Effects of Rare-Earth (R = Pr, Gd, Ho, Er) Doping on Magnetostructural Phase Transitions and Magnetocaloric Properties in Ni43–xRxMn46Sn11 Shape Memory Alloys

Aryal, Anil; Pandey, Sudip; Dubenko, Igor; Mazumdar, Dipanjan; Stadler, Shane; Ali, Naushad

doi:10.1109/tmag.2018.2868134

Title: Effects of Rare-Earth (R = Pr, Gd, Ho, Er) Doping on Magnetostructural Phase Transitions and Magnetocaloric Properties in Ni_43–xR_xMn₄₆Sn₁₁ Shape Memory Alloys

Journal Article · Wed Sep 26 00:00:00 EDT 2018 · IEEE Transactions on Magnetics

DOI:https://doi.org/10.1109/tmag.2018.2868134· OSTI ID:1872888

^[1];

^[1]; Dubenko, Igor ^[1]; Mazumdar, Dipanjan ^[1]; Stadler, Shane ^[2]; Ali, Naushad ^[1]

Southern Illinois Univ., Carbondale, IL (United States)
Louisiana State Univ., Baton Rouge, LA (United States)

A series of rare-earth-doped Ni_43-xRxMn₄₆Sn₁₁ (x = 0, 1 and R = Pr, Gd, Ho, Er) alloys was fabricated by arc melting, and their structural, magnetic, and magnetocaloric properties were studied through room temperature X-ray diffraction (XRD), differential scanning calorimetry, and magnetization measurements. Analysis of XRD data reveal that the alloys crystallize in the cubic L2₁ austenite phase structure as the major phase with a small trace of martensitic phase (MP). The martensitic transition temperature (T_M) shifts to consecutive higher temperatures with the substitution of Pr, Gd, Ho, and Er. A drastic shift in TM by ~60 K relative to the parent compound (TM = 195 K) was found for Ni₄₂PrMn₄₆Sn₁₁. Large values of magnetic entropy changes (ASM) of 32 (Pr), 28 (Gd), and 25 J · kg^-1 · K^-1 (Ho) were obtained at TM for ΔH = 50 kOe. A maximum value of the refrigeration capacity of ~250 J · kg-1 was obtained in the vicinity of TM for ΔH = 50 kOe for the Ho-doped compound. Furthermore, a large exchange bias effect with HEB~ 1.1 kOe at 10 K was observed for the Pr-doped compound in its MP.

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Research Organization:: Louisiana State Univ., Baton Rouge, LA (United States); Southern Illinois Univ., Carbondale, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division

Grant/Contract Number:: FG02-13ER46946; SC0010521

OSTI ID:: 1872888

Journal Information:: IEEE Transactions on Magnetics, Vol. 55, Issue 2; ISSN 0018-9464

Publisher:: Institute of Electrical and Electronics Engineers. Magnetics GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Title: Effects of Rare-Earth (R = Pr, Gd, Ho, Er) Doping on Magnetostructural Phase Transitions and Magnetocaloric Properties in Ni43–xRxMn46Sn11 Shape Memory Alloys

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Title: Effects of Rare-Earth (R = Pr, Gd, Ho, Er) Doping on Magnetostructural Phase Transitions and Magnetocaloric Properties in Ni_43–xR_xMn₄₆Sn₁₁ Shape Memory Alloys