Revisiting spontaneous Raman scattering for direct oxygen atom quantification

van de Steeg, A. W.; Vialetto, L.; Silva, A. F.; Peeters, F. J.; van den Bekerom, D. C. M.; Gatti, N.; Diomede, P.; van de Sanden, M. M.; van Rooij, G. J.

doi:10.1364/ol.424102

Title: Revisiting spontaneous Raman scattering for direct oxygen atom quantification

Journal Article · Wed Apr 28 00:00:00 EDT 2021 · Optics Letters

DOI:https://doi.org/10.1364/ol.424102· OSTI ID:1877143

^[1]; Vialetto, L. ^[1]; Silva, A. F. ^[1]; Peeters, F. J. ^[1];

^[2]; Gatti, N. ^[3]; Diomede, P. ^[4]; van de Sanden, M. M. ^[1]; van Rooij, G. J. ^[5]

DIFFER, Eindhoven (The Netherlands)
Sandia National Lab. (SNL-CA), Livermore, CA (United States)
DIFFER, Eindhoven (The Netherlands); Univ. degli Studi di Trento (Italy)
Maastricht University (The Netherlands)
DIFFER, Eindhoven (The Netherlands); Maastricht University (The Netherlands)

In this paper, the counterintuitive and largely unknown Raman activity of oxygen atoms is evaluated for its capacity to determine absolute densities in gases with significant O-density. The study involves C O 2 microwave plasma to generate a self-calibrating mixture and establish accurate cross sections for the 3 P 2 ↔ 3 P 1 and 3 P 2 ↔ 3 P 0 transitions. The approach requires conservation of stoichiometry, confirmed within experimental uncertainty by a 1D fluid model. The measurements yield σ J = 2 → 1 = 5.27 ± s y s : 0.53 r a n d : 0.17 × 10 - 31 c m 2 / s r and σ J = 2 → 0 = 2.11 ± s y s : 0.21 r a n d : 0.06 × 10 - 31 c m 2 / s r , and the detection limit is estimated to be 1 × 10 15 c m - 3 for systems without other scattering species.

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Research Organization:: Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Sandia National Lab. (SNL-CA), Livermore, CA (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: NA0003525

OSTI ID:: 1877143

Report Number(s):: SAND2022-8518J; 707667; TRN: US2307375

Journal Information:: Optics Letters, Vol. 46, Issue 9; ISSN 0146-9592

Publisher:: Optical Society of America (OSA)Copyright Statement

Country of Publication:: United States

Language:: English

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