Yttrium-based Double Perovskite Nanorods for Electrocatalysis

McGuire, Scott C.; Wesley, Weiqiao; Sasaki, Kotaro; Tong, Xiao; Wong, Stanislaus S.

doi:10.1021/acsami.2c07377

Yttrium-based Double Perovskite Nanorods for Electrocatalysis

Journal Article · Mon Jun 27 00:00:00 EDT 2022 · ACS Applied Materials and Interfaces

DOI:https://doi.org/10.1021/acsami.2c07377· OSTI ID:1898630

McGuire, Scott C. ^[1]; Wesley, Weiqiao ^[1]; ^[2]; Tong, Xiao ^[2]; ^[1]

State Univ. of New York (SUNY), Stony Brook, NY (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)

In this work, we investigate the effect of chemical composition of double perovskite nanorods on their versatile electrocatalytic activity not only as supports for the oxidation of small organic molecules but also as catalysts for the oxygen evolution reaction. Specifically, Y₂CoMnO₆ and Y₂NiMnO₆ nanorods with average diameters of 300 nm were prepared by a two-step hydrothermal method, in which the individual effects of synthetic parameters, such as the pH, annealing temperature, and precursor ratios on both the composition and morphology, were systematically investigated. When used as supports for Pt nanoparticles, Y₂CoMnO₆/Pt catalysts exhibited an electrocatalytic activity for the methanol oxidation reaction, which is 2.1 and 1.3 times higher than that measured for commercial Pt/C and Y₂NiMnO₆/Pt. Similarly, the Co-based catalyst support material displayed an ethanol oxidation activity, which is 2.3 times higher than both Pt/C and Y₂NiMnO₆/Pt. This clear enhancement in the activity for Y₂CoMnO₆ can largely be attributed to strong metal-support interactions, as evidenced by a downshift in the binding energy of the Pt 4f bands, measured by XPS, which is often correlated not only with a downshift in the d-band center but also to a decreased adsorption of poisoning adsorbates. Moreover, when used as catalysts for the oxygen evolution reaction, Y₂CoMnO₆ displayed a much greater activity as compared with Y₂NiMnO₆. This behavior can largely be attributed not only to a preponderance of comparatively more favorable oxidation states and electronic configurations but also to the formation of an active layer on the surface of the Y₂CoMnO₆ catalyst, which collectively give rise to improved performance metrics and greater stability as compared with both IrO₂ and Y₂NiMnO₆. Overall, these results highlight the importance of both the chemical composition and the electronic structure of double perovskites, especially when utilized in multi-functional roles as either supports or catalysts.

View Accepted Manuscript (DOE)

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office

Grant/Contract Number:: SC0012704

OSTI ID:: 1898630

Report Number(s):: BNL-223698-2022-JAAM

Journal Information:: ACS Applied Materials and Interfaces, Journal Name: ACS Applied Materials and Interfaces Journal Issue: 27 Vol. 14; ISSN 1944-8244

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (66)

New Undisputed Evidence and Strategy for Enhanced Lattice‐Oxygen Participation of Perovskite Electrocatalyst through Cation Deficiency Manipulation Xu, Xiaomin; Pan, Yangli; Zhong, Yijun Advanced Science, Vol. 9, Issue 14 https://doi.org/10.1002/advs.202200530	journal	March 2022
Recent Progress on Structurally Ordered Materials for Electrocatalysis Sun, Hainan; Song, Sanzhao; Xu, Xiaomin Advanced Energy Materials, Vol. 11, Issue 37 https://doi.org/10.1002/aenm.202101937	journal	August 2021
Ultrathin PtPdTe Nanowires as Superior Catalysts for Methanol Electrooxidation Li, Hui-Hui; Zhao, Shuo; Gong, Ming Angewandte Chemie International Edition, Vol. 52, Issue 29 https://doi.org/10.1002/anie.201302090	journal	June 2013
Perovskite materials in energy storage and conversion: Perovskite materials in energy storage and conversion Zhu, Liang; Ran, Ran; Tadé, Moses Asia-Pacific Journal of Chemical Engineering, Vol. 11, Issue 3 https://doi.org/10.1002/apj.2000	journal	May 2016
Bifunctional Perovskite Oxide Catalysts for Oxygen Reduction and Evolution in Alkaline Media Gupta, Shiva; Kellogg, William; Xu, Hui Chemistry - An Asian Journal, Vol. 11, Issue 1 https://doi.org/10.1002/asia.201500640	journal	September 2015
Nanoscale Perovskites as Catalysts and Supports for Direct Methanol Fuel Cells Li, Luyao; Tan, Sha; Salvatore, Kenna L. Chemistry – A European Journal, Vol. 25, Issue 33 https://doi.org/10.1002/chem.201805695	journal	April 2019
Advances in Porous Perovskites: Synthesis and Electrocatalytic Performance in Fuel Cells and Metal–Air Batteries Yu, Jie; Ran, Ran; Zhong, Yijun ENERGY & ENVIRONMENTAL MATERIALS, Vol. 3, Issue 2 https://doi.org/10.1002/eem2.12064	journal	February 2020
Development of Perovskite Oxide‐Based Electrocatalysts for Oxygen Evolution Reaction Liu, Dong; Zhou, Pengfei; Bai, Haoyun Small, Vol. 17, Issue 43 https://doi.org/10.1002/smll.202101605	journal	July 2021
Recent Advances in Novel Nanostructuring Methods of Perovskite Electrocatalysts for Energy-Related Applications Xu, Xiaomin; Wang, Wei; Zhou, Wei Small Methods, Vol. 2, Issue 7 https://doi.org/10.1002/smtd.201800071	journal	May 2018
Low-temperature growth of Y 2 O 3 thin films by ultraviolet-assisted pulsed laser deposition Craciun, V.; Howard, J.; Lambers, E. S. Applied Physics A: Materials Science & Processing, Vol. 69, Issue 7 https://doi.org/10.1007/s003390051464	journal	December 1999
Pt–Ni alloy nanoparticles supported on multiwalled carbon nanotubes for methanol oxidation in alkaline media Xiong, Liang; Yang, Xikun; Xu, Mingli Journal of Solid State Electrochemistry, Vol. 17, Issue 3 https://doi.org/10.1007/s10008-012-1905-2	journal	November 2012
Surface electronic structure and reactivity of transition and noble metals1Communication presented at the First Francqui Colloquium, Brussels, 19–20 February 1996.1 Ruban, A.; Hammer, B.; Stoltze, P. Journal of Molecular Catalysis A: Chemical, Vol. 115, Issue 3 https://doi.org/10.1016/S1381-1169(96)00348-2	journal	February 1997
Perovskite oxides as bifunctional oxygen electrocatalysts for oxygen evolution/reduction reactions – A mini review Wang, Haizhen; Zhou, Meng; Choudhury, Pabitra Applied Materials Today, Vol. 16 https://doi.org/10.1016/j.apmt.2019.05.004	journal	September 2019
Seed-mediated synthesis of cross-linked Pt-NiO nanochains for methanol oxidation Gu, Zhulan; Bin, Duan; Feng, Yue Applied Surface Science, Vol. 411 https://doi.org/10.1016/j.apsusc.2017.03.190	journal	July 2017
Blocking the defect sites on ultrathin Pt nanowires with Rh atoms to optimize the reaction path toward alcohol fuel oxidation Zhao, Xiaoyu; Zhao, Huachao; Sun, Jiefang Chinese Chemical Letters, Vol. 31, Issue 7 https://doi.org/10.1016/j.cclet.2020.01.005	journal	July 2020
Vibrational properties and infrared dielectric features of Gd2CoMnO6 and Y2CoMnO6 double perovskites Silva, R. X.; Almeida, R. M.; Moreira, R. L. Ceramics International, Vol. 45, Issue 4 https://doi.org/10.1016/j.ceramint.2018.11.168	journal	March 2019
Preparation of Pt/NiO-C electrocatalyst and heat-treatment effect on its electrocatalytic performance for methanol oxidation Kim, Dong Baek; Chun, Hee-Joon; Lee, Yoon Kyung International Journal of Hydrogen Energy, Vol. 35, Issue 1 https://doi.org/10.1016/j.ijhydene.2009.10.037	journal	January 2010
Synthesis, characterization and formation mechanism of dumbbell-like YOHCO3 and rod-like Y2(CO3)3·2.5H2O Zhang, Youjin; Gao, Minrui; Han, Kaidong Journal of Alloys and Compounds, Vol. 474, Issue 1-2 https://doi.org/10.1016/j.jallcom.2008.07.007	journal	April 2009
Origin and tuning of room temperature ferromagnetism and ferroelectricity in double perovskite Y2NiMnO6 nanostructured thin films Alam, Mahebub; Mandal, Kalyan; Khan, Gobinda Gopal Journal of Alloys and Compounds, Vol. 822 https://doi.org/10.1016/j.jallcom.2019.153540	journal	May 2020
Growth and characterization of Y2O3 thin films Cheng, Xuerui; Qi, Zeming; Zhang, Guobin Physica B: Condensed Matter, Vol. 404, Issue 1 https://doi.org/10.1016/j.physb.2008.10.022	journal	January 2009
Double Perovskites in Catalysis, Electrocatalysis, and Photo(electro)catalysis Xu, Xiaomin; Zhong, Yijun; Shao, Zongping Trends in Chemistry, Vol. 1, Issue 4 https://doi.org/10.1016/j.trechm.2019.05.006	journal	July 2019
Experimental Methods for Quantifying the Activity of Platinum Electrocatalysts for the Oxygen Reduction Reaction Garsany, Yannick; Baturina, Olga A.; Swider-Lyons, Karen E. Analytical Chemistry, Vol. 82, Issue 15 https://doi.org/10.1021/ac100306c	journal	August 2010
Stabilizing Double Perovskite for Effective Bifunctional Oxygen Electrocatalysis in Alkaline Conditions Hua, Bin; Sun, Yi-Fei; Li, Meng Chemistry of Materials, Vol. 29, Issue 15 https://doi.org/10.1021/acs.chemmater.7b01114	journal	July 2017
Fundamental Understanding and Application of Ba_0.5Sr_0.5Co_0.8Fe_0.2O_3−δ Perovskite in Energy Storage and Conversion: Past, Present, and Future Xu, Xiaomin; Su, Chao; Shao, Zongping Energy & Fuels, Vol. 35, Issue 17 https://doi.org/10.1021/acs.energyfuels.1c02111	journal	August 2021
Mechanistic Study of IrO ₂ Dissolution during the Electrocatalytic Oxygen Evolution Reaction Zagalskaya, Alexandra; Alexandrov, Vitaly The Journal of Physical Chemistry Letters, Vol. 11, Issue 7 https://doi.org/10.1021/acs.jpclett.0c00335	journal	March 2020
Controllable P Doping of the LaCoO₃ Catalyst for Efficient Propane Oxidation: Optimized Surface Co Distribution and Enhanced Oxygen Vacancies Luo, Yongjin; Zheng, Yingbin; Feng, Xiaoshan ACS Applied Materials & Interfaces, Vol. 12, Issue 21 https://doi.org/10.1021/acsami.0c01599	journal	May 2020
Bifunctional LaMn_0.3Co_0.7O₃ Perovskite Oxide Catalyst for Oxygen Reduction and Evolution Reactions: The Optimized e_g Electronic Structures by Manganese Dopant Sun, Jia; Du, Lei; Sun, Baoyu ACS Applied Materials & Interfaces, Vol. 12, Issue 22 https://doi.org/10.1021/acsami.0c03983	journal	May 2020
Enhanced Electrocatalytic Oxidation of Small Organic Molecules on Platinum-Gold Nanowires: Influence of the Surface Structure and Pt-Pt/Pt-Au Pair Site Density Smina, Nicole; Rosen, Adam; Sztaberek, Lukasz ACS Applied Materials & Interfaces, Vol. 13, Issue 50 https://doi.org/10.1021/acsami.1c17244	journal	December 2021
Magnetism-Driven Ferroelectricity in Double Perovskite Y ₂ NiMnO ₆ Su, J.; Yang, Z. Z.; Lu, X. M. ACS Applied Materials & Interfaces, Vol. 7, Issue 24 https://doi.org/10.1021/acsami.5b00911	journal	June 2015
Double Perovskites as Model Bifunctional Catalysts toward Rational Design: The Correlation between Electrocatalytic Activity and Complex Spin Configuration Jiang, Min; Li, Jun; Zhao, Yu ACS Applied Materials & Interfaces, Vol. 10, Issue 23 https://doi.org/10.1021/acsami.8b05353	journal	May 2018
Enhancing Bifunctional Electrocatalytic Activities via Metal d-Band Center Lift Induced by Oxygen Vacancy on the Subsurface of Perovskites Lee, Hansol; Gwon, Ohhun; Choi, Keunsu ACS Catalysis, Vol. 10, Issue 8 https://doi.org/10.1021/acscatal.0c01104	journal	March 2020
A Perspective on Thin-Film Perovskites as Supports for Metal Catalysts Mao, Xinyu; Lin, Chao; Graham, George W. ACS Catalysis, Vol. 10, Issue 15 https://doi.org/10.1021/acscatal.0c02360	journal	July 2020
Perovskite Oxide Based Materials for Energy and Environment-Oriented Photocatalysis Kumar, Ashish; Kumar, Ajay; Krishnan, Venkata ACS Catalysis, Vol. 10, Issue 17 https://doi.org/10.1021/acscatal.0c02947	journal	August 2020
Platinum–Ruthenium Nanotubes and Platinum–Ruthenium Coated Copper Nanowires As Efficient Catalysts for Electro-Oxidation of Methanol Zheng, Jie; Cullen, David A.; Forest, Robert V. ACS Catalysis, Vol. 5, Issue 3 https://doi.org/10.1021/cs501449y	journal	February 2015
Mixed-Metal Pt Monolayer Electrocatalysts with Improved CO Tolerance Nilekar, Anand Udaykumar; Sasaki, Kotaro; Farberow, Carrie A. Journal of the American Chemical Society, Vol. 133, Issue 46 https://doi.org/10.1021/ja2072675	journal	November 2011
Vibronic Superexchange in Double Perovskite Electrocatalyst for Efficient Electrocatalytic Oxygen Evolution Tong, Yun; Wu, Junchi; Chen, Pengzuo Journal of the American Chemical Society, Vol. 140, Issue 36 https://doi.org/10.1021/jacs.8b06108	journal	August 2018
Highly Active and Stable Metal Single-Atom Catalysts Achieved by Strong Electronic Metal–Support Interactions Li, Junjie; Guan, Qiaoqiao; Wu, Hong Journal of the American Chemical Society, Vol. 141, Issue 37 https://doi.org/10.1021/jacs.9b06482	journal	September 2019
Electronic Structures of Pt−Co and Pt−Ru Alloys for CO-Tolerant Anode Catalysts in Polymer Electrolyte Fuel Cells Studied by EC−XPS Wakisaka, Mitsuru; Mitsui, Satoshi; Hirose, Yoshikazu The Journal of Physical Chemistry B, Vol. 110, Issue 46 https://doi.org/10.1021/jp0653510	journal	November 2006
Morphology-Controlled Promoting Activity of Nanostructured MnO ₂ for Methanol and Ethanol Electrooxidation on Pt/C Meher, Sumanta Kumar; Rao, G. Ranga The Journal of Physical Chemistry C, Vol. 117, Issue 10 https://doi.org/10.1021/jp3093995	journal	March 2013
Design principles for oxygen-reduction activity on perovskite oxide catalysts for fuel cells and metal–air batteries Suntivich, Jin; Gasteiger, Hubert A.; Yabuuchi, Naoaki Nature Chemistry, Vol. 3, Issue 7, p. 546-550 https://doi.org/10.1038/nchem.1069	journal	June 2011
A first principles comparison of the mechanism and site requirements for the electrocatalytic oxidation of methanol and formic acid over Pt Neurock, Matthew; Janik, Michael; Wieckowski, Andrzej Faraday Discuss., Vol. 140 https://doi.org/10.1039/B804591G	journal	January 2009
Toward the rational design of non-precious transition metal oxides for oxygen electrocatalysis Hong, Wesley T.; Risch, Marcel; Stoerzinger, Kelsey A. Energy & Environmental Science, Vol. 8, Issue 5 https://doi.org/10.1039/C4EE03869J	journal	January 2015
Phase-segregated Pt–Ni chain-like nanohybrids with high electrocatalytic activity towards methanol oxidation reaction Wang, Li-Li; Zhang, Dong-Feng; Guo, Lin Nanoscale, Vol. 6, Issue 9 https://doi.org/10.1039/C4NR00139G	journal	January 2014
Hydrothermal synthesis and multiferroic properties of Y ₂ NiMnO ₆ Zhang, Chenyang; Zhang, Tingsong; Ge, Lei RSC Adv., Vol. 4, Issue 92 https://doi.org/10.1039/C4RA07099B	journal	January 2014
Double perovskite Y₂NiMnO₆ nanowires: high temperature ferromagnetic–ferroelectric multiferroic Alam, Mahebub; Mandal, Kalyan; Khan, Gobinda Gopal RSC Advances, Vol. 6, Issue 67 https://doi.org/10.1039/C6RA10861J	journal	January 2016
Effect of morphology on the oxygen evolution reaction for La _0.8 Sr _0.2 Co _0.2 Fe _0.8 O _3−δ electrochemical catalyst in alkaline media Wang, Zhuang; Li, Mian; Liang, Chenghao RSC Advances, Vol. 6, Issue 73 https://doi.org/10.1039/C6RA14770D	journal	January 2016
Electrochemical supercapacitor based on double perovskite Y ₂ NiMnO ₆ nanowires Alam, Mahebub; Karmakar, Keshab; Pal, Monalisa RSC Advances, Vol. 6, Issue 115 https://doi.org/10.1039/C6RA23318J	journal	January 2016
Oxide perovskites, double perovskites and derivatives for electrocatalysis, photocatalysis, and photovoltaics Yin, Wan-Jian; Weng, Baicheng; Ge, Jie Energy & Environmental Science, Vol. 12, Issue 2 https://doi.org/10.1039/C8EE01574K	journal	January 2019
Anionic defect engineering of transition metal oxides for oxygen reduction and evolution reactions Zhu, Yunmin; Liu, Xi; Jin, Shiguang Journal of Materials Chemistry A, Vol. 7, Issue 11 https://doi.org/10.1039/C8TA12477A	journal	January 2019
Pt nanoparticles supported on YCo_xFe_1−xO₃ perovskite oxides: highly efficient catalysts for liquid-phase hydrogenation of cinnamaldehyde Xue, Yujie; Xin, Huiyue; Xie, Wenhui Chemical Communications, Vol. 55, Issue 23 https://doi.org/10.1039/C9CC00318E	journal	January 2019
Effect of A-site substitution on the simultaneous catalytic removal of NO_x and soot by LaMnO₃ perovskites Zhao, Hairui; Sun, Lvesheng; Fu, Maochen New Journal of Chemistry, Vol. 43, Issue 29 https://doi.org/10.1039/C9NJ01444F	journal	January 2019
Climbing the oxygen reduction reaction volcano plot with laser ablation synthesis of Pt_xY nanoalloys Brandiele, Riccardo; Guadagnini, Andrea; Girardi, Leonardo Catalysis Science & Technology, Vol. 10, Issue 14 https://doi.org/10.1039/D0CY00983K	journal	January 2020
The role of oxygen vacancies of ABO ₃ perovskite oxides in the oxygen reduction reaction Ji, Qianqian; Bi, Lei; Zhang, Jintao Energy & Environmental Science, Vol. 13, Issue 5 https://doi.org/10.1039/D0EE00092B	journal	January 2020
Comparison of electrocatalytic activity of Pt _1−x Pd _x /C catalysts for ethanol electro-oxidation in acidic and alkaline media Zhang, Qiang; Chen, Ting; Jiang, Rongyan RSC Advances, Vol. 10, Issue 17 https://doi.org/10.1039/D0RA00483A	journal	January 2020
Lanthanum-based double perovskite nanoscale motifs as support media for the methanol oxidation reaction McGuire, Scott C.; Koenigsmann, Christopher; Chou, Chun Chieh Catalysis Science & Technology, Vol. 12, Issue 2 https://doi.org/10.1039/D1CY01668G	journal	January 2022
CO Tolerance of Pt alloy electrocatalysts for polymer electrolyte fuel cells and the detoxification mechanism Igarashi, Hiroshi; Fujino, Takeshi; Zhu, Yimin Physical Chemistry Chemical Physics, Vol. 3, Issue 3 https://doi.org/10.1039/b007768m	journal	January 2001
Direct evidence for active site-dependent formic acid electro-oxidation by topmost-surface atomic redistribution in a ternary PtPdCu electrocatalyst Cui, Chun-Hua; Li, Hui-Hui; Cong, Huai-Ping Chemical Communications, Vol. 48, Issue 99 https://doi.org/10.1039/c2cc35822k	journal	January 2012
Nanostructured trimetallic Pt/FeRuC, Pt/NiRuC, and Pt/CoRuC catalysts for methanol electrooxidation Poh, Chee Kok; Tian, Zhiqun; Gao, Jiajian Journal of Materials Chemistry, Vol. 22, Issue 27 https://doi.org/10.1039/c2jm31956j	journal	January 2012
Structural and magnetic properties of epitaxial thin films of the ordered double perovskite La2CoMnO6 Guo, H. Z.; Gupta, A.; Calvarese, T. G. Applied Physics Letters, Vol. 89, Issue 26 https://doi.org/10.1063/1.2422878	journal	December 2006
Size-dependent magnetic properties and Raman spectra of La2NiMnO6 nanoparticles Zhao, Shuangyi; Shi, Lei; Zhou, Shiming Journal of Applied Physics, Vol. 106, Issue 12 https://doi.org/10.1063/1.3269707	journal	December 2009
The magnetic origin of multiferroic Y₂CoMnO₆ Jia, Ting; Zeng, Zhi; Li, X. G. Journal of Applied Physics, Vol. 117, Issue 17 https://doi.org/10.1063/1.4915095	journal	May 2015
Static and dynamic magnetic properties and interplay of Dy³⁺, Gd³⁺and Mn³⁺spins in orthorhombic DyMnO₃and GdMnO₃nanoparticles Das, Raja; Jaiswal, Adhish; Poddar, Pankaj Journal of Physics D: Applied Physics, Vol. 46, Issue 4 https://doi.org/10.1088/0022-3727/46/4/045301	journal	December 2012
Multiple magnetic phases of La 2 CoMnO 6 − δ ( 0 <~ δ <~ 0 . 0 5 ) Dass, R. I.; Goodenough, J. B. Physical Review B, Vol. 67, Issue 1 https://doi.org/10.1103/PhysRevB.67.014401	journal	January 2003
A Perovskite Oxide Optimized for Oxygen Evolution Catalysis from Molecular Orbital Principles Suntivich, J.; May, K. J.; Gasteiger, H. A. Science, Vol. 334, Issue 6061 https://doi.org/10.1126/science.1212858	journal	October 2011
Enhancement of the Electroreduction of Oxygen on Pt Alloys with Fe, Ni, and Co Toda, Takako; Igarashi, Hiroshi; Uchida, Hiroyuki Journal of The Electrochemical Society, Vol. 146, Issue 10, p. 3750-3756 https://doi.org/10.1149/1.1392544	journal	January 1999
Microstructural, Magnetic, and Optical Properties of Pr-Doped Perovskite Manganite La0.67Ca0.33MnO3 Nanoparticles Synthesized via Sol-Gel Process Xia, Weiren; Wu, Heng; Xue, Piaojie Nanoscale Research Letters, Vol. 13, Issue 1 https://doi.org/10.1186/s11671-018-2553-y	journal	May 2018

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Related Subjects

30 DIRECT ENERGY CONVERSION
catalysis
double perovskites
electrocatalysis
nanorods
supports

Yttrium-based Double Perovskite Nanorods for Electrocatalysis

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