Observation of a Large Magnetic Anisotropy and a Field-Induced Magnetic State in SrCo(VO4)(OH): A Structure with a Quasi One-Dimensional Magnetic Chain

Sanjeewa, Liurukara D.; Garlea, Vasile Ovidiu; Fishman, Randy S.; McGuire, Michael A.; Xing, Jie; Cao, Huibo; Kolis, Joseph W.; Sefat, Athena Safa

doi:10.1021/acs.inorgchem.9b02427

Title: Observation of a Large Magnetic Anisotropy and a Field-Induced Magnetic State in SrCo(VO₄)(OH): A Structure with a Quasi One-Dimensional Magnetic Chain

Journal Article · Tue Dec 17 00:00:00 EST 2019 · Inorganic Chemistry

DOI:https://doi.org/10.1021/acs.inorgchem.9b02427· OSTI ID:1761717

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Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division; Clemson Univ., SC (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Neutron Scattering Division
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division
Clemson Univ., SC (United States)

A new member of the descloizite family, a cobalt vanadate, SrCo(VO₄)(OH), has been synthesized as large single crystals using high-temperature and high-pressure hydrothermal methods. SrCo(VO₄)(OH) crystallizes in the orthorhombic crystal system in space group P2₁2₁2₁ with the following unit cell parameters: a = 6.0157(2) Å, b = 7.645(2) Å, c = 9.291(3) Å, V = 427.29(2) Å³, and Z = 4. It contains one-dimensional Co–O–Co chains of edge-sharing CoO₆ octahedra along the a-axis connected to each other via VO₄ tetrahedra along the b-axis forming a three-dimensional structure. The magnetic susceptibility of SrCo(VO₄)(OH) indicates an antiferromagnetic transition at 10 K as well as unusually large spin orbit coupling. Single-crystal magnetic measurements in all three main crystallographic directions displayed a significant anisotropy in both temperature- and field-dependent data. Single-crystal neutron diffraction at 4 K was used to characterize the magnetically ordered state. The Co²⁺ magnetic spins are arranged in a staggered configuration along the chain direction, with a canting angle that follows the tipping of the CoO₆ octahedra. The net magnetization along the chain direction, resulting in ferromagnetic coupling of the a-axis spin components in each chain, is compensated by an antiferromagnetic interaction between nearest neighbor chains. A metamagnetic transition appears in the isothermal magnetization data at 2 K along the chain direction, which seems to correspond to a co-alignment of the spin directions of the nearest neighbor chain. We propose a phenomenological spin Hamiltonian that describes the canted spin configuration of the ground state and the metamagnetic transition in SrCo(VO₄)(OH).

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)

Grant/Contract Number:: AC05-00OR22725; DMR-1410727

OSTI ID:: 1761717

Journal Information:: Inorganic Chemistry, Vol. 59, Issue 2; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Title: Observation of a Large Magnetic Anisotropy and a Field-Induced Magnetic State in SrCo(VO4)(OH): A Structure with a Quasi One-Dimensional Magnetic Chain

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Title: Observation of a Large Magnetic Anisotropy and a Field-Induced Magnetic State in SrCo(VO₄)(OH): A Structure with a Quasi One-Dimensional Magnetic Chain