New insights on carbon black suspension rheology—Anisotropic thixotropy and antithixotropy

Wang, Yilin; Ewoldt, Randy H.

doi:10.1122/8.0000455

New insights on carbon black suspension rheology—Anisotropic thixotropy and antithixotropy

Journal Article · Fri Aug 19 00:00:00 EDT 2022 · Journal of Rheology

DOI:https://doi.org/10.1122/8.0000455· OSTI ID:1882746

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We report a detailed experimental study of peculiar thixotropic dynamics of carbon black (CB, Vulcan XC-72) suspensions in mineral oil, specifically the observation of sequential stress increase then decrease at a fixed shear rate in a step-down test. We verify that such dynamics, though peculiar, come from a true material response rather than experimental artifacts. We also reveal how this long-time stress decay is associated with antithixotropic structural change rather than viscoelastic stress relaxation by using orthogonal superposition (OSP) rheometry to probe viscoelastic moduli during the step-down tests. The orthogonal storage and loss moduli are present, showing this two-timescale recovery then decay response, which demonstrates that this response is antithixotropic, and it involves shear-induced structuring. We further show a mechanical anisotropy in the CB suspension under shear using OSP. Based on the rheological results, a microstructural schematic is proposed, considering qualitatively thixotropic structure build-up, antithixotropic densification, and anisotropic structure evolution. Our observation for these CB suspensions is outside the standard paradigm of thixotropic structure-parameter models, and the elastic response provides us with new insight into the transient dynamics of CB suspensions.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

OSTI ID:: 1882746

Alternate ID(s):: OSTI ID: 1982941

Journal Information:: Journal of Rheology, Journal Name: Journal of Rheology Journal Issue: 5 Vol. 66; ISSN 0148-6055

Publisher:: Society of RheologyCopyright Statement

Country of Publication:: United States

Language:: English

References (82)

Semi-Solid Lithium Rechargeable Flow Battery Duduta, Mihai; Ho, Bryan; Wood, Vanessa C. Advanced Energy Materials, Vol. 1, Issue 4, p. 511-516 https://doi.org/10.1002/aenm.201100152	journal	May 2011
Biphasic Electrode Suspensions for Li-Ion Semi-solid Flow Cells with High Energy Density, Fast Charge Transport, and Low-Dissipation Flow Wei, Teng-Sing; Fan, Frank Y.; Helal, Ahmed Advanced Energy Materials, Vol. 5, Issue 15 https://doi.org/10.1002/aenm.201500535	journal	June 2015
Influence of the Carbon Black Dispersing Process on the Microstructure and Performance of Li‐Ion Battery Cathodes Mayer, Julian Kristoffer; Almar, Laura; Asylbekov, Ermek Energy Technology, Vol. 8, Issue 2 https://doi.org/10.1002/ente.201900161	journal	June 2019
Experimental Challenges of Shear Rheology: How to Avoid Bad Data Ewoldt, Randy H.; Johnston, Michael T.; Caretta, Lucas M. Complex Fluids in Biological Systems https://doi.org/10.1007/978-1-4939-2065-5_6	book	October 2014
Time-resolved rheometry Mours, M.; Winter, H. H. Rheologica Acta, Vol. 33, Issue 5 https://doi.org/10.1007/BF00366581	journal	January 1994
Flow-induced structure in a system of nuclear waste simulant slurries Chang, Chingyi; Smith, Peter A. Rheologica Acta, Vol. 35, Issue 4 https://doi.org/10.1007/BF00403539	journal	July 1996
Rheological behaviour of pigment dispersions as related to roller passage Hellinckx, L.; Mewis, J. Rheologica Acta, Vol. 8, Issue 4 https://doi.org/10.1007/BF01976238	journal	October 1969
A model system for thixotropy studies Dullaert, Konraad; Mewis, Jan Rheologica Acta, Vol. 45, Issue 1 https://doi.org/10.1007/s00397-005-0439-2	journal	July 2005
High shear rate viscometry Pipe, Christopher J.; Majmudar, Trushant S.; McKinley, Gareth H. Rheologica Acta, Vol. 47, Issue 5-6 https://doi.org/10.1007/s00397-008-0268-1	journal	April 2008
New insights on fumed colloidal rheology—shear thickening and vorticity-aligned structures in flocculating dispersions Negi, Ajay Singh; Osuji, Chinedum O. Rheologica Acta, Vol. 48, Issue 8 https://doi.org/10.1007/s00397-008-0341-9	journal	December 2008
Determining the true slip of a yield stress material with a sliding plate rheometer Clasen, Christian Rheologica Acta, Vol. 51, Issue 10 https://doi.org/10.1007/s00397-012-0647-5	journal	August 2012
Superposition rheometry of a wormlike micellar fluid Kim, Sunhyung; Mewis, Jan; Clasen, Christian Rheologica Acta, Vol. 52, Issue 8-9 https://doi.org/10.1007/s00397-013-0718-2	journal	June 2013
Mapping thixo-elasto-visco-plastic behavior Ewoldt, Randy H.; McKinley, Gareth H. Rheologica Acta, Vol. 56, Issue 3 https://doi.org/10.1007/s00397-017-1001-8	journal	March 2017
Thixotropy—a review Barnes, Howard A. Journal of Non-Newtonian Fluid Mechanics, Vol. 70, Issue 1-2 https://doi.org/10.1016/S0377-0257(97)00004-9	journal	May 1997
Orthogonal versus parallel superposition measurements Vermant, J.; Walker, L.; Moldenaers, P. Journal of Non-Newtonian Fluid Mechanics, Vol. 79, Issue 2-3 https://doi.org/10.1016/S0377-0257(98)00105-0	journal	November 1998
Kinetics of clustering of carbon black suspensions by light scattering techniques Bezot, P.; Hesse-Bezot, C. Physica A: Statistical Mechanics and its Applications, Vol. 271, Issue 1-2 https://doi.org/10.1016/S0378-4371(99)00219-8	journal	September 1999
Flowing suspensions of carbon black with high electronic conductivity for flow applications: Comparison between carbons black and exhibition of specific aggregation of carbon particles Parant, H.; Muller, G.; Le Mercier, T. Carbon, Vol. 119 https://doi.org/10.1016/j.carbon.2017.04.014	journal	August 2017
Thixotropy Mewis, Jan; Wagner, Norman J. Advances in Colloid and Interface Science, Vol. 147-148 https://doi.org/10.1016/j.cis.2008.09.005	journal	March 2009
Stress jumps on weakly flocculated dispersions: Steady state and transient results Dullaert, K.; Mewis, J. Journal of Colloid and Interface Science, Vol. 287, Issue 2 https://doi.org/10.1016/j.jcis.2005.02.018	journal	July 2005
A structural kinetics model for thixotropy Dullaert, Konraad; Mewis, Jan Journal of Non-Newtonian Fluid Mechanics, Vol. 139, Issue 1-2 https://doi.org/10.1016/j.jnnfm.2006.06.002	journal	November 2006
Signatures of Overaging in an Aqueous Dispersion of Carbopol Agarwal, Mayank; Kaushal, Manish; Joshi, Yogesh M. Langmuir, Vol. 36, Issue 48 https://doi.org/10.1021/acs.langmuir.0c02887	journal	November 2020
Mechanical History Dependence in Carbon Black Suspensions for Flow Batteries: A Rheo-Impedance Study Narayanan, Aditya; Mugele, Frieder; Duits, Michael H. G. Langmuir, Vol. 33, Issue 7 https://doi.org/10.1021/acs.langmuir.6b04322	journal	February 2017
Clustering and Percolation in Suspensions of Carbon Black Richards, Jeffrey J.; Hipp, Julie B.; Riley, John K. Langmuir, Vol. 33, Issue 43 https://doi.org/10.1021/acs.langmuir.7b02538	journal	August 2017
Rheological Investigation on the Microstructure of Fuel Cell Catalyst Inks Khandavalli, Sunilkumar; Park, Jae Hyung; Kariuki, Nancy N. ACS Applied Materials & Interfaces, Vol. 10, Issue 50 https://doi.org/10.1021/acsami.8b15039	journal	December 2018
Shear-Induced Microstructural Evolution of a Thermoreversible Colloidal Gel Varadan, Priya; Solomon, Michael J. Langmuir, Vol. 17, Issue 10 https://doi.org/10.1021/la001504d	journal	May 2001
Flow-Induced Anisotropy and Reversible Aggregation in Two-Dimensional Suspensions Hoekstra, H.; Vermant, J.; Mewis, J. Langmuir, Vol. 19, Issue 22 https://doi.org/10.1021/la034582k	journal	September 2003
Numerical and Experimental Study of Suspensions Containing Carbon Blacks Used as Conductive Additives in Composite Electrodes for Lithium Batteries Cerbelaud, Manuella; Lestriez, Bernard; Ferrando, Riccardo Langmuir, Vol. 30, Issue 10 https://doi.org/10.1021/la404693s	journal	March 2014
Determining Relaxation Modes in Flowing Associative Polymers Using Superposition Flows Mewis, J.; Kaffashi, B.; Vermant, J. Macromolecules, Vol. 34, Issue 5 https://doi.org/10.1021/ma000987p	journal	January 2001
Stoichiometry effects on rheology of model polyurethanes at the gel point Winter, H. Henning; Morganelli, Paul; Chambon, Francois Macromolecules, Vol. 21, Issue 2 https://doi.org/10.1021/ma00180a048	journal	February 1988
Polysulfide Flow Batteries Enabled by Percolating Nanoscale Conductor Networks Fan, Frank Y.; Woodford, William H.; Li, Zheng Nano Letters, Vol. 14, Issue 4, p. 2210-2218 https://doi.org/10.1021/nl500740t	journal	March 2014
Jamming phase diagram for attractive particles Trappe, V.; Prasad, V.; Cipelletti, Luca Nature, Vol. 411, Issue 6839 https://doi.org/10.1038/35081021	journal	June 2001
Understanding rheological hysteresis in soft glassy materials Radhakrishnan, Rangarajan; Divoux, Thibaut; Manneville, Sébastien Soft Matter, Vol. 13, Issue 9 https://doi.org/10.1039/C6SM02581A	journal	January 2017
Design of yield-stress fluids: a rheology-to-structure inverse problem Nelson, Arif Z.; Ewoldt, Randy H. Soft Matter, Vol. 13, Issue 41 https://doi.org/10.1039/C7SM00758B	journal	January 2017
Orthogonal superposition rheometry of colloidal gels: time-shear rate superposition Sung, Sang Hoon; Kim, Sunhyung; Hendricks, Jan Soft Matter, Vol. 14, Issue 42 https://doi.org/10.1039/C8SM01512K	journal	January 2018
Percolation behaviors of model carbon black pastes Jiang, Jung-Shiun; Guo, Rong-Hao; Chiu, Yu-Shuen Soft Matter, Vol. 14, Issue 48 https://doi.org/10.1039/C8SM01591K	journal	January 2018
Mechanical spectroscopy of colloidal dispersions Mewis, Jan; Schoukens, Gustaaf Faraday Discussions of the Chemical Society, Vol. 65 https://doi.org/10.1039/DC9786500058	journal	January 1978
Highly anisotropic vorticity aligned structures in a shear thickening attractive colloidal system Osuji, Chinedum O.; Weitz, David A. Soft Matter, Vol. 4, Issue 7 https://doi.org/10.1039/b716324j	journal	January 2008
Shear-induced structuration of confined carbon black gels: steady-state features of vorticity-aligned flocs Grenard, Vincent; Taberlet, Nicolas; Manneville, Sébastien Soft Matter, Vol. 7, Issue 8 https://doi.org/10.1039/c0sm01515f	journal	January 2011
Yielding dynamics of a Herschel–Bulkley fluid: a critical-like fluidization behaviour Divoux, Thibaut; Tamarii, David; Barentin, Catherine Soft Matter, Vol. 8, Issue 15 https://doi.org/10.1039/c2sm06918k	journal	January 2012
Non-aqueous carbon black suspensions for lithium-based redox flow batteries: rheology and simultaneous rheo-electrical behavior Youssry, Mohamed; Madec, Lénaïc; Soudan, Patrick Physical Chemistry Chemical Physics, Vol. 15, Issue 34 https://doi.org/10.1039/c3cp51371h	journal	January 2013
Rheopexy and tunable yield stress of carbon black suspensions Ovarlez, Guillaume; Tocquer, Laurent; Bertrand, François Soft Matter, Vol. 9, Issue 23 https://doi.org/10.1039/c3sm27650c	journal	January 2013
Timescales in creep and yielding of attractive gels Grenard, Vincent; Divoux, Thibaut; Taberlet, Nicolas Soft Matter, Vol. 10, Issue 10 https://doi.org/10.1039/c3sm52548a	journal	January 2014
Startup steady shear flow from the Oldroyd 8-constant framework Saengow, C.; Giacomin, A. J.; Grizzuti, Nino Physics of Fluids, Vol. 31, Issue 6 https://doi.org/10.1063/1.5091493	journal	June 2019
Tunable shear thickening in suspensions Lin, Neil Y. C.; Ness, Christopher; Cates, Michael E. Proceedings of the National Academy of Sciences, Vol. 113, Issue 39 https://doi.org/10.1073/pnas.1608348113	journal	September 2016
Hydrodynamics control shear-induced pattern formation in attractive suspensions Varga, Zsigmond; Grenard, Vincent; Pecorario, Stefano Proceedings of the National Academy of Sciences, Vol. 116, Issue 25 https://doi.org/10.1073/pnas.1901370116	journal	June 2019
Flow-induced structure in colloidal suspensions Vermant, J.; Solomon, M. J. Journal of Physics: Condensed Matter, Vol. 17, Issue 4 https://doi.org/10.1088/0953-8984/17/4/R02	journal	January 2005
Simultaneous Rheoelectric Measurements of Strongly Conductive Complex Fluids Helal, Ahmed; Divoux, Thibaut; McKinley, Gareth H. Physical Review Applied, Vol. 6, Issue 6 https://doi.org/10.1103/PhysRevApplied.6.064004	journal	December 2016
Shear thickening and scaling of the elastic modulus in a fractal colloidal system with attractive interactions Osuji, Chinedum O.; Kim, Chanjoong; Weitz, David A. Physical Review E, Vol. 77, Issue 6 https://doi.org/10.1103/PhysRevE.77.060402	journal	June 2008
Thixotropy in viscoplastic drop impact on thin films Sen, Samya; Morales, Anthony G.; Ewoldt, Randy H. Physical Review Fluids, Vol. 6, Issue 4 https://doi.org/10.1103/PhysRevFluids.6.043301	journal	April 2021
Transient Shear Banding in a Simple Yield Stress Fluid Divoux, Thibaut; Tamarii, David; Barentin, Catherine Physical Review Letters, Vol. 104, Issue 20 https://doi.org/10.1103/PhysRevLett.104.208301	journal	May 2010
Rheological Hysteresis in Soft Glassy Materials Divoux, Thibaut; Grenard, Vincent; Manneville, Sébastien Physical Review Letters, Vol. 110, Issue 1 https://doi.org/10.1103/PhysRevLett.110.018304	journal	January 2013
Convective Cage Release in Model Colloidal Glasses Jacob, Alan R.; Poulos, Andreas S.; Kim, Sunhyung Physical Review Letters, Vol. 115, Issue 21 https://doi.org/10.1103/PhysRevLett.115.218301	journal	November 2015
Nonmonotonic Stress Relaxation after Cessation of Steady Shear Flow in Supramolecular Assemblies Hendricks, Jan; Louhichi, Ameur; Metri, Vishal Physical Review Letters, Vol. 123, Issue 21 https://doi.org/10.1103/PhysRevLett.123.218003	journal	November 2019
Multiscale Nature of Thixotropy and Rheological Hysteresis in Attractive Colloidal Suspensions under Shear Jamali, Safa; Armstrong, Robert C.; McKinley, Gareth H. Physical Review Letters, Vol. 123, Issue 24 https://doi.org/10.1103/PhysRevLett.123.248003	journal	December 2019
Scaling of the Viscoelasticity of Weakly Attractive Particles Trappe, V.; Weitz, D. A. Physical Review Letters, Vol. 85, Issue 2 https://doi.org/10.1103/PhysRevLett.85.449	journal	July 2000
Rejuvenation and Overaging in a Colloidal Glass under Shear Viasnoff, Virgile; Lequeux, François Physical Review Letters, Vol. 89, Issue 6 https://doi.org/10.1103/PhysRevLett.89.065701	journal	July 2002
Residual stresses and shear-induced overaging in boehmite gels Sudreau, Iana; Auxois, Mathilde; Servel, Marion Physical Review Materials, Vol. 6, Issue 4 https://doi.org/10.1103/PhysRevMaterials.6.L042601	journal	April 2022
Viscosity bifurcation in thixotropic, yielding fluids Coussot, P.; Nguyen, Q. D.; Huynh, H. T. Journal of Rheology, Vol. 46, Issue 3 https://doi.org/10.1122/1.1459447	journal	May 2002
Thixotropy: Build-up and breakdown curves during flow Dullaert, Konraad; Mewis, Jan Journal of Rheology, Vol. 49, Issue 6 https://doi.org/10.1122/1.2039868	journal	November 2005
Exploring stress overshoot phenomenon upon startup deformation of entangled linear polymeric liquids Wang, Yangyang; Wang, Shi-Qing Journal of Rheology, Vol. 53, Issue 6 https://doi.org/10.1122/1.3208063	journal	November 2009
Letter to the Editor: Wall slip in dispersion rheometry Buscall, Richard Journal of Rheology, Vol. 54, Issue 6 https://doi.org/10.1122/1.3495981	journal	November 2010
The rheology of multiwalled carbon nanotube and carbon black suspensions Yearsley, Kathryn M.; Mackley, Malcolm R.; Chinesta, Francisco Journal of Rheology, Vol. 56, Issue 6 https://doi.org/10.1122/1.4751871	journal	November 2012
Time dependence in large amplitude oscillatory shear: A rheo-ultrasonic study of fatigue dynamics in a colloidal gel Perge, Christophe; Taberlet, Nicolas; Gibaud, Thomas Journal of Rheology, Vol. 58, Issue 5 https://doi.org/10.1122/1.4887081	journal	September 2014
Constitutive equations for thixotropic fluids Larson, R. G. Journal of Rheology, Vol. 59, Issue 3 https://doi.org/10.1122/1.4913584	journal	May 2015
On the inseparability of slip and gap-error Vleminckx, Giovanni; Clasen, Christian Journal of Rheology, Vol. 60, Issue 4 https://doi.org/10.1122/1.4948368	journal	July 2016
Shear-banding in wormlike micelles: Beware of elastic instabilities Fardin, Marc-Antoine; Casanellas, Laura; Saint-Michel, Brice Journal of Rheology, Vol. 60, Issue 5 https://doi.org/10.1122/1.4960333	journal	September 2016
Superposition rheology and anisotropy in rheological properties of sheared colloidal gels Colombo, Gabriele; Kim, Sunhyung; Schweizer, Thomas Journal of Rheology, Vol. 61, Issue 5 https://doi.org/10.1122/1.4998176	journal	September 2017
Modeling the rheology of thixotropic elasto-visco-plastic materials Varchanis, S.; Makrigiorgos, G.; Moschopoulos, P. Journal of Rheology, Vol. 63, Issue 4 https://doi.org/10.1122/1.5049136	journal	July 2019
A review of thixotropy and its rheological modeling Larson, Ronald G.; Wei, Yufei Journal of Rheology, Vol. 63, Issue 3 https://doi.org/10.1122/1.5055031	journal	May 2019
Structure-property relationships of sheared carbon black suspensions determined by simultaneous rheological and neutron scattering measurements Hipp, Julie B.; Richards, Jeffrey J.; Wagner, Norman J. Journal of Rheology, Vol. 63, Issue 3 https://doi.org/10.1122/1.5071470	journal	May 2019
Testing shear thinning/thixotropy and shear thickening/antithixotropy relationships in a fumed silica suspension Rubio-Hernández, F. J.; Sánchez-Toro, J. H.; Páez-Flor, N. M. Journal of Rheology, Vol. 64, Issue 4 https://doi.org/10.1122/1.5131852	journal	July 2020
Viscoelastic Hysteresis. Part II. Numerical and Experimental Examples Marsh, B. Duane Transactions of the Society of Rheology, Vol. 12, Issue 4 https://doi.org/10.1122/1.549093	journal	December 1968
Viscoelastic Hysteresis. Part I. Model Predictions Bird, R. Byron; Marsh, B. Duane Transactions of the Society of Rheology, Vol. 12, Issue 4 https://doi.org/10.1122/1.549096	journal	December 1968
The Response of Viscoelastic Liquids to Complex Strain Histories: The Thixotropic Loop Greener, J.; Connelly, R. W. Journal of Rheology, Vol. 30, Issue 2 https://doi.org/10.1122/1.549849	journal	April 1986
Testing the structure of magnetic paints with and without superimposed shear Potanin, Andrei A.; Shrauti, Suresh M.; Arnold, David W. Journal of Rheology, Vol. 41, Issue 6 https://doi.org/10.1122/1.550867	journal	November 1997
Yielding, thixotropy, and strain stiffening of aqueous carbon black suspensions N’gouamba, E.; Goyon, J.; Tocquer, L. Journal of Rheology, Vol. 64, Issue 4 https://doi.org/10.1122/8.0000028	journal	July 2020
Direct measurements of the microstructural origin of shear-thinning in carbon black suspensions Hipp, Julie B.; Richards, Jeffrey J.; Wagner, Norman J. Journal of Rheology, Vol. 65, Issue 2 https://doi.org/10.1122/8.0000089	journal	March 2021
Distinguishing thixotropy from viscoelasticity Agarwal, Mayank; Sharma, Shweta; Shankar, V. Journal of Rheology, Vol. 65, Issue 4 https://doi.org/10.1122/8.0000262	journal	July 2021
Modeling orthogonal superposition rheometry to probe nonequilibrium dynamics of entangled polymers Zhang, Jiamin; Jurzyk, Andres; Helgeson, Matthew E. Journal of Rheology, Vol. 65, Issue 5 https://doi.org/10.1122/8.0000272	journal	September 2021
Thixotropic spectra and Ashby-style charts for thixotropy Sen, Samya; Ewoldt, Randy H. Journal of Rheology, Vol. 66, Issue 5 https://doi.org/10.1122/8.0000446	journal	August 2022
Shear Banding of Complex Fluids Divoux, Thibaut; Fardin, Marc A.; Manneville, Sebastien Annual Review of Fluid Mechanics, Vol. 48, Issue 1 https://doi.org/10.1146/annurev-fluid-122414-034416	journal	January 2016
Assessment of Percolation Threshold Simulation for Individual and Hybrid Nanocomposites of Carbon Nanotubes and Carbon Black Coelho, Paulo Henrique da Silva Leite; Armellini, Victor Antonio de Deus; Morales, Ana Rita Materials Research, Vol. 20, Issue 6 https://doi.org/10.1590/1980-5373-MR-2016-1084	journal	September 2017

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