High capacity 3D structured tin-based electroplated Li-ion battery anodes

Sun, Pengcheng; Davis, Jerome; Cao, Luoxia; Jiang, Zhelong; Cook, John B.; Ning, Hailong; Liu, Jinyun; Kim, Sanghyeon; Fan, Feifei; Nuzzo, Ralph G.; Braun, Paul V.

doi:10.1016/j.ensm.2018.11.017

Title: High capacity 3D structured tin-based electroplated Li-ion battery anodes

Journal Article · Sun Nov 18 00:00:00 EST 2018 · Energy Storage Materials

DOI:https://doi.org/10.1016/j.ensm.2018.11.017· OSTI ID:1606379

Sun, Pengcheng ^[1]; Davis, Jerome ^[2]; Cao, Luoxia ^[3]; Jiang, Zhelong ^[1]; Cook, John B. ^[2]; Ning, Hailong ^[2]; Liu, Jinyun ^[4]; Kim, Sanghyeon ^[1];

^[3]; Nuzzo, Ralph G. ^[1];

^[1]

Univ. of Illinois at Urbana-Champaign, IL (United States)
Xerion Advanced Battery Corporation, Kettering, OH (United States)
Univ. of Nevada, Reno, NV (United States)
Anhui Normal Univ. (China)

3D structured porous electrodes have been considered as a possible solution for accommodating the volume change of alloying lithium ion battery anode materials during cycling. However, lab-scale porous electrodes tend to be thin, and the loading of the activity materials is also small, the combination of which results in electrodes with impractically low areal and volumetric capacities. In this work, we develop a high areal and volumetric capacity 3D-structured Sn/C anode by using a two steps electroplating process. An electrode with a 20% v/v Sn loading exhibits a high volumetric/areal capacity of similar to 879 mA h/cm³/6.59 mA h/cm² after 100 cycles at 0.5 C and a good rate performance of about 750 mA h/cm³ and 5.5 mA h/cm² (delithiation) at 10 C in a half-cell configuration. The 3D Sn/C anode also shows good compatibility with a commercial LCO cathode in a full cell configuration.

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Research Organization:: Univ. of Illinois at Urbana-Champaign, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; USDOE

Grant/Contract Number:: FG02-07ER46471

OSTI ID:: 1606379

Alternate ID(s):: OSTI ID: 1637212

Journal Information:: Energy Storage Materials, Vol. 17, Issue C; ISSN 2405-8297

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 28 works

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Fabrication of an anode composed of a N, S co-doped carbon nanotube hollow architecture with CoS ₂ confined within: toward Li and Na storage Wang, Junling; Wang, Jingwen; Han, Longfei Nanoscale, Vol. 11, Issue 43 https://doi.org/10.1039/c9nr07767g	journal	January 2019
Tailored Ni ₂ P nanoparticles supported on N-doped carbon as a superior anode material for Li-ion batteries Guo, Huinan; Cai, Haichao; Li, Weiqin Inorganic Chemistry Frontiers, Vol. 6, Issue 7 https://doi.org/10.1039/c9qi00480g	journal	January 2019

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Title: High capacity 3D structured tin-based electroplated Li-ion battery anodes

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