Cooperative Brønsted-Lewis acid sites created by phosphotungstic acid encapsulated metal–organic frameworks for selective glucose conversion to 5-hydroxymethylfurfural

Rahaman, Mohammad Shahinur; Tulaphol, Sarttrawut; Hossain, Md Anwar; Jasinski, Jacek B.; Sun, Ning; George, Anthe; Simmons, Blake A.; Maihom, Thana; Crocker, Mark; Sathitsuksanoh, Noppadon

doi:10.1016/j.fuel.2021.122459

Cooperative Brønsted-Lewis acid sites created by phosphotungstic acid encapsulated metal–organic frameworks for selective glucose conversion to 5-hydroxymethylfurfural

Journal Article · Fri Nov 12 00:00:00 EST 2021 · Fuel

DOI:https://doi.org/10.1016/j.fuel.2021.122459· OSTI ID:1958749

Rahaman, Mohammad Shahinur ^[1]; Tulaphol, Sarttrawut ^[2]; Hossain, Md Anwar ^[1]; ^[1]; ^[3]; George, Anthe ^[4]; Simmons, Blake A. ^[5]; Maihom, Thana ^[6]; Crocker, Mark ^[7]; ^[1]

Univ. of Louisville, KY (United States)
Univ. of Louisville, KY (United States); King Mongkut's University of Technology, Bangkok (Thailand)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Emeryville, CA (United States). Advanced Biofuels and Bioproducts Process Demonstration Unit
Sandia National Lab. (SNL-CA), Livermore, CA (United States); Joint BioEnergy Institute (JBEI), Emeryville, CA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Joint BioEnergy Institute (JBEI), Emeryville, CA (United States)
Kasetsart University (Thailand)
Univ. of Kentucky, Lexington, KY (United States)

Production of 5-hydroxymethylfurfural (HMF) from biomass-derived glucose has great potential for synthesis of renewable fuels and chemicals. Selective glucose conversion to 5-hydroxymethylfurfural requires a balance between Lewis and Brønsted acids for the cascade of glucose isomerization followed by fructose dehydration. A dual Brønsted-Lewis acid, phosphotungstic acid encapsulated MIL-101(Al)–NH₂ metal–organic frameworks (MOFs) was developed to catalyze the glucose dehydration reaction. The encapsulated catalysts had a high HMF selectivity of 58% at 44% glucose conversion at 120°C in [C₄C₁im]Cl. Phosphotungstic acid was uniformly dispersed in the MOF pores, which provided both Brønsted and Lewis acid sites for this cascade reaction. The Brønsted acidic phosphotungstic acid-encapsulated MOF catalyst was stable and recyclable at least four times. Here, these findings explain the effect of phosphotungstic acid location for maximizing the HMF selectivity and suggest a new approach for the design of bifunctional solid acid catalysts for selective HMF production from glucose. Moreover, the tunability of the acid properties of the encapsulated MOF catalysts provides opportunities for other biomass transformations.

View Accepted Manuscript (DOE)

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Science (SC), Biological and Environmental Research (BER)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1958749

Journal Information:: Fuel, Journal Name: Fuel Vol. 310; ISSN 0016-2361

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
cooperative
encapsulation
glucose dehydration
hydroxymethylfurfural
metal-organic frameworks
phosphotungstic acid

Cooperative Brønsted-Lewis acid sites created by phosphotungstic acid encapsulated metal–organic frameworks for selective glucose conversion to 5-hydroxymethylfurfural

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