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Four-electron reduction chemistry using a uranium( iii ) phosphido complex

Journal Article · · Dalton Transactions
DOI:https://doi.org/10.1039/c8dt01406j· OSTI ID:1540028
 [1];  [1];  [1];  [1]
  1. Department of Chemistry; University of Missouri; Columbia; USA
+ Show Author Affiliations

The first uranium(iii) phosphido complex is reported.

Research Organization:
Univ. of Missouri, Columbia, MO (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0014174
OSTI ID:
1540028
Journal Information:
Dalton Transactions, Vol. 47, Issue 25; ISSN 1477-9226
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

References (67)

Uranium-mediated activation of small molecules January 2011
Harnessing redox activity for the formation of uranium tris(imido) compounds July 2014
Molecular Octa-Uranium Rings with Alternating Nitride and Azide Bridges September 2005
Anomalous One-Electron Processes in the Chemistry of Uranium Nitrogen Multiple Bonds August 2014
Thorium–phosphorus triamidoamine complexes containing Th–P single- and multiple-bond interactions September 2016
Thorium Oxo and Sulfido Metallocenes: Synthesis, Structure, Reactivity, and Computational Studies August 2011
Thorium–ligand multiple bonds via reductive deprotection of a trityl group January 2015
Metal-Ligand Multiple Bonding in Thorium Phosphorus and Thorium Arsenic Complexes November 2017
Recent developments in actinide–ligand multiple bonding January 2013
Synthesis and Structure of a Terminal Uranium Nitride Complex June 2012
Synthesis of Imido Analogs of the Uranyl Ion December 2005
Facile Access to Pentavalent Uranium Organometallics:  One-Electron Oxidation of Uranium(IV) Imido Complexes with Copper(I) Salts October 2007
Uranium(VI) Bis(imido) Chalcogenate Complexes: Synthesis and Density Functional Theory Analysis March 2009
Synthesis and Reactivity of the Imido Analogues of the Uranyl Ion August 2006
Thorium Mono- and Bis(imido) Complexes Made by Reprotonation of cyclo -Metalated Amides August 2015
Examining the Effects of Ligand Variation on the Electronic Structure of Uranium Bis(imido) Species October 2016
A Simple Preparative Route to Bis(imido)uranium(VI) Complexes by the Direct Reductions of Diazenes and Azides April 1998
Synthesis and Reduction of Uranium(V) Imido Complexes with Redox-Active Substituents April 2017
Synthesis of Heteroleptic Uranium (μ−η 6 :η 6 -C 6 H 6 ) 2− Sandwich Complexes via Facile Displacement of (η 5 -C 5 Me 5 ) 1− by Ligands of Lower Hapticity and Their Conversion to Heteroleptic Bis(imido) Compounds December 2009
Reduction of Carbonyl Groups by Uranium(III) and Formation of a Stable Amide Radical Anion December 2017
Synthesis and structure of the first uranium(VI) organometallic complex December 1992
Synthesis and structure of high-valent organouranium complexes containing terminal monooxo functional groups October 1993
Synthesis and Properties of High-Valent Organouranium Complexes Containing Terminal Organoimido and Oxo Functional Groups. A New Class of Organo-f-Element Complexes September 1995
Preparation and Reactivity of the Versatile Uranium(IV) Imido Complexes U(NAr)Cl 2 (R 2 bpy) 2 (R = Me, t Bu) and U(NAr)Cl 2 (tppo) 3 August 2014
A General and Modular Synthesis of Monoimidouranium(IV) Dihalides May 2011
A Direct Route to Bis(imido)uranium(V) Halides via Metathesis of Uranium Tetrachloride June 2012
[(C5Me5)2U][(µ-Ph)2BPh2] as a four electron reductant January 2005
Carbon–Carbon Reductive Elimination from Homoleptic Uranium(IV) Alkyls Induced by Redox-Active Ligands April 2012
Chemistry of Tris(pentamethylcyclopentadienyl) f-Element Complexes, (C 5 Me 5 ) 3 M June 2002
Reductive Elimination of Diphosphine from a Thorium–NHC–Bis(phosphido) Complex May 2017
Experimental and Theoretical Comparison of Actinide and Lanthanide Bonding in M[N(EPR 2 ) 2 ] 3 Complexes (M = U, Pu, La, Ce; E = S, Se, Te; R = Ph, i Pr, H) January 2008
Homoleptic uranium(iii) imidodiphosphinochalcogenides including the first structurally characterised molecular trivalent actinide–Se bond January 2005
A Molecular Actinide–Tellurium Bond and Comparison of Bonding in [MIII{N(TePiPr2)2}3] (M=U, La) February 2006
Covalency in the f Element−Chalcogen Bond. Computational Studies of M[N(EPR 2 ) 2 ] 3 (M = La, Ce, Pr, Pm, Eu, U, Np, Pu, Am, Cm; E = O, S, Se, Te; R = H, i Pr, Ph) September 2008
Covalency in the f-element–chalcogen bond October 2007
U(SMes*) n , ( n = 3, 4) and Ln(SMes*) 3 (Ln = La, Ce, Pr, Nd):  Lanthanide(III)/Actinide(III) Differentiation in Agostic Interactions and an Unprecedented η 3 Ligation Mode of the Arylthiolate Ligand, from X-ray Diffraction and DFT Analysis July 2006
C−H and C−S Bond Cleavage in Uranium(III) Thiolato Complexes August 2001
Formation of Trivalent U–C, U–N, and U–S Bonds and Their Reactivity toward Carbon Dioxide and Acetone November 2011
Lanthanide(III)/Actinide(III) Differentiation in Mixed Cyclopentadienyl/Dithiolene Compounds from X-ray Diffraction and Density Functional Theory Analysis October 2005
Comparison of Covalency in the Complexes of Trivalent Actinide and Lanthanide Cations August 2002
Functionalization of Carbon Dioxide and Carbon Disulfide Using a Stable Uranium(III) Alkyl Complex April 2011
Synthesis, properties, and molecular structure of a trivalent organouranium diphosphine hydride February 1982
Preparation of tertiary phosphine complexes of tetravalent and trivalent uranium methyltrihydroborates. Crystal structures of tetrakis(methyltrihydroborato)(1,2-bis(dimethylphosphino)ethane)uranium(IV) and tris(methyltrihydroborato)bis(1,2-bis(dimethylphosphino)ethane)uranium(III) December 1984
Crystal structures of (MeC5H4)3ML [M = uranium or cerium; L = quinuclidine or P(OCH2)3CEt]. Evidence for uranium to phosphorus .pi.-back-bonding June 1988
Formation of a Bridging Phosphinidene Thorium Complex November 2015
Insertion of t BuNC into thorium–phosphorus and thorium–arsenic bonds: phosphaazaallene and arsaazaallene moieties in f element chemistry January 2016
Direct conversion of carbon monoxide to a coordinated secondary alcohol derivative by a thorium phosphido complex January 1994
The synthesis and crystal structure of the thorium tetraphosphido complex, Th[P(CH 2 CH 2 PMe 2 ) 2 ] 4 , an actinide complex with only metal–phosphorus ligand bonds January 1992
Preparation of Actinide Phosphinidene Complexes:  Steric Control of Reactivity January 1996
Organoactinide phosphine/phosphite coordination chemistry. Facile hydride-induced dealkoxylation and the formation of actinide phosphinidene complexes May 1984
Triamidoamine-Uranium(IV)-Stabilized Terminal Parent Phosphide and Phosphinidene Complexes March 2014
Actinide-Pnictide (An−Pn) Bonds Spanning Non-Metal, Metalloid, and Metal Combinations (An=U, Th; Pn=P, As, Sb, Bi) December 2017
A Bridging Hexazene (RNNNNNNR) Ligand from Reductive Coupling of Azides May 2008
Insertion of Carbodiimides and Organic Azides into Actinide−Carbon Bonds June 2009
Insertion and reduction chemistry of isocyanide with a cyclometalated ditantalum hydride complex January 2011
29 Si NMR Spectra of Silicon-Containing Uranium Complexes July 2014
Synthesis of a Uranium(VI)-Carbene: Reductive Formation of Uranyl(V)-Methanides, Oxidative Preparation of a [R 2 C═U═O] 2+ Analogue of the [O═U═O] 2+ Uranyl Ion (R = Ph 2 PNSiMe 3 ), and Comparison of the Nature of U IV ═C, U V ═C, and U VI ═C Double Bonds June 2012
Synthesis, Characterization, and Reactivity of a Uranium(VI) Carbene Imido Oxo Complex May 2014
Formation of the Imide [Ta(NMe 2 ) 3 (μ-NSiMe 3 )] 2 through an Unprecedented α-SiMe 3 Abstraction by an Amide Ligand December 2011
Synthesis and reactivity of bis(imido) uranium(vi) cyclopentadienyl complexes January 2008
Uranium Metallocene Complexes of the 1,3,4,6,7,8-Hexahydro-2 H -pyrimido[1,2- a ]pyrimidinato Ligand, (hpp) − January 2010
Metathesis of a U V imido complex: a route to a terminal U V sulfide January 2017
A Series of Uranium (IV, V, VI) Tritylimido Complexes, Their Molecular and Electronic Structures and Reactivity with CO 2 November 2014
Synthesis of U(iv) imidos from Tp*2U(CH2Ph) (Tp* = hydrotris(3,5-dimethylpyrazolyl)borate) by extrusion of bibenzyl January 2012
Multiple-Bond Metathesis Mediated by Sterically Pressured Uranium Complexes April 2006
Tris[bis(trimethylsilyl)amido](trimethylsilylimido)uranium(V) September 1988
Lanthanide versus Actinide Reactivity in the Formation of Sterically Crowded [(C 5 Me 5 ) 3 ML n ] Nitrile and Isocyanide Complexes November 2009

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