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SrNi(VO4)(OH): The High-Temperature Hydrothermal Synthesis and Magnetic Properties of an Adelite-Descloizite-Type Structure

Journal Article · · Crystals
 [1];  [2];  [3];  [4];  [1];  [1];  [3]
  1. Univ. of Missouri, Columbia, MO (United States)
  2. Eastern Illinois University, Charleston, IL (United States)
  3. Clemson Univ., SC (United States). Center for Optical Materials and Engineering Technologies (COMSET)
  4. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
+ Show Author Affiliations
Single crystals of a new transition metal adelite-descloizite-type structure were synthesized using a high temperature (580 °C) high-pressure hydrothermal technique. Single crystal X-ray diffraction and energy dispersive X-ray analysis (EDX) were used to investigate the structure and elemental composition, respectively. SrNi(VO4)(OH) crystallizes in an acentric orthorhombic crystal system in the space group P212121 (no. 19); Z = 4, a = 5.9952(4) Å, b = 7.5844(4) Å, c = 9.2240(5) Å. The structure is comprised of a Ni–O–V framework where Sr2+ ions reside inside the channels. Single-crystal magnetic measurements display a significant anisotropy in both temperature- and field-dependent data. The temperature dependent magnetic measurement shows antiferromagnetic behavior at TN~8 K. Overall, the magnetic properties indicate the presence of competing antiferromagnetic and ferromagnetic interactions of SrNi(VO4)(OH).
Research Organization:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES); University of Missouri Research Council
Grant/Contract Number:
AC05-00OR22725
OSTI ID:
1923145
Journal Information:
Crystals, Journal Name: Crystals Journal Issue: 10 Vol. 12; ISSN 2073-4352
Publisher:
MDPICopyright Statement
Country of Publication:
United States
Language:
English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
antiferromagnetism
hydrothermal
nickel(III)
vanadates