Ultra-Stretchable, Ionic Conducting, Pressure-Sensitive Adhesive with Dual Role for Stable Li-Metal Batteries

Gao, Shilun; Pan, Yiyang; Li, Bingrui; Rahman, Md Anisur; Tian, Ming; Yang, Huabin; Cao, Peng‐Fei

doi:10.1002/adfm.202210543

Title: Ultra-Stretchable, Ionic Conducting, Pressure-Sensitive Adhesive with Dual Role for Stable Li-Metal Batteries

Journal Article · Thu Dec 08 00:00:00 EST 2022 · Advanced Functional Materials

DOI:https://doi.org/10.1002/adfm.202210543· OSTI ID:1908050

Gao, Shilun ^[1]; Pan, Yiyang ^[1]; Li, Bingrui ^[2];

^[3]; Tian, Ming ^[4]; Yang, Huabin ^[1];

^[5]

Nankai University, Tianjin (China)
University of Tennessee, Knoxville, TN (United States)
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Beijing University of Chemical Technology (China)
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Beijing University of Chemical Technology (China)

The practical application of lithium (Li) metal battery is impeded by the Li dendrite growth and unstable solid electrolyte interphase (SEI) layer. Herein, an ultra-stretchable and ionic conducting chemically crosslinked pressure-sensitive adhesive (cPSA) synthesized via the copolymerization of 2-ethylhexyl acrylate and acrylic acid with poly(ethyleneglycol)dimethacrylate as crosslinker (short for 70cPSA), is developed as both artificial SEI layer and solid polymer electrolyte (SPE) for stable Li-metal electrode, enabling all-solid-state Li metal batteries with excellent cycling performance. As an artificial SEI layer, the 70cPSA-modified electrodes exhibit excellent electrochemical performance in Li|70cPSA@Cu half cells and 70cPSA@Li|70cPSA@Li symmetric cells. In full cells with LiFePO₄ (LFP) as cathode, the 70cPSA@Li|LFP cell exhibits stable cycling performance over 250 cycles. Utilized as SPE, the all-solid-state Li|SPE|LFP cell delivers excellent cycling stability with a capacity retention of 86% over 500 cycles. With high-voltage LiNi_0.8Mn_0.1Co_0.1O₂ (NMC811) as cathode, the Li|SPE|NMC811 cell exhibits a discharge capacity of 124.3 mAh g^-1 with a capacity retention of 71% after 200 cycles. Furthermore, the rational design of PSAs and investigation of their dual role for stable and safe Li-metal batteries may shed a light on adhesive polymers for battery applications.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE; Natural Science Foundation of China; China Postdoctoral Science Foundation; Natural Science Foundation of Tianjin; MOE Innovation Team; Central Universities

Grant/Contract Number:: AC05-00OR22725; 21421001; 2021M701769; 18JCZDJC31400; IRT13022; buctrc202222

OSTI ID:: 1908050

Journal Information:: Advanced Functional Materials, Vol. 12, Issue 12; ISSN 1616-301X

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

References (61)

Over‐Potential Tailored Thin and Dense Lithium Carbonate Growth in Solid Electrolyte Interphase for Advanced Lithium Ion Batteries Qin, Nan; Jin, Liming; Lu, Yanyan Advanced Energy Materials, Vol. 12, Issue 15 https://doi.org/10.1002/aenm.202103402	journal	March 2022
From natural material to high-performance silicon based anode: Towards cost-efficient silicon based electrodes in high-performance Li-ion batteries Gao, Shilun; Yang, Dandan; Pan, Yiyang Electrochimica Acta, Vol. 327 https://doi.org/10.1016/j.electacta.2019.135058	journal	December 2019
Are Porous Polymers Practical to Protect Li‐Metal Anodes? ‐ Current Strategies and Future Opportunities Gao, Shilun; Li, Zhenxi; Liu, Nian Advanced Functional Materials, Vol. 32, Issue 31 https://doi.org/10.1002/adfm.202202013	journal	June 2022
Electro‐Chemo‐Mechanical Modeling of Artificial Solid Electrolyte Interphase to Enable Uniform Electrodeposition of Lithium Metal Anodes Liu, Yangyang; Xu, Xieyu; Kapitanova, Olesya O. Advanced Energy Materials, Vol. 12, Issue 9 https://doi.org/10.1002/aenm.202103589	journal	January 2022
Effect of Binder Architecture on the Performance of Silicon/Graphite Composite Anodes for Lithium Ion Batteries Cao, Peng-Fei; Naguib, Michael; Du, Zhijia ACS Applied Materials & Interfaces, Vol. 10, Issue 4 https://doi.org/10.1021/acsami.7b13205	journal	January 2018
A dual-layered artificial solid electrolyte interphase formed by controlled electrochemical reduction of LiTFSI/DME-LiNO3 for dendrite-free lithium metal anode Zhang, Chunqing; Lan, Qing; Liu, Yutao Electrochimica Acta, Vol. 306 https://doi.org/10.1016/j.electacta.2019.03.162	journal	May 2019
Suppressing Li dendrite by a protective biopolymeric film from tamarind seed polysaccharide for high-performance Li metal anode You, Jin-Hai; Zhang, Shao-Jian; Deng, Li Electrochimica Acta, Vol. 299 https://doi.org/10.1016/j.electacta.2019.01.045	journal	March 2019
A dendrite- and oxygen-proof protective layer for lithium metal in lithium–oxygen batteries Kwak, Won-Jin; Park, Jiwon; Nguyen, Trung Thien Journal of Materials Chemistry A, Vol. 7, Issue 8 https://doi.org/10.1039/C8TA11941D	journal	January 2019
Directing lateral growth of lithium dendrites in micro-compartmented anode arrays for safe lithium metal batteries Zou, Peichao; Wang, Yang; Chiang, Sum-Wai Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-02888-8	journal	January 2018
A “cation-anion regulation” synergistic anode host for dendrite-free lithium metal batteries Zhang, Weidong; Zhuang, Houlong L.; Fan, Lei Science Advances, Vol. 4, Issue 2 https://doi.org/10.1126/sciadv.aar4410	journal	February 2018
Composite protection layers for dendrite-suppressing non-granular micro-patterned lithium metal anodes Kim, Seokwoo; Park, Jinkyu; Friesen, Alex Electrochimica Acta, Vol. 282 https://doi.org/10.1016/j.electacta.2018.05.102	journal	August 2018
Ionic conductive polymers as artificial solid electrolyte interphase films in Li metal batteries – A review Gao, Shilun; Sun, Feiyuan; Liu, Nian Materials Today, Vol. 40 https://doi.org/10.1016/j.mattod.2020.06.011	journal	November 2020
Glass-fiber-reinforced polymeric film as an efficient protecting layer for stable Li metal electrodes Gao, Shilun; Cannon, Andrew; Sun, Feiyuan Cell Reports Physical Science, Vol. 2, Issue 8 https://doi.org/10.1016/j.xcrp.2021.100534	journal	August 2021
Effects of Polymer Coating Mechanics at Solid‐Electrolyte Interphase for Stabilizing Lithium Metal Anodes Huang, Zhuojun; Choudhury, Snehashis; Paul, Neelima Advanced Energy Materials, Vol. 12, Issue 5 https://doi.org/10.1002/aenm.202103187	journal	December 2021
Aligned artificial solid electrolyte interphase layers as versatile interfacial stabilizers on lithium metal anodes Li, Zihao; Ding, Xuesong; Feng, Wei Journal of Materials Chemistry A, Vol. 10, Issue 19 https://doi.org/10.1039/D2TA00119E	journal	January 2022
Ultrahigh Elastic Polymer Electrolytes for Solid-State Lithium Batteries with Robust Interfaces Zheng, Tianxiang; Cui, Ximing; Chu, Ying ACS Applied Materials & Interfaces, Vol. 14, Issue 4 https://doi.org/10.1021/acsami.1c20243	journal	January 2022
Self-Healable, Highly Stretchable, Ionic Conducting Polymers as Efficient Protecting Layers for Stable Lithium-Metal Electrodes Sun, Feiyuan; Li, Zhenxi; Gao, Shilun ACS Applied Materials & Interfaces, Vol. 14, Issue 22 https://doi.org/10.1021/acsami.2c04166	journal	May 2022
Advanced Ultralow‐Concentration Electrolyte for Wide‐Temperature and High‐Voltage Li‐Metal Batteries Wang, Zhicheng; Zhang, Haiyang; Xu, Jingjing Advanced Functional Materials, Vol. 32, Issue 23 https://doi.org/10.1002/adfm.202112598	journal	March 2022
Highly stable lithium metal anode enabled by lithiophilic and spatial-confined spherical-covalent organic framework Wang, Wenbo; Yang, Zehua; Zhang, Yantao Energy Storage Materials, Vol. 46 https://doi.org/10.1016/j.ensm.2022.01.018	journal	April 2022
Interface Between Solid-State Electrolytes and Li-Metal Anodes: Issues, Materials, and Processing Routes Tong, Zizheng; Wang, Shu-Bo; Liao, Yu-Kai ACS Applied Materials & Interfaces, Vol. 12, Issue 42 https://doi.org/10.1021/acsami.0c13591	journal	October 2020
High Performance Composite Polymer Electrolytes for Lithium‐Ion Batteries Fan, Peng; Liu, Hao; Marosz, Vladimir Advanced Functional Materials, Vol. 31, Issue 23 https://doi.org/10.1002/adfm.202101380	journal	April 2021
Self-exfoliated covalent organic framework nano-mesh enabled regular charge distribution for highly stable lithium metal battery Zhang, Yunrui; Wang, Wenbo; Hou, Meiling Energy Storage Materials, Vol. 47 https://doi.org/10.1016/j.ensm.2022.02.029	journal	May 2022
Organic-inorganic composite SEI for a stable Li metal anode by in-situ polymerization Cao, Wenzhuo; Lu, Jiaze; Zhou, Kun Nano Energy, Vol. 95 https://doi.org/10.1016/j.nanoen.2022.106983	journal	May 2022
Plastic crystal in rubbery matrix for light and safe batteries Gao, Shilun; Zhang, Mingxin; Gainaru, Catalin Matter, Vol. 5, Issue 8 https://doi.org/10.1016/j.matt.2022.05.046	journal	August 2022
Single‐Ion Conducting Polymer Electrolytes for Solid‐State Lithium–Metal Batteries: Design, Performance, and Challenges Zhu, Jiadeng; Zhang, Zhen; Zhao, Sheng Advanced Energy Materials, Vol. 11, Issue 14 https://doi.org/10.1002/aenm.202003836	journal	February 2021
Improved Single-Ion Conductivity of Polymer Electrolyte via Accelerated Segmental Dynamics Zhao, Sheng; Zhang, Yiman; Pham, Hoang ACS Applied Energy Materials, Vol. 3, Issue 12 https://doi.org/10.1021/acsaem.0c02079	journal	December 2020
Double-Layer Polymer Electrolyte for High-Voltage All-Solid-State Rechargeable Batteries Zhou, Weidong; Wang, Zhaoxu; Pu, Yuan Advanced Materials, Vol. 31, Issue 4 https://doi.org/10.1002/adma.201805574	journal	December 2018
Macromolecular Design of Lithium Conductive Polymer as Electrolyte for Solid‐State Lithium Batteries Meng, Nan; Lian, Fang; Cui, Guanglei Small, Vol. 17, Issue 3 https://doi.org/10.1002/smll.202005762	journal	December 2020
Nanostructured Polymer Electrolytes for Lithium-Ion Batteries Yoon, Jeong Hoon; Cho, Won-Jang; Kang, Tae Hui Macromolecular Research, Vol. 29, Issue 8 https://doi.org/10.1007/s13233-021-9073-9	journal	August 2021
Tailoring the near-Surface Composition Profiles of Pressure-Sensitive Adhesive Films and the Resulting Mechanical Properties Diethert, Alexander; Ecker, Katharina; Peykova, Yana ACS Applied Materials & Interfaces, Vol. 3, Issue 6 https://doi.org/10.1021/am200254m	journal	June 2011
Crosslinking of pressure sensitive adhesive based on water-borne acrylate Czech, Z. Polymer International, Vol. 52, Issue 3 https://doi.org/10.1002/pi.1151	journal	January 2003
Silicone Liner-Free Pressure-Sensitive Adhesive Labels Empereur, Johanne; Belgacem, Mohamed Naceur; Chaussy, Didier Macromolecular Materials and Engineering, Vol. 293, Issue 3 https://doi.org/10.1002/mame.200700292	journal	February 2008
Unique adhesive properties of pressure sensitive adhesives from plant oils Maassen, Wiebke; Meier, Michael A. R.; Willenbacher, Norbert International Journal of Adhesion and Adhesives, Vol. 64 https://doi.org/10.1016/j.ijadhadh.2015.10.004	journal	January 2016
Fracture and adhesion of soft materials: a review Creton, Costantino; Ciccotti, Matteo Reports on Progress in Physics, Vol. 79, Issue 4 https://doi.org/10.1088/0034-4885/79/4/046601	journal	March 2016
Adhesive Polymers as Efficient Binders for High-Capacity Silicon Electrodes Pan, Yiyang; Ge, Sirui; Rashid, Zahid ACS Applied Energy Materials, Vol. 3, Issue 4 https://doi.org/10.1021/acsaem.9b02420	journal	March 2020
Enhanced Adhesion and Cohesion of Bioinspired Dry/Wet Pressure-Sensitive Adhesives Tiu, Brylee David B.; Delparastan, Peyman; Ney, Max R. ACS Applied Materials & Interfaces, Vol. 11, Issue 31 https://doi.org/10.1021/acsami.9b08429	journal	July 2019
A Flexible Solid Electrolyte Interphase Layer for Long-Life Lithium Metal Anodes Li, Nian-Wu; Shi, Yang; Yin, Ya-Xia Angewandte Chemie International Edition, Vol. 57, Issue 6 https://doi.org/10.1002/anie.201710806	journal	January 2018
Organic–Organic Composite Electrolyte Enables Ultralong Cycle Life in Solid-State Lithium Metal Batteries Xue, Chuanjiao; Zhang, Xue; Wang, Shuo ACS Applied Materials & Interfaces, Vol. 12, Issue 22 https://doi.org/10.1021/acsami.0c05643	journal	May 2020
One-Pot Synthesis of Polyester-Based Linear and Graft Copolymers for Solid Polymer Electrolytes Guo, Kairui; Li, Shaoqiao; Chen, Gong CCS Chemistry, Vol. 4, Issue 9 https://doi.org/10.31635/ccschem.021.202101364	journal	September 2022
High-Performance Lithium Metal Negative Electrode with a Soft and Flowable Polymer Coating Zheng, Guangyuan; Wang, Chao; Pei, Allen ACS Energy Letters, Vol. 1, Issue 6 https://doi.org/10.1021/acsenergylett.6b00456	journal	November 2016
Self-healing and thermoreversible rubber from supramolecular assembly Cordier, Philippe; Tournilhac, François; Soulié-Ziakovic, Corinne Nature, Vol. 451, Issue 7181, p. 977-980 https://doi.org/10.1038/nature06669	journal	February 2008
Elastomeric electrolytes for high-energy solid-state lithium batteries Lee, Michael J.; Han, Junghun; Lee, Kyungbin Nature, Vol. 601, Issue 7892 https://doi.org/10.1038/s41586-021-04209-4	journal	January 2022
AlF ₃ -Modified carbon nanofibers as a multifunctional 3D interlayer for stable lithium metal anodes Guo, Cheng; Yang, Huijun; Naveed, Ahmad Chemical Communications, Vol. 54, Issue 60 https://doi.org/10.1039/C8CC04422H	journal	January 2018
Polyethylene oxide film coating enhances lithium cycling efficiency of an anode-free lithium-metal battery Assegie, Addisu Alemayehu; Cheng, Ju-Hsiang; Kuo, Li-Ming Nanoscale, Vol. 10, Issue 13 https://doi.org/10.1039/C7NR09058G	journal	January 2018
Core–Shell Nanoparticle Coating as an Interfacial Layer for Dendrite-Free Lithium Metal Anodes Liu, Wei; Li, Weiyang; Zhuo, Denys ACS Central Science, Vol. 3, Issue 2 https://doi.org/10.1021/acscentsci.6b00389	journal	January 2017
Critical Parameters for Evaluating Coin Cells and Pouch Cells of Rechargeable Li-Metal Batteries Chen, Shuru; Niu, Chaojiang; Lee, Hongkyung Joule, Vol. 3, Issue 4 https://doi.org/10.1016/j.joule.2019.02.004	journal	April 2019
A Novel Organic “Polyurea” Thin Film for Ultralong-Life Lithium-Metal Anodes via Molecular-Layer Deposition Sun, Yipeng; Zhao, Yang; Wang, Jiwei Advanced Materials, Vol. 31, Issue 4 https://doi.org/10.1002/adma.201806541	journal	December 2018
A Dynamic, Electrolyte-Blocking, and Single-Ion-Conductive Network for Stable Lithium-Metal Anodes Yu, Zhiao; Mackanic, David G.; Michaels, Wesley Joule, Vol. 3, Issue 11 https://doi.org/10.1016/j.joule.2019.07.025	journal	November 2019
Surface Fluorination of Reactive Battery Anode Materials for Enhanced Stability Zhao, Jie; Liao, Lei; Shi, Feifei Journal of the American Chemical Society, Vol. 139, Issue 33 https://doi.org/10.1021/jacs.7b05251	journal	August 2017
Stability of Solid Electrolyte Interphase Components on Lithium Metal and Reactive Anode Material Surfaces Leung, Kevin; Soto, Fernando; Hankins, Kie The Journal of Physical Chemistry C, Vol. 120, Issue 12 https://doi.org/10.1021/acs.jpcc.5b11719	journal	March 2016
Investigating dry room compatibility of sulfide solid-state electrolytes for scalable manufacturing Chen, Yu-Ting; Marple, Maxwell A. T.; Tan, Darren H. S. Journal of Materials Chemistry A, Vol. 10, Issue 13 https://doi.org/10.1039/D1TA09846B	journal	January 2022
Designing solid-state electrolytes for safe, energy-dense batteries Zhao, Qing; Stalin, Sanjuna; Zhao, Chen-Zi Nature Reviews Materials, Vol. 5, Issue 3 https://doi.org/10.1038/s41578-019-0165-5	journal	February 2020
Elastic Single-Ion Conducting Polymer Electrolytes: Toward a Versatile Approach for Intrinsically Stretchable Functional Polymers Cao, Peng-Fei; Li, Bingrui; Yang, Guang Macromolecules, Vol. 53, Issue 9 https://doi.org/10.1021/acs.macromol.9b02683	journal	April 2020
Flexible, Flame-Resistant, and Dendrite-Impermeable Gel-Polymer Electrolyte for Li-O ₂ /Air Batteries Workable Under Hurdle Conditions Zou, Xiaohong; Lu, Qian; Zhong, Yijun Small, Vol. 14, Issue 34 https://doi.org/10.1002/smll.201801798	journal	July 2018
Self-Healing Solid Polymer Electrolyte for Room-Temperature Solid-State Lithium Metal Batteries Zhang, Lanshuang; Zhang, Panpan; Chang, Caiyun ACS Applied Materials & Interfaces, Vol. 13, Issue 39 https://doi.org/10.1021/acsami.1c14462	journal	September 2021
High Energy Density Solid State Lithium Metal Batteries Enabled by Sub‐5 µm Solid Polymer Electrolytes He, Fei; Tang, Wenjing; Zhang, Xinyue Advanced Materials, Vol. 33, Issue 45 https://doi.org/10.1002/adma.202105329	journal	September 2021
10 μm‐Thick High‐Strength Solid Polymer Electrolytes with Excellent Interface Compatibility for Flexible All‐Solid‐State Lithium‐Metal Batteries Wang, Zhiyan; Shen, Lin; Deng, Shungui Advanced Materials, Vol. 33, Issue 25 https://doi.org/10.1002/adma.202100353	journal	May 2021
Ultrathin, flexible, solid polymer composite electrolyte enabled with aligned nanoporous host for lithium batteries Wan, Jiayu; Xie, Jin; Kong, Xian Nature Nanotechnology, Vol. 14, Issue 7 https://doi.org/10.1038/s41565-019-0465-3	journal	May 2019
Electrochemical Kinetics of Lithium Plating and Stripping in Solid Polymer Electrolytes: Pulsed Voltammetry Berliner, Marc D.; McGill, Brandon C.; Majeed, Muneeb Journal of The Electrochemical Society, Vol. 166, Issue 2 https://doi.org/10.1149/2.0851902jes	journal	January 2019
Structural Dynamics of Strongly Segregated Block Copolymer Electrolytes Oparaji, Onyekachi; Narayanan, Suresh; Sandy, Alec Macromolecules, Vol. 51, Issue 7 https://doi.org/10.1021/acs.macromol.7b01803	journal	March 2018
Design of ionic liquid like monomers towards easy-accessible single-ion conducting polymer electrolytes Porcarelli, Luca; Vlasov, Petr S.; Ponkratov, Denis O. European Polymer Journal, Vol. 107 https://doi.org/10.1016/j.eurpolymj.2018.08.014	journal	October 2018

Similar Records

Constructing a multi-functional polymer network for ultra-stable and safe Li-metal batteries

Journal Article · Mon Nov 28 00:00:00 EST 2022 · Energy Storage Materials · OSTI ID:1908050

Gao, Shilun; Li, Zhenxi; Zhang, Zhen; +7 more

High Interfacial-Energy Interphase Promoting Safe Lithium Metal Batteries

Journal Article · Sun Jan 12 00:00:00 EST 2020 · Journal of the American Chemical Society · OSTI ID:1908050

Liu, Sufu; Ji, Xiao; Yue, Jie; +9 more

Design of a multi-functional gel polymer electrolyte with a 3D compact stacked polymer micro-sphere matrix for high-performance lithium metal batteries

Journal Article · Mon May 16 00:00:00 EDT 2022 · Journal of Materials Chemistry. A · OSTI ID:1908050

Liang, Jiyuan; Tao, Runming; Tu, Ji; +9 more

Related Subjects

25 ENERGY STORAGE

Title: Ultra-Stretchable, Ionic Conducting, Pressure-Sensitive Adhesive with Dual Role for Stable Li-Metal Batteries

Citation Formats

References (61)

Similar Records

Related Subjects