Janus and Multiblock Colloidal Particles

Chen, Qian; Yan, Jing; Zhang, Jie; Bae, Sung Chul; Granick, Steve

doi:10.1021/la302226w

Janus and Multiblock Colloidal Particles

Journal Article · Fri Jul 06 00:00:00 EDT 2012 · Langmuir

DOI:https://doi.org/10.1021/la302226w· OSTI ID:1875524

Chen, Qian ^[1]; Yan, Jing ^[2]; Zhang, Jie ^[3]; Bae, Sung Chul ^[2]; Granick, Steve ^[2]

Univ. of Illinois Urbana, IL (United States); University of Illinois
Univ. of Illinois Urbana, IL (United States)
UUniv. of Illinois Urbana, IL (United States)

In this article, we review recent developments in the synthesis and self-assembly of Janus and multiblock colloidal particles, highlighting new opportunities for colloid science and technology that are enabled by encoding orientational order between particles as they self-assemble. Emphasizing the concepts of molecular colloids and colloid valence unique to such colloids, we describe their rational self-assembly into colloidal clusters, taking monodisperse tetrahedra as an example. We also introduce a simple method to lock clusters into permanent shapes. Extending this to 2D lattices, we also review recent progress in assembling new open colloidal networks including the kagome lattice. In each application, areas of opportunity are emphasized.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Illinois Urbana, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division

Grant/Contract Number:: FG02-07ER46471

OSTI ID:: 1875524

Journal Information:: Langmuir, Journal Name: Langmuir Journal Issue: 38 Vol. 28; ISSN 0743-7463

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (53)

Mesocrystals and Nonclassical Crystallization Clfen, Helmut; Antonietti, Markus John Wiley & Sons, Ltd https://doi.org/10.1002/9780470994603	book	January 2008
Synthesis of Monodisperse Bicolored Janus Particles with Electrical Anisotropy Using a Microfluidic Co-Flow System Nisisako, T.; Torii, T.; Takahashi, T. Advanced Materials, Vol. 18, Issue 9 https://doi.org/10.1002/adma.200502431	journal	May 2006
Janus Particle Synthesis and Assembly Jiang, Shan; Chen, Qian; Tripathy, Mukta Advanced Materials, Vol. 22, Issue 10 https://doi.org/10.1002/adma.200904094	journal	January 2010
Phase-Selective Catalysis in Emulsions Stabilized by Janus Silica-Nanoparticles Faria, Jimmy; Ruiz, M. Pilar; Resasco, Daniel E. Advanced Synthesis & Catalysis, Vol. 352, Issue 14-15 https://doi.org/10.1002/adsc.201000479	journal	October 2010
Soft Matter (Nobel Lecture) de Gennes, Pierre-Gilles Angewandte Chemie International Edition in English, Vol. 31, Issue 7 https://doi.org/10.1002/anie.199208421	journal	July 1992
Energy Landscapes of Clusters Bound by Short-Ranged Potentials Wales, David J. ChemPhysChem, Vol. 11, Issue 12 https://doi.org/10.1002/cphc.201000233	journal	June 2010
Differentially Degradable Janus Particles for Controlled Release Applications Hwang, Sangyeul; Lahann, Joerg Macromolecular Rapid Communications, Vol. 33, Issue 14 https://doi.org/10.1002/marc.201200054	journal	May 2012
Sub-micrometer silica spheres dissymmetrically decorated with gold nanoclusters Petit, Laeticia; Manaud, Jean-Pierre; Mingotaud, Christophe Materials Letters, Vol. 51, Issue 6 https://doi.org/10.1016/S0167-577X(01)00338-X	journal	December 2001
Dipole moments of gyricon balls Crowley, Joseph M.; Sheridon, Nicholas K.; Romano, Linda Journal of Electrostatics, Vol. 55, Issue 3-4 https://doi.org/10.1016/S0304-3886(01)00208-X	journal	July 2002
Particle shape: A new design parameter for micro- and nanoscale drug delivery carriers Champion, Julie A.; Katare, Yogesh K.; Mitragotri, Samir Journal of Controlled Release, Vol. 121, Issue 1-2 https://doi.org/10.1016/j.jconrel.2007.03.022	journal	August 2007
Janus and Ternary Particles Generated by Microfluidic Synthesis: Design, Synthesis, and Self-Assembly Nie, Zhihong; Li, Wei; Seo, Minseok Journal of the American Chemical Society, Vol. 128, Issue 29 https://doi.org/10.1021/ja060882n	journal	July 2006
Triblock Colloids for Directed Self-Assembly Chen, Qian; Diesel, Erich; Whitmer, Jonathan K. Journal of the American Chemical Society, Vol. 133, Issue 20 https://doi.org/10.1021/ja202360g	journal	May 2011
Breaking Symmetry toward Nonspherical Janus Particles Based on Polyhedral Oligomeric Silsesquioxanes: Molecular Design, “Click” Synthesis, and Hierarchical Structure Li, Yiwen; Zhang, Wen-Bin; Hsieh, I-Fan Journal of the American Chemical Society, Vol. 133, Issue 28 https://doi.org/10.1021/ja202906m	journal	July 2011
Synthesis of Highly Fluorinated Monodisperse Colloids for Low Refractive Index Crystalline Colloidal Arrays Pan, Guisheng; Tse, Albert S.; Kesavamoorthy, R. Journal of the American Chemical Society, Vol. 120, Issue 26 https://doi.org/10.1021/ja9804823	journal	June 1998
Metal-Capped Brownian and Magnetically Modulated Optical Nanoprobes (MOONs): Micromechanics in Chemical and Biological Microenvironments ^† Behrend, Caleb J.; Anker, Jeffrey N.; McNaughton, Brandon H. The Journal of Physical Chemistry B, Vol. 108, Issue 29 https://doi.org/10.1021/jp040125g	journal	July 2004
One-Dimensional Cluster Growth and Branching Gels in Colloidal Systems with Short-Range Depletion Attraction and Screened Electrostatic Repulsion Sciortino, F.; Tartaglia, P.; Zaccarelli, E. The Journal of Physical Chemistry B, Vol. 109, Issue 46 https://doi.org/10.1021/jp052683g	journal	November 2005
Dynamics in the Presence of Attractive Patchy Interactions De Michele, Cristiano; Gabrielli, Simone; Tartaglia, Piero The Journal of Physical Chemistry B, Vol. 110, Issue 15 https://doi.org/10.1021/jp056380y	journal	March 2006
Dipole–Dipole Interaction Model for Oriented Attachment of BaTiO ₃ Nanocrystals: A Route to Mesocrystal Formation Yasui, Kyuichi; Kato, Kazumi The Journal of Physical Chemistry C, Vol. 116, Issue 1 https://doi.org/10.1021/jp208848j	journal	December 2011
Particles Adsorbed at the Oil−Water Interface: A Theoretical Comparison between Spheres of Uniform Wettability and “Janus” Particles Binks, B. P.; Fletcher, P. D. I. Langmuir, Vol. 17, Issue 16, p. 4708-4710 https://doi.org/10.1021/la0103315	journal	August 2001
Simple Method to Produce Janus Colloidal Particles in Large Quantity Hong, Liang; Jiang, Shan; Granick, Steve Langmuir, Vol. 22, Issue 23 https://doi.org/10.1021/la062716z	journal	November 2006
Sonochemical Synthesis of Magnetic Janus Nanoparticles Teo, Boon M.; Suh, Su Kyung; Hatton, T. Alan Langmuir, Vol. 27, Issue 1 https://doi.org/10.1021/la104284v	journal	December 2010
Silver-Assisted Colloidal Synthesis of Stable, Plasmon Resonant Gold Patches on Silica Nanospheres Bao, Huixin; Butz, Benjamin; Zhou, Zhou Langmuir, Vol. 28, Issue 24 https://doi.org/10.1021/la204762z	journal	March 2012
Clusters of Amphiphilic Colloidal Spheres Hong, Liang; Cacciuto, Angelo; Luijten, Erik Langmuir, Vol. 24, Issue 3 https://doi.org/10.1021/la7030818	journal	February 2008
Controlling the Geometry (Janus Balance) of Amphiphilic Colloidal Particles Jiang, Shan; Granick, Steve Langmuir, Vol. 24, Issue 6 https://doi.org/10.1021/la703274a	journal	March 2008
Single-Particle Tracking of Janus Colloids in Close Proximity Anthony, Stephen M.; Kim, Minsu; Granick, Steve Langmuir, Vol. 24, Issue 13 https://doi.org/10.1021/la800424t	journal	July 2008
Solvent-Free Synthesis of Janus Colloidal Particles Jiang, Shan; Schultz, Mitchell J.; Chen, Qian Langmuir, Vol. 24, Issue 18 https://doi.org/10.1021/la800895g	journal	September 2008
Self-Assembly of Patchy Particles Zhang, Zhenli; Glotzer, Sharon C. Nano Letters, Vol. 4, Issue 8, p. 1407-1413 https://doi.org/10.1021/nl0493500	journal	July 2004
Clusters of Charged Janus Spheres Hong, Liang; Cacciuto, Angelo; Luijten, Erik Nano Letters, Vol. 6, Issue 11 https://doi.org/10.1021/nl061857i	journal	November 2006
Colloids get complex van Blaaderen, Alfons Nature, Vol. 439, Issue 7076 https://doi.org/10.1038/439545a	journal	February 2006
Directed self-assembly of a colloidal kagome lattice Chen, Qian; Bae, Sung Chul; Granick, Steve Nature, Vol. 469, Issue 7330 https://doi.org/10.1038/nature09713	journal	January 2011
Continuous-flow lithography for high-throughput microparticle synthesis Dendukuri, Dhananjay; Pregibon, Daniel C.; Collins, Jesse Nature Materials, Vol. 5, Issue 5, p. 365-369 https://doi.org/10.1038/nmat1617	journal	April 2006
Anisotropy of building blocks and their assembly into complex structures Glotzer, Sharon C.; Solomon, Michael J. Nature Materials, Vol. 6, Issue 8, p. 557-562 https://doi.org/10.1038/nmat1949	journal	August 2007
A molecular toolkit for magnetism Atwood, Jerry L. Nature Materials, Vol. 1, Issue 2 https://doi.org/10.1038/nmat740	journal	October 2002
Energy landscapes of colloidal clusters: thermodynamics and rearrangement mechanisms Calvo, Florent; Doye, Jonathan P. K.; Wales, David J. Nanoscale, Vol. 4, Issue 4 https://doi.org/10.1039/C1NR10679A	journal	January 2012
Design and synthesis of Janus micro- and nanoparticles Perro, Adeline; Reculusa, Stéphane; Ravaine, Serge Journal of Materials Chemistry, Vol. 15, Issue 35-36 https://doi.org/10.1039/b505099e	journal	January 2005
Janus particles Walther, Andreas; Müller, Axel H. E. Soft Matter, Vol. 4, Issue 4 https://doi.org/10.1039/b718131k	journal	January 2008
Design and elaboration of colloidal molecules: an overview Duguet, Etienne; Désert, Anthony; Perro, Adeline Chemical Society Reviews, Vol. 40, Issue 2 https://doi.org/10.1039/c0cs00048e	journal	January 2011
Coupled linear and rotary motion in supramolecular helix handedness inversion Chakrabarti, Dwaipayan; Wales, David J. Soft Matter, Vol. 7, Issue 6 https://doi.org/10.1039/c0sm01507e	journal	January 2011
Bifunctional Janus beads made by “sandwich” microcontact printing using click chemistry Kaufmann, Tobias; Gokmen, M. Talha; Rinnen, Stefan Journal of Materials Chemistry, Vol. 22, Issue 13 https://doi.org/10.1039/c2jm16807c	journal	January 2012
Microfluidic synthesis of multifunctional Janus particles for biomedical applications Yang, Shikuan; Guo, Feng; Kiraly, Brian Lab on a Chip, Vol. 12, Issue 12 https://doi.org/10.1039/c2lc90046g	journal	January 2012
Fabrication of semiconductor Kagome lattice structure by selective area metalorganic vapor phase epitaxy Mohan, Premila; Nakajima, Fumito; Akabori, Masashi Applied Physics Letters, Vol. 83, Issue 4 https://doi.org/10.1063/1.1593823	journal	July 2003
Simulation and theory of a model for tetrahedral colloidal particles Munaó, G.; Costa, D.; Sciortino, F. The Journal of Chemical Physics, Vol. 134, Issue 19 https://doi.org/10.1063/1.3582904	journal	May 2011
Polarization dependence of crystalline colloidal array diffraction Pan, Guisheng; Sood, Ajay K.; Asher, Sanford A. Journal of Applied Physics, Vol. 84, Issue 1 https://doi.org/10.1063/1.368003	journal	July 1998
‘‘Ordered’’ structure in dilute suspensions of charged polymer latices as observed in the vertical planes and in mixtures of heavy and light waters Ito, Kensaku; Nakamura, Hiroshi; Ise, Norio The Journal of Chemical Physics, Vol. 85, Issue 10 https://doi.org/10.1063/1.451479	journal	November 1986
Elasticity and Response in Nearly Isostatic Periodic Lattices Souslov, Anton; Liu, Andrea J.; Lubensky, T. C. Physical Review Letters, Vol. 103, Issue 20 https://doi.org/10.1103/PhysRevLett.103.205503	journal	November 2009
Phase Diagram of Janus Particles Sciortino, Francesco; Giacometti, Achille; Pastore, Giorgio Physical Review Letters, Vol. 103, Issue 23 https://doi.org/10.1103/PhysRevLett.103.237801	journal	November 2009
Dynamical Arrest in Attractive Colloids: The Effect of Long-Range Repulsion Campbell, Andrew I.; Anderson, Valerie J.; van Duijneveldt, Jeroen S. Physical Review Letters, Vol. 94, Issue 20 https://doi.org/10.1103/PhysRevLett.94.208301	journal	May 2005
The Free-Energy Landscape of Clusters of Attractive Hard Spheres Meng, G.; Arkus, N.; Brenner, M. P. Science, Vol. 327, Issue 5965 https://doi.org/10.1126/science.1181263	journal	January 2010
Supracolloidal Reaction Kinetics of Janus Spheres Chen, Q.; Whitmer, J. K.; Jiang, S. Science, Vol. 331, Issue 6014 https://doi.org/10.1126/science.1197451	journal	January 2011
Nanoparticle Superlattice Engineering with DNA Macfarlane, R. J.; Lee, B.; Jones, M. R. Science, Vol. 334, Issue 6053, p. 204-208 https://doi.org/10.1126/science.1210493	journal	October 2011
Thermally Switchable Periodicities and Diffraction from Mesoscopically Ordered Materials Weissman, Jesse M.; Sunkara, Hari B.; Tse, Albert S. Science, Vol. 274, Issue 5289 https://doi.org/10.1126/science.274.5289.959	journal	November 1996
Exploring the Energy Landscape Wales, David J. International Journal of Modern Physics B, Vol. 19, Issue 15n17 https://doi.org/10.1142/S0217979205031857	journal	July 2005
Plasmonic Materials for Surface-Enhanced Sensing and Spectroscopy Haes, Amanda J.; Haynes, Christy L.; McFarland, Adam D. MRS Bulletin, Vol. 30, Issue 5 https://doi.org/10.1557/mrs2005.100	journal	May 2005

Cited By (17)

Crystallization of DNA-coated colloids Wang, Yu; Wang, Yufeng; Zheng, Xiaolong Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8253	journal	June 2015
Spatial confinement governs orientational order in patchy particles Iwashita, Yasutaka; Kimura, Yasuyuki Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep27599	journal	June 2016
Self-assembly of “patchy” nanoparticles: a versatile approach to functional hierarchical materials Lunn, David J.; Finnegan, John R.; Manners, Ian Chemical Science, Vol. 6, Issue 7 https://doi.org/10.1039/c5sc01141h	journal	January 2015
Hydrogen Bonding Directed Colloidal Self-Assembly of Nanoparticles into 2D Crystals, Capsids, and Supracolloidal Assemblies No authors listed Advanced Functional Materials, Vol. 28, Issue 27 https://doi.org/10.1002/adfm.201704328	journal	November 2017
Selective Janus Particle Assembly at Tipping Points of Thermally-Switched Wetting Yu, Changqian; Zhang, Jie; Granick, Steve Angewandte Chemie, Vol. 126, Issue 17 https://doi.org/10.1002/ange.201310465	journal	March 2014
Preparation of Highly Monodisperse Monopatch Particles with Orthogonal Click-Type Functionalization and Biorecognition Tigges, Thomas; Hoenders, Daniel; Walther, Andreas Small, Vol. 11, Issue 35 https://doi.org/10.1002/smll.201501071	journal	June 2015
Janus particles: from synthesis to application Poggi, Elio; Gohy, Jean-François Colloid and Polymer Science, Vol. 295, Issue 11 https://doi.org/10.1007/s00396-017-4192-8	journal	September 2017
Guided hierarchical co-assembly of soft patchy nanoparticles Gröschel, André H.; Walther, Andreas; Löbling, Tina I. Nature, Vol. 503, Issue 7475 https://doi.org/10.1038/nature12610	journal	November 2013
Emerging chirality in nanoscience Wang, Yong; Xu, Jun; Wang, Yawen Chem. Soc. Rev., Vol. 42, Issue 7 https://doi.org/10.1039/c2cs35332f	journal	January 2013
Engineering shape: the novel geometries of colloidal self-assembly Sacanna, Stefano; Pine, David J.; Yi, Gi-Ra Soft Matter, Vol. 9, Issue 34 https://doi.org/10.1039/c3sm50500f	journal	January 2013
Stable cluster phase of Janus particles in two dimensions Iwashita, Yasutaka; Kimura, Yasuyuki Soft Matter, Vol. 9, Issue 45 https://doi.org/10.1039/c3sm52146j	journal	January 2013
Janus particles for biological imaging and sensing Yi, Yi; Sanchez, Lucero; Gao, Yuan The Analyst, Vol. 141, Issue 12 https://doi.org/10.1039/c6an00325g	journal	January 2016
Controlled armoring of metal surfaces with metallodielectric patchy particles Noguchi, Tomohiro G.; Iwashita, Yasutaka; Kimura, Yasuyuki The Journal of Chemical Physics, Vol. 150, Issue 17 https://doi.org/10.1063/1.5090440	journal	May 2019
Recent progress on patchy colloids and their self-assembly Yi, Gi-Ra; Pine, David J.; Sacanna, Stefano Journal of Physics: Condensed Matter, Vol. 25, Issue 19 https://doi.org/10.1088/0953-8984/25/19/193101	journal	April 2013
Self-assembly of "Mickey Mouse" shaped colloids into tube-like structures: experiments and simulations Wolters, Joost R.; Avvisati, Guido; Hagemans, Fabian arXiv https://doi.org/10.48550/arxiv.1412.3373	text	January 2014
Pathways to dewetting in hydrophobic confinement Remsing, Richard C.; Xi, Erte; Vembanur, Srivathsan arXiv https://doi.org/10.48550/arxiv.1502.05436	text	January 2015
A novel transdermal drug delivery system based on self-adhesive Janus nanofibrous film with high breathability and monodirectional water-penetration Shi, Yongli; Li, Yue; Wu, Jianming Taylor & Francis https://doi.org/10.6084/m9.figshare.964892.v2	text	January 2014

Similar Records

Janus Particle Synthesis and Assembly

Journal Article · Mon Mar 08 23:00:00 EST 2010 · Advanced Materials · OSTI ID:1875526

Directed self-assembly of a colloidal kagome lattice

Journal Article · Tue Jan 18 19:00:00 EST 2011 · Nature (London) · OSTI ID:1875134

DNA-Encoded Protein Janus Nanoparticles

Journal Article · Sat Jun 09 20:00:00 EDT 2018 · Journal of the American Chemical Society · OSTI ID:1475554

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Cluster chemistry
Colloidal particles
Hydrophobicity
Nanoparticles
Self organization

Janus and Multiblock Colloidal Particles

Citation Formats

References (53)

Cited By (17)

Similar Records

Related Subjects