Vanadium metal-organic framework for selective adsorption

Long, Jeffrey R.; Jaramillo, David E.; Reed, Douglas A.

Title: Vanadium metal-organic framework for selective adsorption

Patent · Tue Apr 26 00:00:00 EDT 2022

OSTI ID:1892862

Long, Jeffrey R.; Jaramillo, David E.; Reed, Douglas A.

A permanently porous vanadium(II)-containing metal-organic framework (MOF) with vanadium(II) centers and methods for synthesis of such MOF frameworks are provided. Methods for using such compounds to selectively react with N2 over CH4 are provided. In the synthetic methods, a vanadium source, such as VY2(tmeda)2, where Y is a halogen and tmeda is N,N,N′,N′-tetramethylethane-1,2-diamine and a H2(ligand) are reacted in the presence of acid in a solvent at between 110° C. and 130° C. to form an intermediate product. The intermediate product is collected and washed with a washing agent, such as DMF and acetonitrile, and the vanadium(II) based MOF is activated by heating the washed intermediate product to at least 160° C. under dynamic vacuum.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC02-05CH11231; AC02-06CH11357; SC0001015; SC0016961

Assignee:: The Regents of the University of California (Oakland, CA)

Patent Number(s):: 11,311,856

Application Number:: 16/767,488

OSTI ID:: 1892862

Resource Relation:: Patent File Date: 11/29/2018

Country of Publication:: United States

Language:: English

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