance of the counter-cation in reductive rare-earth metal chemistry: 18-crown-6 instead of 2,2,2-cryptand allows isolation of [Y II (NR 2 ) 3 ] 1− and ynediolate and enediolate complexes from CO reactions
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January 2020
Cooperative strategies for CO homologation
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January 2020
Sterically controlled reductive oligomerisations of CO by activated magnesium( i ) compounds: deltate vs. ethenediolate formation
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January 2020
Systematic reductive oligomerization of isocyanides with a vanadium(ii) complex
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January 2021
Exploring the reactivity of homoleptic organozincs towards SO2 : synthesis and structure of a homologous series of organozinc sulfinates
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January 2022
CO reductive oligomerization by a divalent thulium complex and CO2 -induced functionalization
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January 2022
Uranium-mediated activation of small molecules
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January 2011
Reductive coupling of carbon monoxide by U(iii) complexes—a computational study
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January 2011
Computational insight into the reductive oligomerisation of CO at uranium(iii) mixed-sandwich complexes
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January 2012
Radical-anion chemistry of carbon monoxide
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January 1983
Infrared study of carbon monoxide adsorption on calcium and strontium oxides
Coluccia, Salvatore; Garrone, Edoardo; Guglielminotti, Eugenio
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 77, Issue 5
https://doi.org/10.1039/f19817701063
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January 1981
Homologation and functionalization of carbon monoxide by a recyclable uranium complex
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May 2012
Structural variations in cyclopentadienyl uranium(III) iodide complexes
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December 2020
Reductive Cyclotrimerization of Carbon Monoxide to the Deltate Dianion by an Organometallic Uranium Complex
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February 2006
Building Molecules with Carbon Monoxide Reductive Coupling
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February 2006
Synthesis and X-ray Crystallographic Study of [(UO2)2(C3H2O4)(Cl)2(C4H9NO)4]
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March 2018