Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Black silicon solar thin-film microcells integrating top nanocone structures for broadband and omnidirectional light-trapping

Journal Article · · Nanotechnology
 [1];  [2];  [2];  [2];  [2];  [2];  [2]
  1. Univ. of Illinois at Urbana-Champaign, IL (United States); University of Illinois
  2. Univ. of Illinois at Urbana-Champaign, IL (United States)

Recently developed classes of monocrystalline silicon solar microcells (μ-cell) can be assembled into modules with characteristics (i.e., mechanically flexible forms, compact concentrator designs, and high-voltage outputs) that would be impossible to achieve using conventional, wafer-based approaches. In this paper, we describe a highly dense, uniform and non-periodic nanocone forest structure of black silicon (bSi) created on optically-thin (30 μm) μ-cells for broadband and omnidirectional light-trapping with a lithography-free and high-throughput plasma texturizing process. With optimized plasma etching conditions and a silicon nitride passivation layer, black silicon μ-cells, when embedded in a polymer waveguiding layer, display dramatic increases of as much as 65.7% in short circuit current, as compared to a bare silicon device. Here, the conversion efficiency increases from 8.1% to 11.5% with a small drop in open circuit voltage and fill factor.

Research Organization:
Univ. of Illinois at Urbana-Champaign, IL (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division; NSF
Grant/Contract Number:
FG02-07ER46471; SC0001293
OSTI ID:
1875082
Alternate ID(s):
OSTI ID: 1210695
OSTI ID: 22377404
OSTI ID: 1385342
Journal Information:
Nanotechnology, Journal Name: Nanotechnology Journal Issue: 30 Vol. 25; ISSN 0957-4484
Publisher:
IOP PublishingCopyright Statement
Country of Publication:
United States
Language:
English

References (31)

Transfer Printing Techniques for Materials Assembly and Micro/Nanodevice Fabrication journal August 2012
Cover Picture journal November 2013
Optical reflectance and transmission of a textured surface journal August 1977
Photovoltaic technologies journal December 2008
Role of hydrazine monohydrate during texturization of large-area crystalline silicon solar cell fabrication journal November 2006
Mechanisms of Enhanced Optical Absorption for Ultrathin Silicon Solar Microcells with an Integrated Nanostructured Backside Reflector journal April 2013
Surface Passivation of Efficient Nanotextured Black Silicon Solar Cells Using Thermal Atomic Layer Deposition journal September 2013
Monolithic Integrations of Slanted Silicon Nanostructures on 3D Microstructures and Their Application to Surface-Enhanced Raman Spectroscopy journal November 2012
Electrowetting Properties of Micro/Nanostructured Black Silicon journal August 2010
Performance of Ultrathin Silicon Solar Microcells with Nanostructures of Relief Formed by Soft Imprint Lithography for Broad Band Absorption Enhancement journal August 2010
Optical Absorption Enhancement in Amorphous Silicon Nanowire and Nanocone Arrays journal December 2008
Flexible concentrator photovoltaics based on microscale silicon solar cells embedded in luminescent waveguides journal June 2011
Transfer printing by kinetic control of adhesion to an elastomeric stamp journal December 2005
Ultrathin silicon solar microcells for semitransparent, mechanically flexible and microconcentrator module designs journal October 2008
Local ionic and electron heating in single-molecule junctions journal October 2007
An 18.2%-efficient black-silicon solar cell achieved through control of carrier recombination in nanostructures journal September 2012
Compact monocrystalline silicon solar modules with high voltage outputs and mechanically flexible designs journal January 2010
Pyramidal light trapping and hydrogen passivation for high-efficiency heteroepitaxial (100) crystal silicon solar cells journal January 2012
Fabrication and assembly of ultrathin high-efficiency silicon solar microcells integrating electrical passivation and anti-reflection coatings journal January 2013
Black nonreflecting silicon surfaces for solar cells journal May 2006
Microstructured silicon photodetector journal July 2006
Microbubble-enhanced ultrasound-modulated fluorescence in a turbid medium journal November 2009
A piezoelectric multilayer-stacked hybrid actuation/transduction system journal June 2011
Near infrared electroluminescence from n-InN/p-GaN light-emitting diodes journal March 2012
Recombination at the interface between silicon and stoichiometric plasma silicon nitride journal January 2002
The black silicon method: a universal method for determining the parameter setting of a fluorine-based reactive ion etcher in deep silicon trench etching with profile control journal June 1995
Very low surface recombination velocities on p- and n-type silicon wafers passivated with hydrogenated amorphous silicon films
  • Dauwe, S.; Schmidt, J.; Hezel, R.
  • Conference Record of the Twenty-Ninth IEEE Photovoltaic Specialists Conference 2002, Conference Record of the Twenty-Ninth IEEE Photovoltaic Specialists Conference, 2002. https://doi.org/10.1109/PVSC.2002.1190834
conference January 2002
Lithography-free sub-100 nm nanocone array antireflection layer for low-cost silicon solar cell journal January 2012
Absorption coefficient modeling of microcrystalline silicon thin film using Maxwell-Garnett effective medium theory journal January 2012
Visible and near-infrared responsivity of femtosecond-laser microstructured silicon photodiodes journal January 2005
Fabrication of Nanocone Subwavelength Antireflection Structures on Quartz Substrates journal June 2012

Similar Records

Performance of Ultrathin Silicon Solar Microcells with Nanostructures of Relief Formed by Soft Imprint Lithography for Broad Band Absorption Enhancement
Journal Article · Mon Jun 28 00:00:00 EDT 2010 · Nano Letters · OSTI ID:1876030

Enhanced reflection from inverse tapered nanocone arrays
Journal Article · Mon Aug 04 00:00:00 EDT 2014 · Applied Physics Letters · OSTI ID:22314507

Synthesis of silicon nanocones using rf microplasma at atmospheric pressure
Journal Article · Mon Oct 03 00:00:00 EDT 2005 · Applied Physics Letters · OSTI ID:20709822