Sn doping on partially dealuminated Beta zeolite by solid state ion exchange for 5‐hydroxymethylfurfural ( 5‐HMF ) production from glucose

Zhang, Wei; Shen, Zheng; Kong, Ling; Chen, Wenbo; Gu, Minyan; Xia, Meng; Dong, Wenjie; Zhang, Yalei

doi:10.1002/jctb.7282

Sn doping on partially dealuminated Beta zeolite by solid state ion exchange for 5‐hydroxymethylfurfural ( 5‐HMF ) production from glucose

Journal Article · Fri Dec 09 00:00:00 EST 2022 · Journal of Chemical Technology and Biotechnology

DOI:https://doi.org/10.1002/jctb.7282· OSTI ID:1922990

Zhang, Wei ^[1]; ^[2]; Kong, Ling ^[3]; Chen, Wenbo ^[3]; Gu, Minyan ^[1]; Xia, Meng ^[1]; Dong, Wenjie ^[4]; Zhang, Yalei ^[5]

State Key Laboratory of Pollution Control and Resource Reuse Tongji University Shanghai China
State Key Laboratory of Pollution Control and Resource Reuse Tongji University Shanghai China, National Engineering Research Center of Protected Agriculture Tongji University Shanghai China
National Engineering Research Center of Protected Agriculture Tongji University Shanghai China
College of Quality &, Safety Engineering China Jiliang University Hangzhou China
State Key Laboratory of Pollution Control and Resource Reuse Tongji University Shanghai China, National Engineering Research Center of Protected Agriculture Tongji University Shanghai China, Shanghai Institute of Pollution Control and Ecological Security Tongji University Shanghai China

Abstract BACKGROUND

The conversion of glucose into 5‐hydroxymethylfurfural (5‐HMF) involves the isomerization of glucose to fructose catalyzed by Lewis acid and subsequent dehydration of fructose catalyzed by Brönsted acid. In this work, in order to obtain a high yield of 5‐HMF, a series of Sn‐Al‐Beta catalysts containing both Lewis and Brönsted acid sites were prepared by a convenient solid state ion exchange (SSIE) method using partially dealuminated Beta zeolite and tin(II) acetate.

RESULTS

The obtained bifunctional catalysts were investigated for one‐pot production of 5‐HMF from glucose in the ionic liquid (IL) [C ₄ mim]Cl. Among various catalysts, Sn‐Al‐Beta‐ 4 ‐ 8 exhibited the best catalytic performance, giving a 5‐HMF yield of 54% under optimal reaction conditions (393 K, 2 h), along with a glucose conversion of 81%. The Sn‐Al‐Beta‐ 4‐8 catalyst and IL were regenerated by the extraction of 5‐HMF, and the reactivity was reserved after five runs of recycling. In addition to glucose, the Sn‐Al‐Beta‐ 4‐8 /[C ₄ mim]Cl system was also proven to have the potential to effectively convert other carbohydrates into 5‐HMF.

CONCLUSION

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

OSTI ID:: 1922990

Journal Information:: Journal of Chemical Technology and Biotechnology, Journal Name: Journal of Chemical Technology and Biotechnology Journal Issue: 3 Vol. 98; ISSN 0268-2575

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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