Selective Gas Adsorption within a Five-Connected Porous Metal-Organic Framework

Journal Article · Fri Jan 01 04:00:00 EST 2010 · Journal of Materials Chemistry

DOI:https://doi.org/10.1039/b927486c· OSTI ID:980704

Xue, Ming ^[1]; Zhang, Zhangjing ^[2]; Xiang, Shengchang ^[2]; Zhao, Jin ^[1]; Liang, Chengdu ^[3]; Guang-Shan, Zhu ^[1]; Qiu, Shi-Lun ^[1]; Chen, Banglin ^[3]

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1. Jilin University, Changchun
2. University of Texas, Pan American, Edinburg, TX
3. ORNL

A metal-organic framework, Zn3(OH)( BDC-2,5-Cl2)2.5(DMF)3(H2O) 1 (BDC-2,5-Cl2 = 1,4-benzenedicarboxylate-2,5-dichloro and DMF = N,N -dimethylformamide) of rare five-connected (44)(66) topology was synthesized and structurally characterized. The framework is thermally stable up to 350 C, thus activation of this new MOF material at different temperature of 150 and 300 C under high vacuum formed two microporous materials 1a and 1b, respectively, exhibiting selective gas adsorption behavior with respect to H2/N2 and O2/N2, and CO2/CH4 and CO2/N2.

• Research Organization: Oak Ridge National Laboratory (ORNL); Center for Nanophase Materials Sciences
• Sponsoring Organization: SC USDOE - Office of Science (SC)
• DOE Contract Number: AC05-00OR22725
• OSTI ID: 980704
• Journal Information: Journal of Materials Chemistry, Journal Name: Journal of Materials Chemistry Journal Issue: 19 Vol. 20; ISSN JMACEP; ISSN 0959-9428
• Country of Publication: United States
• Language: English

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36 MATERIALS SCIENCE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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