3D Scaffolded Nickel-Tin Li-Ion Anodes with Enhanced Cyclability

Zhang, Huigang; Shi, Tan; Wetzel, David J.; Nuzzo, Ralph G.; Braun, Paul V.

doi:10.1002/adma.201504780

3D Scaffolded Nickel-Tin Li-Ion Anodes with Enhanced Cyclability

Journal Article · Mon Nov 30 00:00:00 EST 2015 · Advanced Materials

DOI:https://doi.org/10.1002/adma.201504780· OSTI ID:1874983

Zhang, Huigang ^[1]; Shi, Tan ^[2]; Wetzel, David J. ^[2]; Nuzzo, Ralph G. ^[2]; Braun, Paul V. ^[2]

Nanjing Univ., Jiangsu (China); Univ. of Illinois at Urbana-Champaign, IL (United States); University of Illinois
Univ. of Illinois at Urbana-Champaign, IL (United States)

A 3D mechanically stable scaffold is shown to accommodate the volume change of a high-specific-capacity nickel–tin nanocomposite during operation as a Li-ion battery anode. Here, the nickel–tin anode is supported by an electrochemically inactive conductive scaffold with an engineered free volume and controlled characteristic dimensions, which engender the electrode with significantly improved cyclability.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Illinois at Urbana-Champaign, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division

Grant/Contract Number:: FG02-07ER46471

OSTI ID:: 1874983

Journal Information:: Advanced Materials, Journal Name: Advanced Materials Journal Issue: 4 Vol. 28; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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