Three-dimensional bicontinuous ultrafast-charge and -discharge bulk battery electrodes

Zhang, Huigang; Yu, Xindi; Braun, Paul V.

doi:10.1038/nnano.2011.38

Three-dimensional bicontinuous ultrafast-charge and -discharge bulk battery electrodes

Journal Article · Sun Mar 20 00:00:00 EDT 2011 · Nature Nanotechnology

DOI:https://doi.org/10.1038/nnano.2011.38· OSTI ID:1876445

Zhang, Huigang ^[1]; Yu, Xindi ^[2]; Braun, Paul V. ^[2]

Univ. of Illinois at Urbana-Champaign, IL (United States); University of Illinois
Univ. of Illinois at Urbana-Champaign, IL (United States)

Rapid charge and discharge rates have become an important feature of electrical energy storage devices, but cause dramatic reductions in the energy that can be stored or delivered by most rechargeable batteries (their energy capacity). Supercapacitors do not suffer from this problem, but are restricted to much lower stored energy per mass (energy density) than batteries. A storage technology that combines the rate performance of supercapacitors with the energy density of batteries would significantly advance portable and distributed power technology. Furthermore, we demonstrate very large battery charge and discharge rates with minimal capacity loss by using cathodes made from a self-assembled three-dimensional bicontinuous nanoarchitecture consisting of an electrolytically active material sandwiched between rapid ion and electron transport pathways. Rates of up to 400C and 1,000C for lithium-ion and nickel-metal hydride chemistries, respectively, are achieved (where a 1C rate represents a one-hour complete charge or discharge), enabling fabrication of a lithium-ion battery that can be 90% charged in 2 minutes.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Illinois at Urbana-Champaign, IL (United States)

Sponsoring Organization:: US Army Research Laboratory; US Army Research Office; USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division

Grant/Contract Number:: FG02-07ER46471

OSTI ID:: 1876445

Journal Information:: Nature Nanotechnology, Journal Name: Nature Nanotechnology Journal Issue: 5 Vol. 6; ISSN 1748-3387

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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