Lanthanum-based double perovskite nanoscale motifs as support media for the methanol oxidation reaction

McGuire, Scott C.; Koenigsmann, Christopher; Chou, Chun Chieh; Tong, Xiao; Wong, Stanislaus S.

doi:10.1039/d1cy01668g

Lanthanum-based double perovskite nanoscale motifs as support media for the methanol oxidation reaction

Journal Article · Mon Dec 13 00:00:00 EST 2021 · Catalysis Science and Technology

DOI:https://doi.org/10.1039/d1cy01668g· OSTI ID:1855754

McGuire, Scott C. ^[1]; ^[2]; Chou, Chun Chieh ^[1]; ^[3]; ^[1]

State Univ. of New York (SUNY), Stony Brook, NY (United States)
Fordham Univ., Bronx, NY (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)

In this report we have not only analyzed the performance of perovskite oxides as support media for the methanol oxidation reaction (MOR) but also examined the impact and significance of various reaction parameters on their synthesis. Specifically, we have generated (a) La₂NiMnO₆, LaMnO₃, and LaNiO₃ nanocubes with average sizes of ~200 nm, in addition to a series of La₂NiMnO₆ (b) nanocubes possessing average sizes of ~70 and 400 nm and (c) anisotropic nanorods characterized by average diameters of 40-50 nm. All of these samples, when used as supports for Pt nanoparticles, exhibited activities which were at least twice that measured for Pt/C. We have investigated and correlated the effect of varying perovskite (i) composition, (ii) size, and (iii) morphology upon the measured MOR activity. (i) The Ni-containing perovskites yielded generally higher performance metrics than LaMnO₃ alone, suggesting that the presence of Ni is favorable for MOR, a finding supported by a shift in the Pt d-band in XPS. (ii) MOR activity is enhanced as the perovskite size increases in magnitude, suggesting that a growth in the perovskite particle size enables favorable, synergistic metal–support interactions. (iii) A comparison of the nanorods and nanocubes of a similar diameter implied that the one-dimensional morphology achieved a greater activity, a finding which can be attributed not only to the anisotropic structure but also to a desirable surface structure. Overall, these data yield key insights into the tuning of metal–support interactions via rational control over the composition, size, and morphology of the underlying catalyst support.

View Accepted Manuscript (DOE)

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704

OSTI ID:: 1855754

Alternate ID(s):: OSTI ID: 1835343

Report Number(s):: BNL-222868-2022-JAAM

Journal Information:: Catalysis Science and Technology, Journal Name: Catalysis Science and Technology Journal Issue: 2 Vol. 12; ISSN 2044-4753

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (69)

The Excellence of Both Worlds: Developing Effective Double Perovskite Oxide Catalyst of Oxygen Reduction Reaction for Room and Elevated Temperature Applications Hua, Bin; Zhang, Ya-Qian; Yan, Ning Advanced Functional Materials, Vol. 26, Issue 23 https://doi.org/10.1002/adfm.201600339	journal	April 2016
Highly Defective Layered Double Perovskite Oxide for Efficient Energy Storage via Reversible Pseudocapacitive Oxygen-Anion Intercalation Liu, Yu; Wang, Zhenbin; Veder, Jean-Pierre Marcel Advanced Energy Materials, Vol. 8, Issue 11 https://doi.org/10.1002/aenm.201702604	journal	January 2018
Conductivity-Dependent Completion of Oxygen Reduction on Oxide Catalysts Lee, Dong-Gyu; Gwon, Ohhun; Park, Han-Saem Angewandte Chemie International Edition, Vol. 54, Issue 52 https://doi.org/10.1002/anie.201508129	journal	November 2015
Double Perovskite LaFe _x Ni _{1− x} O ₃ Nanorods Enable Efficient Oxygen Evolution Electrocatalysis Wang, Huaping; Wang, Juan; Pi, Yecan Angewandte Chemie International Edition, Vol. 58, Issue 8 https://doi.org/10.1002/anie.201812545	journal	January 2019
Formation of Intermetallic Compounds by Reactive Metal-Support Interaction: A Frequently Encountered Phenomenon in Catalysis Penner, Simon; Armbrüster, Marc ChemCatChem, Vol. 7, Issue 3 https://doi.org/10.1002/cctc.201402635	journal	December 2014
Nanoscale Perovskites as Catalysts and Supports for Direct Methanol Fuel Cells Li, Luyao; Tan, Sha; Salvatore, Kenna L. Chemistry – A European Journal, Vol. 25, Issue 33 https://doi.org/10.1002/chem.201805695	journal	April 2019
Effect of Annealing Temperature on the Structural and the Electrical Transport Properties of La ₂ NiMnO ₆ Nanoparticles Chakraborty, Deblina; Nandi, Upendranath; Dey, Animesh Kumar physica status solidi (b), Vol. 255, Issue 4 https://doi.org/10.1002/pssb.201700436	journal	December 2017
Influence of Cation Order and Valence States on Magnetic Ordering in La ₂ Ni _{1− x} Mn _{1+ x} O ₆ Nasir, Mohd.; Khan, Mahmud; Bhatt, Subhash physica status solidi (b), Vol. 256, Issue 11 https://doi.org/10.1002/pssb.201900019	journal	June 2019
Multifunctional catalysts toward methanol oxidation in direct methanol fuel cell Yavari, Zahra; Noroozifar, Meissam; Khorasani-Motlagh, Mozhgan Journal of Applied Electrochemistry, Vol. 45, Issue 5 https://doi.org/10.1007/s10800-015-0806-3	journal	March 2015
Thermodynamic parameters for the formation of glycine complexes with magnesium(II), calcium(II), lead(II), manganese(II), cobalt(II), nickel(II), zinc(II) and cadmium(II) at different temperatures and ionic strengths, with particular reference to natural fluid conditions Casale, Agatino; De Robertis, Alessandro; De Stefano, Concetta Thermochimica Acta, Vol. 255 https://doi.org/10.1016/0040-6031(94)02181-M	journal	May 1995
Methanol oxidation on LaBO3 (B=Co, Mn, Fe) perovskite-type catalysts prepared by reactive grinding Levasseur, B.; Kaliaguine, S. Applied Catalysis A: General, Vol. 343, Issue 1-2 https://doi.org/10.1016/j.apcata.2008.03.016	journal	July 2008
Photo-assisted methanol oxidation on Pt-TiO2 catalysts for direct methanol fuel cells: A short review Antolini, Ermete Applied Catalysis B: Environmental, Vol. 237 https://doi.org/10.1016/j.apcatb.2018.06.029	journal	December 2018
Plasma-induced synthesis of Pt nanoparticles supported on TiO 2 nanotubes for enhanced methanol electro-oxidation Su, Nan; Hu, Xiulan; Zhang, Jianbo Applied Surface Science, Vol. 399 https://doi.org/10.1016/j.apsusc.2016.12.095	journal	March 2017
Combustion synthesized crystalline La-Mn perovskite catalysts: Role of fuel molecule on thermal and chemical events Hammami, Ramzi; Batis, Habib Arabian Journal of Chemistry, Vol. 13, Issue 1 https://doi.org/10.1016/j.arabjc.2017.07.009	journal	January 2020
Novel orange-emitting Ba2LaNbO6:Eu3+ nanophosphors for NUV-based WLEDs and photocatalytic water purification Pavitra, E.; Raju, G. Seeta Rama; Ghoreishian, Seyed Majid Ceramics International, Vol. 45, Issue 4 https://doi.org/10.1016/j.ceramint.2018.11.171	journal	March 2019
Unique CO-tolerance of Pt–WOx materials Micoud, F.; Maillard, F.; Gourgaud, A. Electrochemistry Communications, Vol. 11, Issue 3 https://doi.org/10.1016/j.elecom.2009.01.007	journal	March 2009
Support effects on the oxidation of methanol at platinum nanoparticles Moghaddam, Reza B.; Pickup, Peter G. Electrochemistry Communications, Vol. 13, Issue 7 https://doi.org/10.1016/j.elecom.2011.04.015	journal	July 2011
Pt nanoparticles supported on submicrometer-sized TiO2 spheres for effective methanol and ethanol oxidation Hua, Hao; Hu, Chenguo; Zhao, Zhenhuan Electrochimica Acta, Vol. 105 https://doi.org/10.1016/j.electacta.2013.05.002	journal	August 2013
Promoting methanol-oxidation-reaction by loading PtNi nano-catalysts on natural graphitic-nano-carbon Teng, Xueai; Shan, Aixian; Zhu, Yuchen Electrochimica Acta, Vol. 353 https://doi.org/10.1016/j.electacta.2020.136542	journal	September 2020
Investigation of epitaxial LaNiO3−x thin films by high-energy XPS Mickevičius, S.; Grebinskij, S.; Bondarenka, V. Journal of Alloys and Compounds, Vol. 423, Issue 1-2 https://doi.org/10.1016/j.jallcom.2005.12.038	journal	October 2006
The effect of high temperature annealing on the antisite defects in ferromagnetic La2NiMnO6 double perovskite Nasir, Mohd; Khan, Mahmud; Kumar, Sunil Journal of Magnetism and Magnetic Materials, Vol. 483 https://doi.org/10.1016/j.jmmm.2019.03.083	journal	August 2019
An electrocatalyst for methanol oxidation based on tungsten trioxide microspheres and platinum Ganesan, Raman; Lee, Jae Sung Journal of Power Sources, Vol. 157, Issue 1 https://doi.org/10.1016/j.jpowsour.2005.07.069	journal	June 2006
Understanding and approaches for the durability issues of Pt-based catalysts for PEM fuel cell Shao, Yuyan; Yin, Geping; Gao, Yunzhi Journal of Power Sources, Vol. 171, Issue 2, p. 558-566 https://doi.org/10.1016/j.jpowsour.2007.07.004	journal	September 2007
Effect of the rare earth in the perovskite-type mixed oxides AMnO3 (A=Y, La, Pr, Sm, Dy) as catalysts in methanol oxidation Levasseur, B.; Kaliaguine, S. Journal of Solid State Chemistry, Vol. 181, Issue 11 https://doi.org/10.1016/j.jssc.2008.07.029	journal	November 2008
Tungsten trioxide nanorods as supports for platinum in methanol oxidation Rajeswari, Janarthanan; Viswanathan, Balasubramanian; Varadarajan, Thirukkallam Kanthadai Materials Chemistry and Physics, Vol. 106, Issue 2-3 https://doi.org/10.1016/j.matchemphys.2007.05.032	journal	December 2007
Double-shelled hollow LaNiO3 nanocage as nanoreactors with remarkable catalytic performance: Illustrating the special morphology and performance relationship Peng, Cheng; Rao, Cheng; Ji, Yongjun Molecular Catalysis, Vol. 455 https://doi.org/10.1016/j.mcat.2018.02.016	journal	August 2018
Advanced nanoelectrocatalyst for methanol oxidation and oxygen reduction reaction, fabricated as one-dimensional pt nanowires on nanostructured robust Ti0.7Ru0.3O2 support Ho, Van Thi Thanh; Nguyen, Nam Giang; Pan, Chun-Jern Nano Energy, Vol. 1, Issue 5 https://doi.org/10.1016/j.nanoen.2012.07.007	journal	September 2012
The roles of oxygen vacancies in electrocatalytic oxygen evolution reaction Zhu, Kaiyue; Shi, Fang; Zhu, Xuefeng Nano Energy, Vol. 73 https://doi.org/10.1016/j.nanoen.2020.104761	journal	July 2020
The influence of post-preparation annealing atmospheres on the optical properties and energy transfer between Pr 3+ and Dy 3+ in mixed lanthanum-yttrium oxyorthosilicate hosts Ogugua, Simon N.; Swart, Hendrik C.; Ntwaeaborwa, Odireleng M. Optical Materials, Vol. 76 https://doi.org/10.1016/j.optmat.2017.12.032	journal	February 2018
Platinum nano-flowers with controlled facet planted in titanium dioxide nanotube arrays bed and their high electro-catalytic activity Li, Hongyi; Liu, Shaojing; Wang, Xinxin Sustainable Materials and Technologies, Vol. 20 https://doi.org/10.1016/j.susmat.2019.e00093	journal	July 2019
Nonstoichiometry Driven Ferromagnetism in Double Perovskite La ₂ Ni _{1– x} Mn _{1+ x} O ₆ Insulating Thin Films Bernal-Salamanca, Monica; Konstantinović, Zorica; Balcells, Lluis Crystal Growth & Design, Vol. 19, Issue 5 https://doi.org/10.1021/acs.cgd.8b01897	journal	March 2019
Generalizable, Electroless, Template-Assisted Synthesis and Electrocatalytic Mechanistic Understanding of Perovskite LaNiO ₃ Nanorods as Viable, Supportless Oxygen Evolution Reaction Catalysts in Alkaline Media McBean, Coray L.; Liu, Haiqing; Scofield, Megan E. ACS Applied Materials & Interfaces, Vol. 9, Issue 29 https://doi.org/10.1021/acsami.7b06855	journal	July 2017
Double Perovskites as Model Bifunctional Catalysts toward Rational Design: The Correlation between Electrocatalytic Activity and Complex Spin Configuration Jiang, Min; Li, Jun; Zhao, Yu ACS Applied Materials & Interfaces, Vol. 10, Issue 23 https://doi.org/10.1021/acsami.8b05353	journal	May 2018
Specific Metal–Support Interactions between Nanoparticle Layers for Catalysts with Enhanced Methanol Oxidation Activity Yoon, Sinmyung; Oh, Kyunghwan; Liu, Fudong ACS Catalysis, Vol. 8, Issue 6 https://doi.org/10.1021/acscatal.8b00276	journal	May 2018
Porous Perovskite-Type Lanthanum Cobaltite as Electrocatalysts toward Oxygen Evolution Reaction Kim, Jaemin; Chen, Xuxia; Shih, Pei-Chieh ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 11 https://doi.org/10.1021/acssuschemeng.7b02815	journal	October 2017
Toward a Reliable Synthesis of Strontium Ruthenate: Parameter Control and Property Investigation of Submicrometer-Sized Structures Tiano, Amanda L.; Santulli, Alexander C.; Koenigsmann, Christopher Chemistry of Materials, Vol. 23, Issue 14 https://doi.org/10.1021/cm1029497	journal	July 2011
Noncarbon Support Materials for Polymer Electrolyte Membrane Fuel Cell Electrocatalysts Wang, Yan-Jie; Wilkinson, David P.; Zhang, Jiujun Chemical Reviews, Vol. 111, Issue 12 https://doi.org/10.1021/cr100060r	journal	December 2011
Chemical Structures and Performance of Perovskite Oxides Pena, M.; Fierro, J. Chemical Reviews, Vol. 101, Issue 7, p. 1981-2018 https://doi.org/10.1021/cr980129f	journal	July 2001
Controlled Generation of Uniform Spherical LaMnO ₃ , LaCoO ₃ , Mn ₂ O ₃ , and Co ₃ O ₄ Nanoparticles and Their High Catalytic Performance for Carbon Monoxide and Toluene Oxidation Liu, Yuxi; Dai, Hongxing; Deng, Jiguang Inorganic Chemistry, Vol. 52, Issue 15 https://doi.org/10.1021/ic400832h	journal	July 2013
Complex SrRuO ₃ −Pt and LaRuO ₃ −Pt Catalysts for Direct Alcohol Fuel Cells Lan, Aidong; Mukasyan, Alexander S. Industrial & Engineering Chemistry Research, Vol. 47, Issue 23 https://doi.org/10.1021/ie8000698	journal	December 2008
Vibronic Superexchange in Double Perovskite Electrocatalyst for Efficient Electrocatalytic Oxygen Evolution Tong, Yun; Wu, Junchi; Chen, Pengzuo Journal of the American Chemical Society, Vol. 140, Issue 36 https://doi.org/10.1021/jacs.8b06108	journal	August 2018
Perovskite-Based Catalysts for Direct Methanol Fuel Cells Lan, Aidong; Mukasyan, Alexander S. The Journal of Physical Chemistry C, Vol. 111, Issue 26 https://doi.org/10.1021/jp067343p	journal	July 2007
Morphology-Controlled Promoting Activity of Nanostructured MnO ₂ for Methanol and Ethanol Electrooxidation on Pt/C Meher, Sumanta Kumar; Rao, G. Ranga The Journal of Physical Chemistry C, Vol. 117, Issue 10 https://doi.org/10.1021/jp3093995	journal	March 2013
Porous Perovskite LaNiO3 Nanocubes as Cathode Catalysts for Li-O2 Batteries with Low Charge Potential Zhang, Jian; Zhao, Yubao; Zhao, Xiao Scientific Reports, Vol. 4, Issue 1 https://doi.org/10.1038/srep06005	journal	August 2014
Correlating the chemical composition and size of various metal oxide substrates with the catalytic activity and stability of as-deposited Pt nanoparticles for the methanol oxidation reaction Scofield, Megan E.; Koenigsmann, Christopher; Bobb-Semple, Dara Catalysis Science & Technology, Vol. 6, Issue 7 https://doi.org/10.1039/C5CY01444A	journal	January 2016
Polyvinylpyrrolidone (PVP) in nanoparticle synthesis Koczkur, Kallum M.; Mourdikoudis, Stefanos; Polavarapu, Lakshminarayana Dalton Transactions, Vol. 44, Issue 41 https://doi.org/10.1039/C5DT02964C	journal	January 2015
Ruthenium and ruthenium oxide nanofiber supports for enhanced activity of platinum electrocatalysts in the methanol oxidation reaction An, Geon-Hyoung; Lee, Eun-Hwan; Ahn, Hyo-Jin Physical Chemistry Chemical Physics, Vol. 18, Issue 22 https://doi.org/10.1039/C6CP01964A	journal	January 2016
Electrochemical supercapacitor based on double perovskite Y ₂ NiMnO ₆ nanowires Alam, Mahebub; Karmakar, Keshab; Pal, Monalisa RSC Advances, Vol. 6, Issue 115 https://doi.org/10.1039/C6RA23318J	journal	January 2016
Pt nanoparticles anchored over Te nanorods as a novel and promising catalyst for methanol oxidation reaction Yang, Xudong; Xue, Jia; Feng, Ligang Chemical Communications, Vol. 55, Issue 75 https://doi.org/10.1039/C9CC06004A	journal	January 2019
Understanding of binding energy calibration in XPS of lanthanum oxide by in situ treatment Li, Jerry Pui Ho; Zhou, Xiaohong; Pang, Yaoqi Physical Chemistry Chemical Physics, Vol. 21, Issue 40 https://doi.org/10.1039/C9CP04187G	journal	January 2019
The hydrogen evolution reaction: from material to interfacial descriptors Dubouis, Nicolas; Grimaud, Alexis Chemical Science, Vol. 10, Issue 40 https://doi.org/10.1039/C9SC03831K	journal	January 2019
Effect of alkali metal hydroxide on formation processes of zinc oxide crystallites from aqueous solutions containing Zn(OH)42? ions Uekawa, Naofumi; Yamashita, Ryo; Jun Wu, Yong Physical Chemistry Chemical Physics, Vol. 6, Issue 2 https://doi.org/10.1039/b310306d	journal	January 2004
Robust non-carbon Ti0.7Ru0.3O2 support with co-catalytic functionality for Pt: enhances catalytic activity and durability for fuel cells Thanh Ho, Van Thi; Pillai, K. Chandrasekara; Chou, Hung-Lung Energy & Environmental Science, Vol. 4, Issue 10 https://doi.org/10.1039/c1ee01522b	journal	January 2011
Direct methanol oxidation at low overpotentials using Pt nanoparticles electrodeposited at ultrathin conductive RuO2 nanoskins Pietron, Jeremy J.; Pomfret, Michael B.; Chervin, Christopher N. Journal of Materials Chemistry, Vol. 22, Issue 11 https://doi.org/10.1039/c2jm15553b	journal	January 2012
Pt nanoparticles residing in the pores of porous LaNiO3 nanocubes as high-efficiency electrocatalyst for direct methanol fuel cells Yu, Nan; Kuai, Long; Wang, Qing Nanoscale, Vol. 4, Issue 17 https://doi.org/10.1039/c2nr31055d	journal	January 2012
Facile molten-salt synthesis of double perovskite La2BMnO6 nanoparticles Mao, Yuanbing RSC Advances, Vol. 2, Issue 33 https://doi.org/10.1039/c2ra21789a	journal	January 2012
Studies on colloidal stability of PVP-coated LSMO nanoparticles for magnetic fluid hyperthermia Jadhav, S. V.; Nikam, D. S.; Khot, V. M. New Journal of Chemistry, Vol. 37, Issue 10 https://doi.org/10.1039/c3nj00554b	journal	January 2013
Magnetic properties of double perovskite La2BMnO6 (B = Ni or Co) nanoparticles Mao, Yuanbing; Parsons, Jason; McCloy, John S. Nanoscale, Vol. 5, Issue 11 https://doi.org/10.1039/c3nr00825h	journal	January 2013
Ni-substituted LaMnO3 perovskites for ethanol oxidation Hou, Yi-Chen; Ding, Ming-Wei; Liu, Shih-Kang RSC Advances, Vol. 4, Issue 11 https://doi.org/10.1039/c3ra46323k	journal	January 2014
Size-dependent magnetic properties and Raman spectra of La2NiMnO6 nanoparticles Zhao, Shuangyi; Shi, Lei; Zhou, Shiming Journal of Applied Physics, Vol. 106, Issue 12 https://doi.org/10.1063/1.3269707	journal	December 2009
Large magnetodielectric effect in nanocrystalline double perovskite Y ₂ FeCrO ₆ Maiti, R. P.; Dutta, S.; Mitra, M. K. Journal of Physics D: Applied Physics, Vol. 46, Issue 41 https://doi.org/10.1088/0022-3727/46/41/415303	journal	September 2013
Determination of B-site ordering and structural transformations in the mixed transition metal perovskites La ₂ CoMnO ₆ and La ₂ NiMnO ₆ Bull, C. L.; Gleeson, D.; Knight, K. S. Journal of Physics: Condensed Matter, Vol. 15, Issue 29 https://doi.org/10.1088/0953-8984/15/29/304	journal	July 2003
Tailoring the Magnetocaloric Effect in La 2 NiMnO 6 Thin Films Matte, D.; de Lafontaine, M.; Ouellet, A. Physical Review Applied, Vol. 9, Issue 5 https://doi.org/10.1103/PhysRevApplied.9.054042	journal	May 2018
X-ray photoelectron final-state screening in La(OH ) 3 : A multiplet structural analysis Mullica, D. F.; Lok, C. K. C.; Perkins, H. O. Physical Review B, Vol. 31, Issue 6 https://doi.org/10.1103/PhysRevB.31.4039	journal	March 1985
Oxygen stoichiometry, ferromagnetism, and transport properties of La 2 − x NiMnO 6 + δ Dass, R. I.; Yan, J. -Q.; Goodenough, J. B. Physical Review B, Vol. 68, Issue 6 https://doi.org/10.1103/PhysRevB.68.064415	journal	August 2003
Effect of anti-site disorder on magnetism in La 2 NiMnO 6 Pal, Somnath; Goyal, Manik Physical Review B, Vol. 97, Issue 16 https://doi.org/10.1103/PhysRevB.97.165137	journal	April 2018
Nonprecious Metal Perovskite Electrocatalysts for Direct Methanol Fuel Cells Zhou, Xiangyang; Hu, Baili; Chen, Zhen Electrochemical and Solid-State Letters, Vol. 8, Issue 11 https://doi.org/10.1149/1.2073627	journal	January 2005
The Formation of Perovskite during the Combustion of an Energy-Rich Glycine–Nitrate Precursor Komova, Oksana; Mukha, Svetlana; Ozerova, Anna Materials, Vol. 13, Issue 22 https://doi.org/10.3390/ma13225091	journal	November 2020
Boosting the Peroxidase-Like Activity of Nanostructured Nickel by Inducing Its 3+ Oxidation State in LaNiO ₃ Perovskite and Its Application for Biomedical Assays Wang, Xiaoyu; Cao, Wen; Qin, Li Theranostics, Vol. 7, Issue 8 https://doi.org/10.7150/thno.19257	journal	January 2017

Similar Records

Surfactant-Free Synthesis of Three-Dimensional Perovskite Titania-Based Micron-Scale Motifs Used as Catalytic Supports for the Methanol Oxidation Reaction

Journal Article · Mon Feb 08 19:00:00 EST 2021 · Molecules · OSTI ID:1817042

Yttrium-based Double Perovskite Nanorods for Electrocatalysis

Journal Article · Sun Jun 26 20:00:00 EDT 2022 · ACS Applied Materials and Interfaces · OSTI ID:1898630

ZnO/perovskite core–shell nanorod array based monolithic catalysts with enhanced propane oxidation and material utilization efficiency at low temperature

Journal Article · Thu Apr 23 20:00:00 EDT 2015 · Catalysis Today · OSTI ID:1430252

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Lanthanum-based double perovskite nanoscale motifs as support media for the methanol oxidation reaction

Citation Formats

References (69)

Similar Records

Related Subjects